Nanoanalytics : nanoobjects and nanotechnologies in analytical chemistry / edited by Sergei Shtykov.

Format:

Book

Contributor:

Shtykov, S. N. (Sergeĭ Nikolaevich), editor.

Language:

English

Subjects (All):

Analytical chemistry.

Nanostructured materials.

Physical Description:

xvii, 446 pages ; 24 cm

Place of Publication:

Berlin ; Boston : Walter de Gruyter, GmbH, [2018]

Contents:

Part I Nanoanalytics: Concepts, Elements, and Peculiarities

1 Nanoanalytics: Definitions, Classification, History, and Primary Advances p. 3 / S. N. Shtykov

1.2 Brief historical overview p. 7

1.3 The concept of nanoanalytics p. 11

1.4 Nanoobjects as tools for nanoanalytics p. 13

1.4.1 Definition, classification, and fundamental properties of nanoobjects p. 13

1.4.2 Liquid nanoobjects p. 15

1.4.3 Solid nanoobjects (nanomaterials) p. 22

1.5 Nanotechnologies as tools for nanoanalytics p. 27

1.6 Nanoanalysis and nanometrology p. 31

1.6.1 Definitions and elements p. 31

1.6.2 Analysis of chemical composition of nanoobjects p. 32

1.6.3 Imaging of bioobjects and theranostics p. 36

1.6.4 Nanometrology in nanoanalytics p. 37

Part II Application in Spectrometric Methods

2 Gold Nanoparticles in Bioanalytical Techniques p. 55 / L. A. Dykman and N. G. Khlebtsov and S. Y. Shchyogolev

2.2 Homophase techniques p. 58

2.3 Dot blot immunoassay p. 60

2.4 Immunocbromatographic assays p. 64

2.5 Plasmonic biosensors p. 66

3 Extinction and Emission of Nanoparticles for Application in Rapid Immunotests p. 87 / I. Y. Goryacheva

3.2 Extinction of nanoparticles p. 88

3.2.1 Colloidal gold p. 88

3.2.2 Colloidal carbon p. 91

3.2.3 "Colloidal" dyes p. 92

3.3 Emission of nanoparticles p. 92

3.3.1 Fluorescence dyes p. 93

3.3.2 Lanthanide chelates p. 94

3.3.3 Quantum dots p. 94

3.3.4 Nanoparticles with infrared luminescence p. 96

3.3.5 Up converting phosphors p. 97

3.3.6 Nanoparticles with long-lived luminescence p. 98

4 Nanofilms as Sensitive Layers of Chemical and Biochemical Sensors p. 107 / T. Yu. Rusanova

4.2 Nanofilm types and techniques of their preparation p. 108

4.2.1 Self-assembled monolayers p. 108

4.2.2 LbL technique p. 110

4.2.3 LB films p. 112

4.3 Nanofilms' sensor application p. 113

4.3.1 SAM p. 113

4.3.2 LbL technique p. 114

4.3.3 LB films p. 117

5 Energy Transfer in Liquid and Solid Nanoobjects: Application In Luminescent Analysis p. 131 / T. D. Smirnova and S. N. Shtykov and E. A. Zhelobitskaya

5.2 Nanoobjects involved in ET p. 133

5.3 Application of FRET in analysis p. 135

5.3.1 FRET in micellar solutions p. 135

5.3.2 FRET with protein participation p. 136

5.3.3 FRET with nanomaterials' participation p. 136

5.3.3.1 Quantum dots p. 136

5.3.3.2 Nanoparticles based on Au, Ag, Au-Ag, and graphene p. 140

5.4 The lanthanide chelates' ET application p. 146

5.4.1 Liquid micellar nanosystems p. 146

5.4.2 ET in binuclear complexes of heteronanoparticles p. 152

Part III Application in Electroanalysis

6 Nanomaterials: Electrochemical Properties and Application in Sensors p. 165 / Kh. Brainina and N. Stozhko and M. Bukharinova and E. Vikulova

6.2 Properties of nanoparticles p. 166

6.3 Theoretical and experimental approaches to nanoscale material study p. 167

6.4 Macro- to micro- and to nanoscale transition p. 171

6.5 Nanostructures in chemical monitoring p. 177

6.5.1 Nanomaterials as transducers and catalysts in electrochemical sensors p. 177

6.5.2 Nanomaterials in electrochemical sensors for antioxidant detection p. 189

6.5.3 Nanomaterials in electrochemical immunoassay p. 196

6.5.4 Nanomaterials - transducers and adsorbents in electrochemical immunosensors p. 196

6.5.5 Nanomaterials as analyte transporters p. 201

6.5.6 Nanomaterials as labels in electrochemical immunosensors p. 202

7 Carbon Nanomaterials and Surfactants as Electrode Surface Modifiers in Organic Electroanalysis p. 223 / G. Ziyatdinova and H. Budnikov

7.2 Carbon nanomaterial-based electrodes p. 224

7.2.1 Graphene p. 224

7.2.2 Fullerenes p. 228

7.2.3 Carbon nanotubes p. 229

7.3 Surfactant-modified electrodes for the organic electroanalysis p. 232

7.4 Analytical possibilities of the electrodes with co-immobilized carbon nanomaterials and surfactants p. 238

8 Nanomaterials in the Assembly of Electrochemical DMA Sensors p. 253 / G. Evtugyn and A. Porfireva and H. Budnikov and T. Hianik

8.2 DNA sensors: Recognition elements and signal transduction p. 255

8.2.1 Biochemical elements applied in the DNA sensors assemblies p. 255

8.2.2 Measurement of the signal of electrochemical DNA sensors p. 258

8.3 DNA sensors based on metal nanoparticles p. 262

8.3.1 Au nanoparticles p. 262

8.3.2 Other metal nanoparticles p. 269

8.4 DNA sensors based on carbonaceous materials p. 271

8.4.1 Carbon nanotubes p. 271

8.4.2 Graphene-based DNA sensors p. 281

Part IV Application in Sorption and Separation Methods

9 Molecularly Imprinted Polymers: Synthesis, Properties, and Application in Analysis of Real Samples p. 303 / S. G. Dmitrienko and V. V. Apyari

9.2 The principle of molecular imprinting p. 304

9.2.1 Covalent and noncovalent approach p. 304

9.2.2 Selecting the template and the reagents p. 306

9.3 Methods for synthesis of MIPs p. 308

9.3.1 Radical bulk polymerization p. 308

9.3.2 Synthesis of spherical microparticles p. 309

9.3.3 Synthesis of nanoscale imprinted materials p. 312

9.4 Sorption properties of MIPs and selectivity of processes with their participation p. 315

9.5 Application in the analysis of real samples p. 320

10 Sorbents Based on Carbon Nanotubes p. 343 / S. Grazhulene and A. Red'kin

10.2 Synthesis, properties of CNTs, and methods of their study p. 344

10.2.1 History of CNTs p. 344

10.2.2 Synthesis, functionalization, and characterization of CNTs

10.2.2.1 Methods of synthesis p. 346

10.2.2.2 Modification and functionalization p. 350

10.2.2.3 Methods of characterization p. 353

10.3 Sorption properties of CNTs p. 356

10.3.1 Sorption of metals from aqueous solutions p. 356

10.3.2 Sorption of organic substances p. 362

10.3.3 Comparison of CNTs with other sorbents p. 364

10.4 CNTs for chemical analysis p. 366

10.4.1 Concentration and determination of metals p. 366

10.4.2 On-line preconcentration and speciation analysis p. 368

10.4.3 Piezosensors p. 369

10.4.4 Other applications of CNTs p. 372

11 Application of Microemulsions for Extraction and Preconcentration of Hydrophobic Target Compounds p. 389 / A. V. Pirogov

11.2 Microemulsions: structure and classification p. 389

11.3 Preparation and decomposition of microemulsions p. 393

11.4 Application of micellar and microemulsion media for extraction of target compounds p. 396

11.4.1 Extraction and preconcentration of organic substances p. 396

11.4.2 Extraction and preconcentration of metals p. 398

11.4.3 Extraction and preconcentration of PAHs p. 402

12 Surfactant Micelles in Liquid Chromatography p. 411 / E. G. Sumina

12.2 General characteristics of the method p. 413

12.3 Features of mobile and stationary phases in MLC p. 415

12.3.1 Mobile phases p. 415

12.3.2 Stationary phases p. 420

12.4 Retention models in MLC p. 423

12.5 Application of MLC in analysis p. 427.

Notes:

Includes bibliographical references and index.

Other Format:

Online version: Nanoanalytics

ISBN:

9783110540062

3110540061

OCLC:

994368681