Zeolites and zeolite-like materials / edited by Bert F. Sels, Leonid M. Kustov.

Format:

Book

Contributor:

Sels, Bert, editor.

Kustov, Leonid M., editor.

Language:

English

Subjects (All):

Zeolites.

Physical Description:

1 online resource (475 p.)

Place of Publication:

Amsterdam, [Netherlands] : Elsevier, 2016.

Summary:

Zeolites and Zeolite-like Materials offers a comprehensive and up-to-date review of the important areas of zeolite synthesis, characterization, and applications. Its chapters are written in an educational, easy-to-understand format for a generation of young zeolite chemists, especially those who are just starting research on the topic and need a reference that not only reflects the current state of zeolite research, but also identifies gaps and opportunities.The book demonstrates various applications of zeolites in heterogeneous catalysis and biomass conversion and identifies the endless possibilities that exist for this class of materials, their structures, functions, and future applications. In addition, it demonstrates that zeolite-like materials should be regarded as a living body developing towards new modern applications, thereby responding to the needs of modern technology challenges, including biomass conversion, medicine, laser techniques, and nanomaterial design, etc.The book will be of interest not only to zeolite-focused researchers, but also to a broad scientific and non-scientific audience.- Provides a comprehensive review of the literature pertaining to zeolites and zeolite-like materials since 2000- Covers the chemistry of novel zeolite-like materials such as Metal-Organic Frameworks (MOFs), Covalent Organic Frameworks (COFs), hierarchical zeolite materials, new mesoporous and composite zeolite-like micro/mesoporous materials- Presents essential information of the new zeolite-like structures, with a balanced coverage of the most important areas of the zeolite research (synthesis, characterization, adsorption, catalysis, new applications of zeolites and zeolite-like materials)- Contains chapters prepared by known specialists who are members of the International Zeolite Association

Contents:

Front Cover; Zeolites and Zeolite-like Materials; Copyright; Contents; Contributors; Preface; Chapter 1: Toward Greener and Designed Synthesis of Zeolite Materials; 1 Introduction; 2 Green Synthesis; 2.1 Synthesis for Reduced Cost and Environmental Impact; 2.1.1 Organic-template-free synthesis; 2.1.1.1 Metal-cation-directed synthesis; 2.1.1.2 Seed-assisted synthesis; 2.1.2 Solvent-free synthesis; 2.1.3 Cheap or low-toxic organic-template-directed synthesis; 2.2 Synthesis for Waste Reused; 2.2.1 Organic-template-reused synthesis; 2.2.2 Mother-liquor-reused synthesis

2.3 Synthesis for Energy Efficiency: Microwave-Assisted Synthesis2.4 Synthesis for Process Safety: Ionothermal Synthesis; 3 Designed Synthesis; 3.1 Designing Novel SDAs; 3.1.1 SDA design for novel zeolite structures; 3.1.2 SDA design for hierarchical zeolites; 3.2 Charge Density Mismatch; 3.3 Heteroatom Substitution; 3.3.1 Heteroatom substitution with trivalent and divalent metal ions; 3.3.2 Heteroatom substitution with Ge atom to direct D4R; 3.4 Topotactic Conversion of Framework; 3.4.1 Topotactic condensation of layered structures (2D-3D); 3.4.2 Topotactic conversion of a 3D framework

4 ConclusionReferences; Chapter 2: Metal-Organic Frameworks and Related Materials: Miles to Go; 1 Introduction; 1.1 Synthesis of Carboxylate MOFs; 2 MOFs as Selective Heterogeneous Catalysts; 3 The Nature of Catalitically Active Sites in MOFs; 3.1 Catalysis on Open Catalytically Active Sites; 3.2 Catalysis on Formally Saturated Catalytically Active Sites; 3.3 Catalysis on Framework Defects; 4 Design of Catalysts Based on MOFs; 4.1 MOF as a Support for Heterogeneous Catalysts; 4.2 Bridging Ligand as an Active Site; 4.2.1 Metal-containing ligands; 4.2.2 Catalysis by metal-free organic ligands

4.3 Inorganic Node as an Active Site4.4 Introduction of Guest Molecules Containing Catalytically Active Sites; 4.5 Active Sites Introduced by the Postsynthetic Modification of the Framework; 5 Catalysis in the Presence of Chiral MOFs; 6 Other Types of Catalytic Processes on MOFs; 7 Adsorption on MOFs; 7.1 Hydrogen Storage; 7.1.1 Physical sorption of hydrogen; 7.1.2 H2 storage in zeolites; 7.1.3 H2 storage in MOFs; 7.1.4 Specific surface area; 7.1.5 Pore shape and size; 7.1.6 MOFs with catenane structures; 7.1.7 Chemistry of organic linkers; 7.1.8 Flexibility of organic linkers

7.1.9 Presence of coordinatively unsaturated (open) metal centers7.1.10 Hydrogen spillover; 7.1.11 Adsorption and storage of other molecules; 8 MOFs as Sensor Materials; 9 Other Potential Applications; 10 Conclusions; Acknowledgment; References; Chapter 3: Computational Chemistry of Zeolite Catalysis; 1 Introduction; 2 Methodology; 2.1 The Concept of the Potential Energy Surface; 2.2 The Many-Body Problem and Born-Oppenheimer Approximation; 2.3 Ab Initio Methods; 2.4 Density Functional Theory; 2.5 Basis Sets; 2.6 Models; 3 Reactions in Confined Space: The Role of Dispersion Interactions

4 Structural Complexity of Active Sites in Zeolites

Notes:

Description based upon print version of record.

Includes bibliographical references at the end of each chapters and index.

Description based on online resource; title from PDF title page (ebrary, viewed May 17, 2016).

ISBN:

9780444635143

0444635149

9780444635068

0444635068