New fluorinated carbons : fundamentals and applications / edited by Olga V. Boltalina, Tsuyoshi Nakajima.

Format:

Book

Contributor:

Boltalina, Olga V., editor.

Nakajima, Tsuyoshi, 1943- editor.

Series:

Progress in fluorine science series.

Progress in Fluorine Science Series

Language:

English

Subjects (All):

Fluorine.

Physical Description:

1 online resource (444 pages) : illustrations (some color).

Edition:

1st ed.

Place of Publication:

Amsterdam, Netherlands : Elsevier, 2017.

Summary:

New Fluorinated Carbons: Fundamentals and Applications is the second volume in Alain Tressaud's Progress in Fluorine Science series.This volume provides an overview of cutting-edge research and emerging applications using new fluorinated carbon materials such as fullerenes, carbon nanotubes, polycyclic aromatic molecules, carbon nanofibers, and.

Contents:

Front Cover

New Fluorinated Carbons: Fundamentals and Applications

Copyright

Contents

List of Contributors

Preface

1 - Electronic Properties and Applications of Fluorofullerenes

1.1 Introduction

1.2 Molecular Structures

1.3 Electronic Properties

1.3.1 Electron Affinity in the Gas Phase

1.3.2 Reduction Potentials in Solution

1.3.3 Electronic Properties in the Solid State

1.4 Applications

1.4.1 Surface Doping of Diamond, Silicon, and Graphene

1.4.2 Bulk p-Doping of Organic Semiconductors in OLEDs and OPVs

1.5 Summary and Outlook

References

2 - Synthesis and Isolation of Trifluoromethylfullerenes

2.1 Introduction

2.2 Synthetic Methodologies

2.2.1 General Remarks on Trifluoromethylfullerene Formation

2.2.2 Solution Reactions

2.2.3 Solid-Solid Reactions

2.2.4 Gas-Solid Reactions

2.3 Trifluoromethylfullerene Isolation Methodologies

2.3.1 High-Performance Liquid Chromatography

2.3.2 Solvent Extraction and Selective Crystallization

2.3.3 Sublimation and Thermal Annealing

2.4 Conclusions and Outlook

Appendix

Acknowledgment

3 - Thirteen Decakis(trifluoromethyl)decahydro(C60-Ih)[5,6]fullerenes (C60(CF3)10): Structures and Structure-Related Proper ...

3.1 Introduction

3.2 The 13 Isomers of C60(CF3)10

3.3 Enumerating C60(CF3)10 Addition Patterns That Meet the Guidelines

3.4 The Molecular Structures of the Seven Recently Reported C60(CF3)10 Isomers

3.5 The Links Between Molecular and Electronic Structures of C60(CF3)10 Isomers

3.6 The Solid-State Packing of C60(CF3)10 Isomers

Acknowledgments

4 - Trifluoromethylated Corannulene Derivatives: Thermodynamic Stability and Electron-Accepting Properties

4.1 Introduction.

4.2 Thermodynamic Stability of CORA(CF3)x Derivatives

4.3 Electron-Accepting Properties of CORA(CF3)x Derivatives and Addition Patterns

4.4 Conclusions

5 - Fluorination-Defluorination and Fluorine Storage Properties of Single-Wall Carbon Nanotubes and Carbon Nanohorns

5.1 Introduction

5.2 Fluorination-Defluorination and Fluorine Storage Properties of Single-Wall Carbon Nanotubes

5.3 Fluorine Storage Properties of Carbon Nanohorns

5.3.1 Structural Features and Fundamental Aspects of Fluorine Adsorption on Single-Wall Carbon Nanohorns

5.3.1.1 Structural Features of Single-Wall Carbon Nanohorns

5.3.1.2 Adsorption Sites, Surface Areas, and Fluorine Adsorption Stoichiometry of Single-Wall Carbon Nanohorns

5.3.2 Fluorine Adsorption and Desorption Properties of Single-Wall Carbon Nanohorns

5.3.3 Mechanism of Fluorine Desorption and Nature of CF Bonding

5.3.4 Distinguishing Features of Single-Wall Carbon Nanohorns Associated With the Fluorine Storage Properties

6 - Synthesis and Characterization of Fluorinated Carbon Fibers and Nanotubes

6.1 Introduction

6.2 Synthesis of Fluorinated Carbon Materials

6.2.1 Direct Fluorination

6.2.1.1 Direct Fluorination of Carbon Nanotubes

6.2.1.2 Direct Fluorination of Carbon Fibers

6.2.2 Plasma Fluorination

6.2.2.1 Plasma Fluorination of Carbon Nanotubes

6.2.2.2 Plasma Fluorination of Carbon Fibers

6.3 Electrical Characteristics of Fluorinated Carbon Materials

6.3.1 Electrical Characteristics of Fluorinated Carbon Fibers

6.3.2 Electrical Characteristics of Fluorinated Single-Walled Carbon Nanotubes

6.3.3 Electrical Characteristics of Fluorinated Multi-Walled Carbon Nanotubes

7 - Perfluoroalkylated PAH n-Type Semiconductors: Theory and Experiment

7.1 Introduction.

7.2 Stereoelectronic Consideration of Perfluoroalkylated Polyaromatic Hydrocarbons

7.2.1 The Electronic Effect of Perfluoroalkyl Substituents

7.2.2 Changes in Reorganization Energy Associated With Electron Transfer Upon Perfluoroalkyation

7.2.3 Changes in Intermolecular Interactions Upon Perfluoroalkylation

7.3 Perfluoroalkylated Polyaromatic Hydrocarbons: Synthesis, Characterization, and Crystal Engineering

7.3.1 Synthesis and Purification: Early Stage Versus Late-Stage Perfluoroalkylation

7.3.2 Characterization: NMR, MS, and Single Crystal X-Ray Diffraction

7.3.3 Crystal Engineering: How Perfluoroalkyl Substitution Affects the Solid-State Structures of the Polyaromatic Hydrocarbons

7.4 Physicochemical Properties of Perfluoroalkylated Polyaromatic Hydrocarbons

7.4.1 Changes in Electrochemical Properties Upon Perfluoroalkylation

7.4.2 Changes in Photophysical and Photochemical Properties Upon Perfluoroalkylation

7.4.3 n-Type Semiconductor Performance of Perfluoroalkylated Polyaromatic Hydrocarbons

7.5 Summary and Perspective

8 - Electronic Structure of Fluorinated Graphene

8.1 Introduction

8.2 Brief Guide to Graphite Fluorides

8.3 Key Issues Studied for Fluorinated Graphene

8.4 Fluorographene

8.5 One-Side Graphene Fluorination

8.6 Two-Side Partially Fluorinated Graphene

8.7 Fluorinated Bi- and Few-Layer Graphene

8.8 Fluorographene/Graphene Hybrids

8.9 Insights Into Fluorination Mechanisms

8.10 Nature of CF Bonding

8.11 Optical Properties

8.12 Conclusions

9 - Nature of C-F Bonds in Fluorinated Carbons

9.1 Introduction

9.2 Fluorination Methods: From Room Temperature to 600°C

9.2.1 Conventional Fluorination With F2: From C60 to Graphite as Precursor

9.2.1.1 Graphitization

9.2.1.2 Curvature Effect.

9.2.1.3 Porous Materials

9.2.2 Catalytic Fluorination

9.3 Nuclear Magnetic Resonance as a Powerful Tool for the Investigation of the C-F Bonding

9.3.1 Chemical Shifts

9.3.1.1 Hyperconjugation

9.3.1.2 Curvature Effect

9.3.2 C-F Bond Length via Inverse 19F-13C CP-MAS

9.3.3 Nuclear Magnetic Resonance Versus Near-Edge X-Ray Absorption Fine Structure

9.3.4 Nuclear Magnetic Resonance Versus Electrochemistry (CFx in Li Battery as a Local Probe of the C-F Bonding)

9.4 Tuning the C-F Covalence to Enhance the Applicative Properties

10 - Preparation and Application of Fluorine-Carbon and Fluorine-Oxygen-Carbon Materials

10.1 Introduction

10.2 Electrochemical Preparation of CxF

10.2.1 Synthesis and Structure of CxF

10.2.2 Electrochemical Fluorination of Graphite in an Aqueous Solution of Hydrofluoric Acid [14,15]

10.2.3 Electrochemical Fluorination of Graphite in an All-Solid Cell [16]

10.2.4 Cathodic Performance of CxF

10.3 Preparation of Transparent and Conducting Electrode From Graphene Oxide Containing Perfluoroalkyl Groups

10.3.1 Graphene Oxide for Transparent and Conducting Electrode

10.3.2 The Use of Fluorine in Fluoroalkyl Groups for the Modification of Inorganic Materials

10.3.3 Introduction of Perfluoroalkyl Groups Into Graphene Oxide and Preparation of Carbon Thin Film Samples

10.3.4 Properties of Transparent and Conducting Electrodes From Silylated Graphene Oxide Containing Perfluoroalkyl Groups

11 - Intercalation Chemistry and Application of B/C/N Materials to Secondary Batteries

11.1 Introduction

11.2 Preparation of Boron/Carbon/Nitrogen and Boron/Carbon Materials

11.3 Intercalation of Li Into Boron/Carbon/Nitrogen and Boron/Carbon Materials and Its Application to Anode of Li-Ion Batteries.

11.3.1 Electrochemical Intercalation of Li Into Boron/Carbon/Nitrogen Materials

11.3.2 Electrochemical Intercalation of Li Into Boron/Carbon/Nitrogen Material Treated With Hydrofluoric Acid

11.3.3 Electrochemical Intercalation of Li Into Boron/Carbon Materials

11.4 Intercalation of Na and Mg Into Boron/Carbon/Nitrogen Materials

11.4.1 Intercalation of Na Into BC2N by Chemical Reaction

11.4.2 Intercalation of Mg Into BC2N by Chemical Reaction

11.5 Intercalation Mechanism of Metals Into Boron/Carbon/Nitrogen Materials

11.5.1 Electronic Structure of Boron/Carbon/Nitrogen Materials

11.5.2 Relation Between Electronic Structures of Host Materials and Ionization Potentials of Metals

11.6 Intercalation of Na Into Boron/Carbon/Nitrogen and Boron/Carbon Materials and Its Application to Anode of Na-Ion Batteries

11.6.1 Electrochemical Intercalation of Na Into Boron/Carbon/Nitrogen and Boron/Carbon Materials

11.6.2 Mechanism of Electrochemical Intercalation of Na Into Boron/Carbon/Nitrogen and Boron/Carbon Materials

11.7 Application of Boron/Carbon/Nitrogen Materials to Dual Carbon Alloy Batteries

11.8 Summary

12 - Structures of Highly Fluorinated Compounds of Layered Carbon

12.1 Introduction

12.2 Experimental

12.3 Results and Discussion

12.3.1 Structures of (CF)n and (C2F)n

12.3.2 Structure of CxF

13 - Lithium-Graphite Fluoride Battery-History and Fundamentals

13.1 Development of Li/(CF)n Battery

13.2 Synthesis and Properties of Graphite Fluorides

13.2.1 Graphite Intercalation Compounds

13.2.2 Synthesis of Graphite Fluorides

13.2.3 Surface Properties of Graphite Fluoride

13.3 Cell Reaction of Lithium-Graphite Fluoride Battery

13.3.1 Electromotive Forces of Li/CFx Cell Calculated on the Basis of Simple Cell Reaction.

13.3.2 Thermodynamic Data of Real Cell.

Notes:

Includes bibliographical references at the end of each chapters and index.

Description based on online resource; title from PDF title page (ebrary, viewed September 26, 2016).

Description based on publisher supplied metadata and other sources.

ISBN:

9780128035023

0128035021

OCLC:

958573093