Handbook of polymer solution thermodynamics / Ronald P. Danner, Martin S. High.

Format:

Book

Author/Creator:

Danner, R. P. (Ronald P.), 1939-

Contributor:

Pennsylvania State University. Department of Chemical Engineering.

High, Martin S., 1959-

Language:

English

Subjects (All):

Polymer solutions--Thermal properties--Handbooks, manuals, etc.

Polymer solutions.

Physical Description:

1 online resource (194 p.)

Place of Publication:

New York : Design Institute for Physical Property Data, American Institute of Chemical Engineers, c1993.

Language Note:

English

Summary:

Created for engineers and students working with pure polymers and polymer solutions, this handbook provides up-to-date, easy to use methods to obtain specific volumes and phase equilibrium data. A comprehensive database for the phase equilibria of a wide range of polymer-solvent systems, and PVT behavior of pure polymers are given, as are accurate predictive techniques using group contributions and readily available pure component data. Two computer programs on diskettes are included. POLYPROG implements procedures given for prediction and correlation for specific volume of pure polymer liquid

Contents:

Handbook Of Polymer Solution Thermodynamics; TABLE OF CONTENTS; PREFACE; Chapter 1 : INTRODUCTION; A. OBJECTIVES OF THE HANDBOOK OF POLYMER SOLUTION THERMODYNAMICS; Chapter 2: FUNDAMENTALS OF POLYMER SOLUTION THERMODYNAMICS; A. PURE POLYMER PVT BEHAVIOR; B. PHASE EQUILIBRIA THERMODYNAMICS; C. MODELING APPROACHES TO POLYMER SOLUTION THERMODYNAMICS; D. LATTICE MODELS; 1. Flory-Huggins Model; 2. Solubility Parameters and the Flory-Huggins Model; 3. Modifications of the Flory-Huggins Model; 4. Sanchez-Lacombe Equation of State; 5. Panayiotou-Vera Equation of State; 6. Kumar Equation of State

7. High-Danner Equation of State8. Oishi-Prausnitz Activity Coefficient Model; E. VAN DER WAALS MODELS; 1. Flory Equation of State; 2. Chen, Fredenslund, and Rasmussen Equation of State; F. LIQUID-LIQUID EQUILIBRIA OF POLYMER SOLUTIONS; 1. Thermodynamics of Liquid-Liquid Equilibria; 2. Types of Liquid-Liquid Equilibria; 3. Models for Liquid-Liquid Equilibria; 4. Computation of Liquid-Liquid Equilibria Compositions; 5. Parameter Estimation from Liquid-Liquid Equilibria Data; 6. Sample Correlations of Liquid-Liquid Equilibria Data; G. EFFECT OF POLYDISPERSION; Chapter 3: RECOMMENDED PROCEDURES

A. SELECTION OF MODELS1. Correlation of Pure Polymer PVT Behavior; 2. Prediction of Vapor-Liquid Equilibria; B. PROCEDURE: METHOD FOR ESTIMATING THE SPECIFIC VOLUME OF A PURE POLYMER LIQUID; 1. Method; 2. Procedure; 3. Limitations and Reliability; 4. Comments; 5. Literature Sources; 6. Example; C. PROCEDURE: OISHI-PRAUSNITZ METHOD FOR ESTIMATING THE ACTIVITY COEFFICIENTS OF SOLVENTS IN POLYMER SOLUTIONS; 1. Method; 2. Procedure; 3. Limitations and Reliability; 4. Comments; 5. Literature Sources; 6. Example

D. PROCEDURE: CHEN-FREDENSLUND-RASMUSSEN EQUATION OF STATE FOR ESTIMATING THE ACTIVITY COEFFICIENTS OF SOLVENTS IN POLYMER SOLUTIONS1. Method; 2. Procedure; 3. Limitations and Reliability; 4. Literature Source; 5. Example; E. PROCEDURE: HIGH-DANNER EQUATION OF STATE FOR ESTIMATING THE ACTIVITY COEFFICIENT OF A SOLVENT IN A POLYMER SOLUTION; 1. Method; 2. Procedure; 3. Limitations and Reliability; 4. Literature Sources; 5. Example; F. PROCEDURE: FLORY-HUGGINS CORRELATION FOR VAPOR-LIQUID EQUILIBRIA OF POLYMER SOLVENT SYSTEMS; 1. Method; 2. Procedure; 3. Limitiations and Reliability

4. Literature Source5. Example; Chapter 4: POLYMER DATA BASE; A. INTRODUCTION; B. EXPERIMENTAL METHODS; 1. Inverse Gas Chromatography (IGC); 2. Piezoelectric Sorption (PZS); 3. Differential Vapor Pressure (DVP); 4. Gravimetric Sorption (GS); 5. Light Scattering (LS); 6. Ultracentrifuge (UC); 7. Turbidimetry (TB) and Light Scattering Turbidimetry (LST); 8. Microanalytical (MA); 9. Ultraviolet Spectrometry (UVS) and Infrared Spectrometry (1RS); 10. Size Exclusion Chromatography (SEC); C. DATA REDUCTION PROCEDURES; 1. Pure Polymer PVT Data; 2. Finite Dilution Flory Chi Parameter

3. Infinite Dilution Flory Chi Parameter

Notes:

Description based upon print version of record.

Includes bibliographical references (p. 161-184).

ISBN:

1-282-81737-X

9786612817373

0-470-93823-4

1-59124-701-2

0-470-93822-6

OCLC:

56516533