Industrial catalytic processes for fine and specialty chemicals / edited by Sunil S. Joshi, Vivek V. Ranade.

Format:

Book

Contributor:

Joshi, Sunil S., editor.

Ranade, Vivek V., editor.

Language:

English

Subjects (All):

Catalysis.

Catalysts.

Catalysts--Industrial applications.

Physical Description:

1 online resource (784 p.)

Place of Publication:

Amsterdam, Netherlands : Elsevier, 2016.

Summary:

Industrial catalytic processes for fine and specialty chemicals provides a comprehensive methodology and state-of-the art toolbox for industrial catalysis. The book begins by introducing the reader to the interesting, challenging, and important field of catalysis and catalytic processes. The fundamentals of catalysis and catalytic processes are fully covered before delving into the important industrial applications of catalysis and catalytic processes, with an emphasis on green and sustainable technologies. Several case studies illustrate new and sustainable ways of designing catalysts and catalytic processes. The intended audience of the book includes researchers in academia and industry, as well as chemical engineers, process development chemists, and technologists working in chemical industries and industrial research laboratories.

Contents:

Front Cover; Industrial Catalytic Processes for Fine and Specialty Chemicals; Copyright; Contents; Contributors; Notations; Preface; Chapter 1: Catalysis and Catalytic Processes; 1.1. Introduction; 1.2. Catalysts and Catalytic Reactions; 1.2.1. Characteristics of Catalysts; 1.2.2. Homogeneous Catalysts; 1.2.3. Heterogeneous Catalysts; 1.3. Reaction and Reactor Engineering; 1.4. Organization of This Book; References; Part 1: Fundamentals; Chapter 2: Fundamentals of Homogeneous Catalysis; 2.1. Introduction; 2.2. Distinguishing Features of Homogeneous Catalysts

2.3. Basic Concepts in Homogeneous Catalysis2.3.1. Elementary Steps in Homogeneous Catalysis; 2.3.1.1. Oxidative addition; 2.3.1.2. Coordination; 2.3.1.3. Insertion; 2.3.1.4. Reductive elimination; 2.4. Catalytic Cycle; 2.4.1. Hydrogenation of Olefins Using the Wilkinson Catalyst; 2.4.2. Hydroformylation of Propylene Using Co and Rh Complex Catalysts; 2.4.3. Carbonylation of Methanol to Acetic Acid; 2.5. Catalyst Performance; 2.6. Catalyst Deactivation; 2.7. Kinetics and Mechanism; 2.7.1. Classification of Catalysts and Reactions; 2.7.2. Hydrogenation Reactions; 2.7.3. Carbonylation Reactions

2.7.4. Hydroformylation Reactions2.8. Scale-Up and Practical Considerations; 2.9. Conclusions and Future Trends; References; Chapter 3: Heterogeneous Catalysis; 3.1. Introduction; 3.2. Catalytic Steps in Heterogeneous Catalysis; 3.2.1. Diffusion; 3.2.2. Adsorption; 3.2.2.1. Heat of adsorption; 3.2.2.2. Concept of precursor-mediated adsorption; 3.2.2.3. Adsorption isotherms; 3.2.2.3.1. Freundlich adsorption isotherm; 3.2.2.3.2. Langmuir adsorption isotherm; 3.2.2.3.3. Multilayer physisorption isotherms; 3.2.2.3.4. Temkin isotherm; 3.2.2.4. Types of adsorption isotherms

3.2.2.5. Kinetics of adsorption3.2.3. Surface Reactivity: Concept, Kinetics, and Mechanism; 3.2.3.1. Langmuir-Hinshelwood mechanism; 3.2.3.1.1. Rate-determining step approximation; 3.2.3.1.2. Steady state approximation; 3.2.3.2. Eley-Rideal mechanism; 3.2.4. Desorption; 3.3. Definitions; 3.4. Types of Solid Catalysts; 3.4.1. Bulk Catalysts; 3.4.1.1. Zeolites and mesoporous silica; 3.4.1.2. MOFs and COFs; 3.4.1.3. Oxides; 3.4.1.4. Layered compounds; 3.4.1.5. Carbon; 3.4.1.6. Carbides and nitrides; 3.4.2. Supported Catalysts; 3.4.2.1. Immobilized or grafted catalysts

3.4.3. Key Issues in Catalyst Process Scale-Up3.5. Solid Catalysts in Industrial Processes; 3.6. Catalyst Preparation Methodologies; 3.6.1. Conventional Methods; 3.6.1.1. Precipitation and coprecipitation; 3.6.1.2. Fusion and alloy leaching; 3.6.1.3. Sol-gel process; 3.6.1.4. Flame hydrolysis method; 3.6.1.5. Hydrothermal method; 3.6.1.6. Impregnation, ion-exchange, and deposition-precipitation; 3.6.1.7. Grafting; 3.6.2. Advanced Methods; 3.6.2.1. Chemical and physical vapor deposition; 3.6.2.2. Ultrasound methods; 3.6.2.3. Microemulsion method; 3.6.2.4. Mechanochemical synthesis

3.7. Catalyst Characterization Techniques

Notes:

Description based upon print version of record.

Includes bibliographical references at the end of each chapters and index.

Description based on print version record.

ISBN:

9780128016701

0128016701