Asymmetric heterogeneous supported catalysis : use of nitrogen-containing ligands / Christine Saluzzo and Stephane Guillarme.

Format:

Book

Author/Creator:

Saluzzo, Christine.

Contributor:

Guillarme, Stéphane.

Series:

Polymer science and technology series (Nova Science Publishers)

Polymer science and technology

Language:

English

Subjects (All):

Asymmetric synthesis.

Enantioselective catalysis.

Ligands.

Nitrogen compounds.

Physical Description:

1 online resource (185 p.)

Edition:

1st ed.

Place of Publication:

New York : Nova Science Publishers, c2011.

Language Note:

English

Summary:

Homogeneous asymmetric catalysis has been used to perform a variety of transformations under mild conditions with high enantioselectivity. This book discusses the contribution of soluble polymer-supported ligands and insoluble polymer-supported ligands to asymmetric catalysis in the field of reduction.

Contents:

Intro

ASYMMETRIC HETEROGENEOUS SUPPORTED CATALYSIS: USE OF NITROGEN-CONTAINING LIGANDS

Library of Congress Cataloging-in-Publication Data

Contents

Preface

Chapter 1: Introduction

Chapter 2: Reduction of C=O and C=N Bond

2.1. Hydrogenation

2.2. Hydrogenation Transfer Reduction

2.2.1. 1,2-Diamine and Derivatives

2.2.2. Imprinting Technique for Hydrogen Transfer Reduction with 1,2-Diamines

2.2.3. Aminoalcohol as Ligand

2.2.4. Dialdimine Ligand as Ligand

2.3. Enantioselective Hydride Reduction

2.4. Hydrosilylation with Ligands as Pendent Group

2.5. Reduction of C=N bond

Chapter 3: Cyclopropanation

3.1. Oxazolines Ligands

3.1.1. Insoluble Supported-Polymer Box a Ligands

3.1.2. Insoluble Supported-Polymer AzaBOX as Ligands

3.1.3. Insoluble Supported-Polymer PyBox as Ligands

3.1.4. Immobilization of PyBox on Natural Polymers

3.1.5. Soluble Supported-Polymer Box as Ligands

3.1.6. Soluble Supported-Polymer AzaBox as Ligands

3.2. Porphyrins

3.3. Miscellaneous

Chapter 4: Cycloadditions and Heterocycloadditions

4.1. Supported Box Ligands

4.2. Supported Aminoalcohol and N-Sulfonylamino Acid-Derived Oxazaborolidine or Oxazaborolidinone

4.3. Supported Salen as Ligand

Chapter 5: Addition of Organometallic Reagents to Aldehydes, Ketones and Imines

5.1. Supported Aminoalcohols as Ligands

5.2. Supported Sulfonamide

and N-Sulfonylated Aminoalcohols

5.3. Supported Oxazoline

or Oxazolidine as Ligands

5.4. Supported Salen as Chiral Ligands

Chapter 6: Asymmetric (-Allylic Substitution

Chapter 7: Dihydroxylation and Aminohydroxylation

7.1. Insoluble Supported Alkaloid as Ligand

7.2. Soluble Supported Alkaloid as Ligand

Chapter 8: Epoxidation

8.1. Supported Salen as Ligand

8.2. Porphyrins

8.3. Soluble Polymers.

Chapter 9: Kinetic Resolution of Terminal Epoxides

Chapter 10: Miscellaneous

Chapter 11: Conclusion

References

Index.

Notes:

Description based upon print version of record.

Includes bibliographical references and index.

Description based on print version record and CIP data provided by publisher.

ISBN:

1-61728-101-8

OCLC:

923669073