Palladium : compounds, production and applications / Kenneth M. Brady, editor.

Format:

Book

Contributor:

Brady, Kenneth M.

Series:

Materials science and technologies series.

Materials science and technologies

Language:

English

Subjects (All):

Palladium compounds--Industrial applications.

Palladium compounds.

Palladium--Metallurgy.

Palladium.

Physical Description:

1 online resource (370 p.)

Edition:

1st ed.

Place of Publication:

New York : Nova Science Publishers, c2011.

Language Note:

English

Summary:

Palladium is a chemical element with the chemical symbol Pd Palladium is also a rare and lustrous silvery-white metal. The unique properties of palladium and other platinum group metals account for their widespread use. This book presents topical research data from across the globe in the study of palladium and its production and applications.

Contents:

Intro

PALLADIUM: COMPOUNDS, PRODUCTION AND APPLICATIONS

CONTENTS

PREFACE

Chapter 1 SHAPE-CONTROLLED SYNTHESIS OF PALLADIUM NANOPARTICLES: MECHANISM OF FORMATION AND APPLICATIONS

ABSTRACT

I. INTRODUCTION

II. COLLOIDAL SYNTHESIS TECHNIQUES

III. NUCLEATION AND GROWTH OF NANOCRYSTALS

III.1. The Artificial Division between Seeds and Nuclei

III.2. Concept of Nucleation

III.2.1. Homogeneous Nucleation

III.2.2. Heterogeneous Nucleation

III.3. Role of Twinned Defects

III.4. Thermodynamic Versus Kinetic Growth Regime

III.5. Oxidative Etching

III.6. Surface Capping Agents: Thermodynamic Stabilization of Facets and Complexation Role

III.7. Role of Foreign Ions

III.8. Oriented Attachment Mechanism

III.9. Conclusion

IV. TYPES OF MORPHOLOGIES: SYNTHESIS STRATEGIES

IV.1. Single Crystalline Pd Nanocrystals

IV.1.1. Cubes - Nanobars

IV.1.2. Cubooctahedra

IV.1.3. Tetrahedra

IV.1.4. Octahedra

IV.1.5. Single Crystalline Nanorods

IV.1.6. Nanoboxes - Nanocages

IV.2. Single Twinned Nanoparticles

IV.2.1. Triangular and Hexagonal Nanoplates

IV.2.2. Bipyramidal Nanoparticles

IV.2.3. Single Twinned Nanorods or Nanodisks

IV.3. Multiply-Twinned Nanoparticles

IV.3.1. Decahedra

IV.3.2. Fivefold Twinned Nanorods

IV.3.3. Multiply-Twinned Icosahedra

IV.4. Complex Pd Morphologies

IV.4.1. Kinetic Control and the Formation of Multipods and Nanodendritic Structures

IV.4.2. Other Complex Morphologies

V. APPLICATIONS

V.1. Applications Based on the SERS Effect

V.2. Catalytic and Electrocatalytic Applications

V.2.1. Catalytic Applications

V.2.2. Electrocatalytic Applications

CONCLUSION

REFERENCES

Chapter 2 PALLADIUM IN GAS-PHASE PROCESSES OF ENVIRONMENTAL CATALYSIS

INTRODUCTION.

CARBON MONOXIDE OXIDATION ON MODEL PALLADIUM-CONTAINING CATALYSTS

FEATURES OF THE RED-OX INTERACTIONS (СO, Н2, СNHM, О2, NOX) ON PALLADIUM CATALYSTS

PALLADIUM IN COMPOSITION OF NANOPHASE STRUCTURED CATALYSTS FOR HIGH-TEMPERATURE NITROGEN OXIDES REDUCTION BY METHANE

STRUCTURAL-FUNCTIONAL DESIGN OF THE PALLADIUM-CONTAINING CATALYSTS FOR CONTROL OF INTERNAL COMBUSTION ENGINES EMISSIONS

PALLADIUM AS CO-CATALYST IN THE COMPOSITION OF STRUCTURED OXIDE COMPOSITES

SULFUR RESISTANCE OF PALLADIUM-CONTAINING CATALYSTS IN THE PROCESSES OF CARBON MONOXIDE AND METHANE OXIDATION

Effect of Sulfur Dioxide on Carbon Monoxide Oxidation over Pd-Containing Catalysts

Tolerance to Sulfur Compounds of Anodic Materials of SOFCs with Direct Oxidation of Hydrocarbon Fuels

Chapter 3 PALLADIUM COMPLEXES OF N-HETEROCYCLIC CARBENES IN HOMOGENEOUS CATALYSIS AND BIOMEDICAL APPLICATIONS

INTRODUCTION

Palladium(0) N-Heterocyclic Carbene Complexes

Palladium(II) N-Heterocyclic Carbene Complexes

Palladium(IV) N-Heterocyclic Carbene Complexes

C−C Bond Forming Reactions

Suzuki-Miyaura Cross-Coupling Reaction

Heck−Mizoroki Reaction

Stille Cross-Coupling Reaction

Kumada-Tamao-Corriu (KTC) Cross-Coupling Reaction

Negishi Cross-Coupling Reaction

Hiyama Cross-Coupling Reaction

Sonogashira Cross-Coupling Reactions

Arylation Reaction

(I). Arylation of Enolates

(II). Direct Arylation Reactions

Hydroarylation Reactions

C−N Bond Formation Reaction

Buchwald−Hartwig Amination Reaction

Hydroamination Reaction

Oxidation Reaction

(i). Oxidation of Alcohols

(II). Wacker Oxidation and Oxidative Cyclization Reactions

Reduction Reaction

Tsuji-Trost Alkylation Reaction

Telomerization Reactions

(I). Telomerization of Dienes with Alcohols.

(ii). Telomerization of Dienes with Amines

Polymerization Reactions

Cycloisomerization Reactions

Addition Reactions

Domino Reactions

Palladium in Biomedical Application

CONCLUSIONS

Chapter 4 SUPPORTED PD NANOPARTICLES: METHODS AND APPLICATIONS

1. INTRODUCTION

2. NATURE OF SUPPORTS: POROUS/NON POROUS MATERIALS

2.1. Porous Materials

2.1.1. Carbonaceous Materials

2.1.2. (Bio)Polymers

2.1.3. Metal Oxides

2.2. Non Porous Materials

3. SUPPORTED PD NANOPARTICLES PREPARATION ROUTES

3.1. Physical Routes

3.1.1. Sonochemistry

3.1.2. Microwave Irradiation (MWI)

3.1.3. Pulsed Laser Ablation (PLA)

3.1.4. Supercritical Fluids (SCF)

3.1.5. Plasma

3.1.6. Other Physical Routes

3.2. Chemical Routes

3.2.1. Traditional Methods

3.2.1.1. Impregnation

3.2.1.2.Grafting

3.2.1.3.Co-Precipitation

3.2.2. Novel Methods

3.2.2.1. Microemulsions

3.2.2.2. Photochemistry

3.2.2.3. Chemical Vapor Deposition (CVD)

3.2.2.4. 'In Situ' Incorporation of Palladium Nanoparticles

3.2.3. Other Chemical Methods

3.3. Physico-Chemical Routes

3.3.1. Sonoelectrochemistry

3.3.2. Flame Spray Pyrolysis

4. CATALYTIC APPLICATIONS OF SUPPORTED PD NANOPARTICLES

5. FUTURE PROSPECTS AND OUTLOOK

5.1. Sustainable Preparation of Pd SNP

5.2. Sustainable and Future Catalytic Applications

ACKNOWLEDGMENTS

Chapter 5 APPLICATION OF PALLADIUM IN OHMIC CONTACTS TO GAAS

2. EXPERIMENTAL

3. SURFACE CLEANING OF GAAS SUBSTRATES

4. THICKNESS OPTIMIZATION OF PD AND GE LAYERS IN GE/PD/GAAS CONTACT STRUCTURE

5. VERIFICATION OF SOLID PHASE REGROWTH MECHANISM

6. ROLE OF REACTIVE METALS IN THE GEPD METALLIZATION

7. APPLICATION OF INDIUM IN PDGE METALLIZATION.

8. ROLE OF SELENIUM IN PDGE METALLIZATION

9. THERMAL STABILITY OF PDGE OHMIC CONTACTS

10. APPLICATION OF PDGE OHMIC CONTACTS IN UHF SCHOTTKY DIODES

ACKNOWLEDGMENT

Chapter 6 PALLADIUM COMPLEXES WITH POTENTIAL PHARMACOLOGICAL ACTIVITIES

2. PALLADIUM(II) COMPLEXES BEARING NITROGEN OR PHOSPHINE DONOR LIGANDS

2.1. Antitumor Activity

Other Biological Activities

3. PALLADIUM(II) COMPLEXES BEARING NITROGEN AND SULFUR/OXYGEN MIXED DONOR LIGANDS

3.1. Antitumor Activity

3.2. Other Biological Activities

Chapter 7 PALLADIUM NANOSTRUCTURE FOR FUEL CELL SYSTEM

2. PD-CARBON NANOSTRUCTURE AND CHARACTERIZATION

3. APPLICATION AND MEASUREMENT OF PD-CARBON NANOSTRUCTURE IN FUEL CELL SYSTEM

Chapter 8 THE APPLICATION OF SUPPORTED PALLADIUM CATALYSTS IN CO- AND TERPOLYMERIZATION REACTIONS OF CARBON MONOXIDE AND OLEFINS

RESULTS AND DISCUSSION

The Supported Catalyst Investigation

Reactions of CO/C2H4 Copolymerization and CO/C2H4/C3H6 Terpolymerization in the Presence of Supported Catalysts

The Characterization of the Terpolymer by Means of IR and 13C NMR Spectroscopy

Chapter 9 PORPHYRIN PALLADIUM (II) COMPLEXES STABLE INTERMEDIATES IN SOME REDOX AND CATALYTIC REACTIONS

EXPERIMENTAL

Materials

Spectroscopic and Kinetic Measurements

RESULTS

Kinetics of Oxidation Reactions of Palladium (II) Porphyrins by Aerated Sulfuric Acid

Alkaline Decomposition of Hydrogen Peroxide in a Water-Dimethylformamide Medium Catalyzed by Palladium (II) Porphyrines

REFERENCES.

Chapter 10 COMPOSITE PALLADIUM MEMBRANES WITH IMPROVED DURABILITY TOWARD HYDROGEN EMBRITTLEMENT*

Pd and Ag Alloy Membranes

Simultaneous Plating of Palladium and Silver

Hydrogen Permeation of the Pd-Ag Alloy Membranes

"Pore-Fill" Type Palladium Membranes

Fabrication of "Pore-Fill" Type Membranes

Chapter 11 SELECTIVITY ON THE COORDINATION SITE AND THE BONDING MODE OF PHOSPHORUS YLIDES TOWARDS PALLADIUM AND PLATINUM SUBSTRATES*

REACTIVITY OF P-YLIDES WITH (8-QUINOLYLMETHYL-C,N)PALLADIUM

REACTIVITY OF P-YLIDES WITH (2-PHENYLPYRIDINATE-C,N)

REACTIVITY OF P-YLIDES WITH PINCER COMPLEXES

EXPERIMENTAL SECTION

Safety Note

General Methods

Synthesis of the Starting Compounds

Synthesis of [Pd(phpy)(NCMe)2]ClO4 (4)

Synthesis of the Ylide Complexes

INDEX

Blank Page.

Notes:

Description based upon print version of record.

Includes bibliographical references and index.

Description based on print version record.

ISBN:

1-61122-084-X

OCLC:

726744608