Lithium batteries : research, technology and applications / Greger R. Dahlin and Kalle E. Strom, editors.

Format:

Book

Contributor:

Dahlin, Greger R.

Strøm, Kalle E.

Series:

Electrical engineering developments series.

Electrical engineering developments

Language:

English

Subjects (All):

Lithium cells.

Physical Description:

1 online resource (240 p.)

Edition:

1st ed.

Place of Publication:

New York : Nova Science Publishers, c2010.

Language Note:

English

Summary:

Deals with the developments in and research of LiFePo4 cathode materials with an emphasis on the synthesis method and how to improve electrochemical performance. This book reviews the efforts made to develop other inorganic cathode materials for lithium ion batteries. It discusses the safety of lithium-ion battery packs.

Contents:

Intro

LITHIUM BATTERIES: RESEARCH, TECHNOLOGY AND APPLICATIONS

CONTENTS

PREFACE

Chapter 1 LIFEPO4 CATHODE MATERIALS FOR LITHIUM-ION BATTERIES

1. INTRODUCTION

2. SYNTHESIS METHOD OF LIFEPO4 CATHODE MATERIALS

2.1. Solid-State Reaction

2.2. Hydrothermal Method

2.3. Co-Precipitation

2.4. Emulsion-Drying Method

2.5. Sol-Gel Method

2.6. Mechanical Alloying

2.7. Microwave Processing

2.8. Other Synthesis Methods

3. HOW TO IMPROVE ELECTROCHEMICAL PERFORMANCE OF LIFEPO4 CATHODE MATERIALS

3.1. Effect of Particle Size and Morphology on Electrochemical Performance of LiFePO4

3.2. Substitution of Li+ or Fe2+ with Cations

3.3. Effect of Carbon Coating and Metal or Metal Oxide Mixing on Charge/Discharge Performance of LiFePO4

4. SUMMARY AND FUTURE PROSPECT

5. ACKNOWLEDGMENTS

REFERENCES

Chapter 2 INORGANIC CATHODE MATERIALS FOR LITHIUM ION BATTERIES

2. LAYERED LITHIUM METAL OXIDES

2.1 Introduction

2.2 LiNiO2

2.2.1 Problems with LiNiO2

2.2.2 Synthesis of stoichiometric LiNiO2-based materials

2.2.3 Structural stability of delithiated LiNiO2-based materials

2.2.4 Thermal stability of delithiated LiNiO2-based materials

2.3 LiMnO2

2.3.1 Challenges of LiMnO2

2.3.2 Development of monoclinic LiMnO2 cathode materials

2.3.3 Development of orthorhombic LiMnO2 cathode materials

2.4 Mixed Transition Metal Dioxides

3 SPINEL LITHIUM MANGANESE OXIDES

3.1 Introduction

3.2 LiMn2O4

3.2.1 Problems with LiMn2O4

3.2.2 Modification of LiMn2O4

4 OLIVINE LITHIUM METAL PHOSPHATES

4.1 Introduction

4.2 LiFePO4

4.2.1 Problems with LiFePO4

4.2.2 Synthesis methods for LiFePO4

4.2.3 Electrochemical performance upgrading of LiFePO4

4.3 LiMPO4 (M = Mn, Co, Ni)

5 CONCLUSION.

REFERENCES

Chapter 3 ANALYSIS OF CELL IMPEDANCE FOR THE DESIGNOF A HIGH-POWER LITHIUM-ION BATTERY

ABSTRACT

I. INTRODUCTION

II. OVERVIEW OF HIGH POWER CELL DESIGN

III. TIME-DEPENDENT CONTRIBUTION OF REACTION STEPS TO TOTAL POLARIZATION

1. Overview of the Approach

2. Model Case: Analysis on Hypothetical Electrode in LIB

IV. IN-DEPTH DIAGNOSIS OF THE BATTERY WITH DEGRADED POWER

1. Cell Configuration and Electrochemical Test Procedures

2. Analysis Based on a Two-Electrode Electrochemical Cell and its Limitation

3. Analysis Based on a Three-Electrode Electrochemical Cell

V. CRITICAL FACTORS FOR LOW-TEMPERATURE POWER DECLINE

1. Brief Description of Electrochemical Test Procedures

2. Effect of Temperature on Total and Elementary Polarizations

3. Power Performance of Hybrid Electrodes

VI. CONCLUSION

ACKNOWLEDGMENTS

Chapter 4 CHEMICAL OVERCHARGE PROTECTION OF LITHIUM-ION CELLS

INTRODUCTION

COMPARISON OF AVAILABLE TECHNOLOGIES

HISTORICAL REVIEW

STABILITY OF REDOX SHUTTLES

Electronic Stability

Structural Stability

EXAMPLES OF STABLE REDOX SHUTTLES

Aromatic Redox Shuttles

Non-Aromatic Redox Shuttles

CONCLUSION

ACKNOWLEDGMENT

Chapter 5 THERMAL STABILITY AND ELECTROCHEMICAL PERFORMANCE OF LICOO2 AND LICO0.2NI0.8O2 IN LITHIUM-ION BATTERIES

2. MEASUREMENT OF THERMAL STABILITY

2.1. Differential Scanning Calorimetry

2.2. Accelerating Rate Calorimetry

3. HAZARD TRIGGERS

3.1. Temperature Coefficient of Cell Voltage

3.2. Cell Design

3.3. Electrolyte

3.4. Active Materials

4. LICOO2

4.1. Coated LiCoO2 Cathodes

5. LICO0.2NI0.8O2

5.1. Substituted LiNiyCo1-yO2 Compositions

5.2. Coated LiNiyCo1-yO2 Compositions

6. CONCLUSIONS

REFERENCES.

Chapter 6 COMPOSITIONAL AND STRUCTURAL EVOLUTION OF CATHODE PARTICLES OF THE CYCLED LITHIUM BATTERIES INVESTIGATED BY ANALYTICAL HIGH RESOLUTION TRANSMISSION ELECTRON MICROSCOPY(AHRTEM)

1.1 The Cathode of Lithium Battery is the Li+ Source and Sinks

1.2 The Compositional and Structural Feature of Surface of a Cathode Particle

1.3 Fundamental Structural and Compositional Relationships between the NaFeO2 and LiMO2 (M=Co,Ni,Mn)

1.4 Analytical High Resolution Transmission Electron Microscopy (AHRTEM) is a Powerful Tool for Revealing Composition and Structure Variation of the Cathode Particles of a Cycled Lithium Battery at Atomic Scale

2. BASIC EXPERIMENT TECHNIQUES

2.1 Preparation of the Cycled Cathode Particles for AHRTEM

2.2 Micro-Diffraction and Micro-Analysis of the Cycled Cathode Particles

2.3 One- and Two- Dimension Lattices Images and Analysis

3. COMPOSITIONAL AND STRUCTURAL EVOLUTION OF THE CATHODE CYCLED PARTICLES OF THE LITHIUM BATTERIES

3.1 LiCoO2

3.2 LiNi1/3Co1/3Mn1/3O2

3.3 LiNi0.8Co0.2O2

4. DISCUSSION AND CONCLUSION

Chapter 7 SOFT SOLUTION PROCESSING OF NANOSCALED LITHIUM VANADIUM OXIDES AS CATHODE MATERIALS FOR RECHARGEABLE LITHIUM ION BATTERIES

LI1+XV3O8

Introduction

Experimental Section

Synthesis and characterization of LiV3O8

Electrochemical measurements

Results and Discussion

TGA result

The XRD and the Structure of LiV3O8

The morphology of the as-synthesized LiV3O8

FTIR of the as-synthesized LiV3O8

Electrochemical properties of the as-synthesized LiV3O8

-LIV2O5

Synthesis and characterization of -LiV2O5

Results and Discussion.

The XRD results and the kinetic processing of the formation of -LiV2O5

FTIR of the as-synthesized -LiV2O5

XPS of the as-synthesized -LiV2O5

The morphologies of the as-synthesized -LiV2O5

Electrochemical properties of the as-synthesized -LiV2O5

REFERENCE

Chapter 8 ADVANCED LITHIUM-ION BATTERIES FOR PLUG-IN HYBRID-ELECTRIC VEHICLES

2. STATUS OF ADVANCED BATTERY DEVELOPMENT

3. SPINEL-TITANATE BATTERY PERFORMANCE MODELING

3.1 Approach

3.2 Experimental Data

3.3 Battery Design Modeling

3.4 Impedance Modeling

4. VEHICLE SIMULATION FOR HIGH-POWER BATTERIES

4.1 Approach

4.2 Vehicle Characteristics

4.3 Component Sizing Algorithm

4.4 Control Strategy Philosophy

4.5 Fuel Economy Results

(1) Engine started during the first cycle

5. CONCLUSIONS

6. ACKNOWLEDGMENTS

7. REFERENCES

INDEX

Blank Page.

Notes:

Description based upon print version of record.

Includes bibliographical references and index.

Description based on print version record.

ISBN:

1-61668-517-4

OCLC:

923662354