Kinetics and thermodynamics of multistep nucleation and self-assembly in nanoscale materials / edited by Gregoire Nicolis and Dominique Maes.

Format:

Book

Contributor:

Nicolis, Gregoire.

Maes, Dominique.

Series:

Advances in chemical physics ; v. 151.

Advances in chemical physics ; v. 151

Language:

English

Subjects (All):

Nucleation.

Dynamics.

Thermodynamics.

Physical Description:

1 online resource (353 p.)

Edition:

1st ed.

Place of Publication:

Hoboken, N.J. : John Wiley & Sons, 2012.

Language Note:

English

Summary:

The Advances in Chemical Physics series-the cutting edge of research in chemical physics The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series presents contributions from internationally renowned chemists and serves as the perfect supplement to any advanced graduate class de

Contents:

Kinetics and Thermodynamics of Multistep Nucleation and Self-Assembly in Nanoscale Materials: Advances in Chemical Physics Volume 151; CONTRIBUTORS; PREFACE; PREFACE TO THE SERIES; CONTENTS; KINETICS AND THERMODYNAMICS OF FLUCTUATION-INDUCED TRANSITIONS IN MULTISTABLE SYSTEMS; I. INTRODUCTION; II. FORMULATION; A. Stationary Distribution; B. Exit from an Attraction Basin; III. CLOSED SYSTEMS AND DETAILED BALANCE; IV. GENERIC POTENTIALS AND THEIR UNFOLDINGS; A. Transitions from 1 to 3 Occur Necessarily Through State 2; B. Transitions from 1 to 3 Need Not Occur Through State 2

V. KINETICS OF TRANSITIONS BETWEEN STATES: MAPPING INTO A DISCRETE MARKOV PROCESSA. Three Simultaneously Stable States (Seven-Steady-State Region); B. Two Simultaneously Stable States (Five-Steady-State Region); C. Two Simultaneously Stable States (Three-Steady-State Region); VI. IRREVERSIBLE THERMODYNAMICS OF FLUCTUATION-INDUCED TRANSITIONS; VII. CONCLUSIONS; ACKNOWLEDGMENTS; REFERENCES; DYNAMICAL RARE EVENT SIMULATION TECHNIQUES FOR EQUILIBRIUM AND NONEQUILIBRIUM SYSTEMS; I. INTRODUCTION; II. REACTIVE FLUX METHOD; III. TRANSITION PATH SAMPLING; IV. TRANSITION INTERFACE SAMPLING

V. PARTIAL PATH SAMPLINGVI. FORWARD FLUX SAMPLING; VII. REPLICA EXCHANGE TIS; VIII. NUMERICAL EXAMPLE; IX. CONCLUSIONS; ACKNOWLEDGMENTS; REFERENCES; CONFOCAL DEPOLARIZED DYNAMIC LIGHT SCATTERING; I. INTRODUCTION; II. FUNDAMENTALS OF DEPOLARIZED SCATTERING: THE STATE OF THE ART; III. THE TRADITIONAL APPROACH; IV. THE NOVEL APPROACH; V. THE OPTICAL LAYOUT; VI. DATA REDUCTION SCHEME; VII. RESULTS; VIII. CONCLUSIONS; ACKNOWLEDGMENT; REFERENCES; THE TWO-STEP MECHANISM AND THE SOLUTION-CRYSTAL SPINODAL FOR NUCLEATION OF CRYSTALS IN SOLUTION; I. INTRODUCTION; II. THE CLASSICAL NUCLEATION THEORY

A. The Crystallization Driving ForceB. The Thermodynamic Theory of J.W. Gibbs; C. The Rate of Crystal Nucleation; III. THE TWO-STEP MECHANISM AND THE SOLUTION-CRYSTAL SPINODAL; A. Experimental Data on the Rate of Nucleation of Crystals; B. The Nucleus Size and Solution-to-Crystal Spinodal; C. The Classical Theory Overestimates the Crystal Nucleation Rate by 10 Orders of Magnitude; D. The Two-Step Mechanism of Nucleation of Crystal in Solution; E. Dense Liquid Clusters; F. The Rate Law for the Two-Step Mechanism of Crystal Nucleation

G. The Rate-determining Step in the Two-Step Nucleation MechanismH. The Role of Heterogeneous Nucleation Substrates; I. The Broad Applicability of the Two-Step Nucleation Mechanism; IV. SUMMARY AND CONCLUSIONS; ACKNOWLEDGMENTS; REFERENCES; EXPERIMENTAL STUDIES OF TWO-STEP NUCLEATION DURING TWO-DIMENSIONAL CRYSTALLIZATION OF COLLOIDAL PARTICLES WITH SHORT-RANGE ATTRACTION; I. INTRODUCTION; II. EXPERIMENTAL METHODS: SAMPLE PREPARATION AND IMAGING; III. ANALYSIS OF IMAGES: PARTICLE COORDINATES, AREA FRACTION, CLUSTER SIZES, AND CRYSTALLINE ORDER; IV. RESULTS

A. Single-Step and Two-Step Nucleation of Crystallites

Notes:

Description based upon print version of record.

Includes bibliographical references and indexes.

ISBN:

9786613619327

9781280589492

1280589493

9781118309483

1118309480

9781118309513

1118309510

9781118309476

1118309472

OCLC:

787842608