Phase modeling tools : applications to gases / Michel Soustelle.

Format:

Book

Author/Creator:

Soustelle, Michel, author.

Series:

Chemical thermodynamics set ; Volume 1.

Chemical Thermodynamics Set ; Volume 1

Language:

English

Subjects (All):

Thermodynamics.

Chemical reactions.

Physical Description:

1 online resource (301 p.)

Edition:

1st ed.

Place of Publication:

London, England ; Hoboken, New Jersey : ISTE : Wiley, 2015.

Summary:

This book is part of a set of books which offers advanced students successive characterization tool phases, the study of all types of phase (liquid, gas and solid, pure or multi-component), process engineering, chemical and electrochemical equilibria, and the properties of surfaces and phases of small sizes. Macroscopic and microscopic models are in turn covered with a constant correlation between the two scales. Particular attention has been given to the rigor of mathematical developments.

Contents:

Cover; Title Page; Copyright; Contents; Preface; Notations; Symbols; 1: Thermodynamic Functions and Variables; 1.1. State variables and characteristic functions of a phase; 1.1.1. Intensive and extensive conjugate variables; 1.1.2. Variations in internal energy during a transformation; 1.1.3. Characteristic function associated with a canonical set of variables; 1.2. Partial molar parameters; 1.2.1. Definition; 1.2.2. Properties of partial molar variables; 1.3. Chemical potential and generalized chemical potentials; 1.3.1. Chemical potential and partial molar free enthalpy

1.3.2. Definition of generalized chemical potential1.3.3. Variations in the chemical potential and generalized chemical potential with variables; 1.3.3.1. Variations with intensive variables; 1.3.3.2. Variations with composition; 1.3.3.3. Total differential; 1.3.4. Gibbs-Duhem relation; 1.3.5. Generalized Helmholtz relations; 1.3.6. Chemical system associated with the general system; 1.4. The two modeling scales; 2: Macroscopic Modeling of a Phase; 2.1. Thermodynamic coefficients and characteristic matrices

2.1.1. Thermodynamic coefficients and characteristic matrix associated with the internal energy2.1.2. Symmetry of the characteristic matrix; 2.1.3. The thermodynamic coefficients needed and required to thermodynamically define the phase; 2.1.4. Choosing other variables: thermodynamic coefficients and characteristic matrix associated with a characteristic function; 2.1.5. Change in variable from one characteristic matrix to another; 2.1.6. Relations between thermodynamic coefficients and secondary derivatives of the characteristic function

2.1.7. Examples of thermodynamic coefficients: calorimetric coefficients2.2. Partial molar variables and thermodynamic coefficients; 2.3. Common variables and thermodynamic coefficients; 2.3.1. State equation; 2.3.2. Expansion coefficients; 2.3.2.1. Cubic expansion coefficient (or coefficient of relative increase in volume); 2.3.2.2. Coefficient of pressure increase at a constant volume; 2.3.2.3. Isothermal compressibility coefficient at constant temperature T; 2.3.2.4. Linear expansion coefficient; 2.3.3. Molar heat capacities; 2.3.4. Young's Modulus; 2.3.5. Electric permittivity

2.3.6. Volumic and area densities of electric charge2.4. Thermodynamic charts: justification of different types; 2.4.1. Representation of a variable as a function of its conjugate; 2.4.2. Representation of a characteristic function as a function of one of its natural variables; 2.5. Stability of phases; 2.5.1. Case of ensemble E0 of extensive variables; 2.5.2. Coefficients associated with ensemble En; 2.5.3. Case of other ensembles of variables; 2.5.4. Conclusion: stability conditions of a phase in terms of thermodynamic coefficients; 2.5.5. Example - applying stability conditions

2.6. Consistency of thermodynamic data

Notes:

Description based upon print version of record.

Includes bibliographical references and index.

Description based on online resource; title from PDF title page (ebrary, viewed November 9, 2015).

ISBN:

9781119178477

1119178479

9781119178460

1119178460

9781119178453

1119178452

OCLC:

917551854