Dyes and chromophores in polymer science / edited by Jacques Lalevée, Jean-Pierre Fouassier.

Format:

Book

Contributor:

Lalevée, Jacques, editor.

Fouassier, Jean-Pierre, editor.

Series:

Materials science series (London, England)

Materials Science Series

Language:

English

Subjects (All):

Nanoscience.

Nanotechnology.

Physical Description:

1 online resource (377 p.)

Edition:

1st ed.

Place of Publication:

London, England ; Hoboken, New Jersey : ISTE : Wiley, 2015.

Language Note:

English

Summary:

The design and development of dyes and chromophores have recently attracted much attention in various research fields such as materials, radiation curing, (laser) imaging, optics, medicine, microelectronics, nanotechnology, etc.. In this book, the recent research for the use of dyes and chromophores in polymer science is presented. The interaction of the visible light with the dyes or the selected chromophores is particularly important in different fields (e.g. for photovoltaic, display applications (LED...), laser imaging or laser direct writing, green chemistry with sunlight induced photopolymerization etc...). This book gives an overview of the dyes and chromophores for all the important fields.

Contents:

Cover

Title Page

Copyright

Contents

Preface

1: Trends in Dye Photosensitized Radical Polymerization Reactions

1.1. Introduction

1.2. A brief overview of dye-based PISs

1.2.1. Dye one-component systems

1.2.2. Dye two-component systems

1.2.3. Dye three-component systems

1.3. A discussion on specific or recent developments in dye-based photoinitiating systems

1.3.1. Dyes for use with polychromatic visible lights

1.3.2. Dyes for blue, green and red laser light-induced polymerizations

1.3.3. Dyes as part of PISs in the medical area

1.3.4. Dyes in controlled radical photopolymerization reactions

1.3.5. Photoinitiation under soft irradiation conditions: novel three-componentsystems

1.3.6. Dyes with red-shifted absorptions and high molar extinction coefficients

1.3.7. Performances of novel three-component PISs in low-viscosity matrices under LEDs/laser diodes and low-intensity household devices

1.3.8. Recoverable dyes: the concept of photoinitiator catalysts

1.3.9. Metal-based dyes: recent perspectives

1.3.10. Dyes under sunlight exposure

1.3.11. Dye-based PISs as a source of mediator radicals: application to FRPCP

1.3.12. Dyes exhibiting a dual radical/cationic behavior: application to concomitant radical/cationic photopolymerizations

1.3.13. Dyes in thiol-ene photopolymerizations

1.3.14. Dyes for the manufacture of photopolymerizable panchromatic films

1.3.15. Dyes for polymerization of in situ nanoparticle containing films

1.4. Dye-based photoinitiating systems: properties, efficiency and reactivity

1.5. Trends and perspectives

1.6. Bibliography

2: Sensitization of Cationic Photopolymerizations

2.1. Introduction

2.2. Photosensitization of onium salts

2.3. Synthesis of long wavelength absorbing photoinitiators.

2.4. Photosensitization of onium salt cationic photoinitiators

2.5. Early dye sensitization studies

2.6. Polynuclear aromatic hydrocarbons and their derivatives

2.7. Phenothiazine photosensitizers

2.8. Carbazole photosensitizers

2.9. Thioxanthone photosensitizers

2.10. Curcumin as a photosensitizer

2.11. Quinoxaline photosensitizers

2.12. Miscellaneous electron-transfer photosensitizers

2.13. Free-radical-promoted photosensitization

2.14. Conclusions

2.15. Bibliography

3: Controlled Photopolymerization and Novel Architectures

3.1. Introduction

3.2. Photoinitiated controlled radical polymerizations

3.2.1. Photoiniferter

3.2.2. Photoinitiated nitroxide-mediated radical polymerization

3.2.3. Photoinitiated atom transfer radical polymerization

3.2.4. Photoinitiated RAFT polymerization

3.3. Photoinitiated living ionic polymerization

3.3.1. Living cationic photopolymerization

3.3.2. Living anionic photopolymerization

3.4. Acknowledgments

3.5. Bibliography

4: Applied Photochemistry in Dental Materials: From Beginnings to State of the Art

4.1. Photoinitiated free radical polymerization

4.1.1. Introduction: from ultraviolet to visible light curing

4.1.2. The camphorquinone/amine system

4.1.3. Acyl phosphine oxides

4.1.4. Various other photoinitiator systems

4.2. Cationic photopolymerization

4.3. Conclusion

4.4. Bibliography

5: Photoinitiated Cross-linking in OLEDs: An Efficient Tool for Addressing the Solution-Processed Devices Elaboration and Stability Issues

5.1. Introduction

5.2. Cross-linking of light-emitting materials

5.2.1. Polymer-based light-emitting materials

5.2.1.1. Conjugated polymers

5.2.1.2. Non-conjugated polymers

5.2.2. Small-molecule-based light-emitting materials

5.3. Cross-linking of charge-transport materials.

5.3.1. Polymer-based hole-transport materials

5.3.2. Polymer-based electron-transport/injection materials

5.3.3. Small-molecule-based hole-transport materials

5.4. Conclusion

5.5. Bibliography

6: Polymers as Light-Harvesting Dyes in Dye-Sensitized Solar Cells

6.1. Introduction

6.2. Characterization of DSSC devices

6.3. Poly(3-thiophenylacetic acid)-based polymers

6.4. Phenylenevinylene-based polymers

6.5. Triphenylamine-based polymer

6.6. Fluorene-based polymers

6.7. Dye polymers with acceptor-donor structure

6.8. Polymer containing metal complexes

6.9. Conclusion

6.10. Bibliography

7: NIR-Dyes for Photopolymers and Laser Drying in the Graphic Industry

7.1. Introduction

7.2. Computer to plate systems

7.2.1. Technical remarks

7.2.2. Photochemical aspects of photoinitiation using NIR lasers

7.2.3. Importance of thermal deactivation

7.2.4. Contrast materials and color on demand

7.2.5. Sensitivity

7.3. Laser-drying and offset-printing

7.3.1. Principle of laser-drying

7.3.2. Chemical systems

7.4. Conclusions and outlook

7.5. Acknowledgments

7.6. Bibliography

8: Dyes and Photopolymers

8.1. Photopolymer

8.2. Dye study of the photopolymer materials

8.3. Conclusion

8.4. Bibliography

9: Advanced Strategies for Spatially Resolved Surface Design via Photochemical Methods

9.1. Introduction

9.2. Inorganic surfaces

9.3. Bio and bioinspired surfaces

9.4. Cross-linking

9.5. Conclusion

9.6. Bibliography

10: Photosynthesized High-Performance Biomaterials

10.1. Introduction

10.2. Surface photografting methodology

10.2.1. Photoinduced "grafting-from" method

10.2.2. Benzophenone and derivatives

10.2.3. Ketones and derivatives

10.2.4. Photo-oxidation process

10.2.5. Photoiniferters for living/controlled surface photografting.

10.2.6. Triarylsulfonium salts

10.3. Photoinduced "grafting-to" procedure

10.3.1. Aryl azides chemistry

10.3.2. Anthraquinone-derived monomers

10.4. Achievements and biomedical applications of the photosynthesized materials

10.4.1. Achievements

10.4.1.1. Wettability

10.4.2. Stimuli-responsive materials

10.4.3. Modification of membranes

10.4.4. Biomedical applications

10.4.4.1. Antibacterial properties

10.4.5. Enzymes and proteins immobilization

10.4.6. Cell adhesion and compatibility

10.5. Conclusion

10.6. Bibliography

11: Light-cured Luminescent Coatings for Photovoltaic Devices

11.1. Photovoltaics: technology, devices and spectral management

11.1.1. Energy demand and photovoltaic converters

11.1.2. Spectral management for photovoltaics: principles, materials and applications

11.2. Photocurable luminescent downshifting layers and dye-sensitized solar cells

11.3. Luminescent solar concentrators

11.4. Bibliography

12: Polymers with Photoinduced Self-healing Properties

12.1. Introduction

12.2. Healing based on photo-reversible cycloadditions

12.3. Healing based on photoinduced homolytic dissociations of covalent bonds

12.4. Photoinduced healing in supramolecular polymers and related systems

12.5. Healing based on photothermally induced phase transitions or photo-isomerizations

12.6. Conclusion and perspectives

12.7. Bibliography

List of Authors

Index.

Notes:

Description based upon print version of record.

Includes bibliographical references at the end of each chapters and index.

Description based on online resource; title from PDF title page (ebrary, viewed May 12, 2015).

ISBN:

9781119006688

1119006686

9781119006879

1119006872

OCLC:

908670319