The organometallic chemistry of the transition metals / Robert H. Crabtree.

Format:

Book

Author/Creator:

Crabtree, Robert H., 1948- author.

Language:

English

Subjects (All):

Organometallic chemistry.

Organotransition metal compounds.

Physical Description:

1 online resource (522 p.)

Edition:

6th edition.

Place of Publication:

Hoboken, New Jersey : Wiley, 2014.

Language Note:

English

Summary:

Fully updated and expanded to reflect recent advances, the sixth edition of this bestselling text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications. Increased focus is given to organic synthesis applications, nanoparticle science, and green chemistry. This edition features: New sections on Multifunctional Ligands, Oxidation Catalysis, and Green ChemistryExp

Contents:

Cover; Title page; Copyright page; Contents; Preface; List of Abbreviations; 1: Introduction; 1.1 Why Study Organometallic Chemistry?; 1.2 Coordination Chemistry; 1.3 Werner Complexes; Stereochemistry; Chelate Effect; Werner's Coordination Theory; 1.4 The Trans Effect; 1.5 Soft versus Hard Ligands; 1.6 The Crystal Field; High Spin versus Low Spin; Inert versus Labile Coordination; Jahn-Teller Distortion; Low- versus High-Field Ligands; Magnetism and Nuclearity; Other Geometries; Isoconfigurational Ions; 1.7 The Ligand Field; 1.8 The sdn Model and Hypervalency; 1.9 Back Bonding

Frontier Orbitalsπ-Donor Ligands; 1.10 Electroneutrality; Oxidation State Trends; Periodic Trends; 1.11 Types of Ligand; Ambidentate Ligands; Actor and Spectator Ligands; Multifunctional Ligands29; Organometallic versus Coordination Compounds; References; Problems; 2: Making Sense of Organometallic Complexes; 2.1 The 18-Electron Rule; Covalent Electron Counting Model; Ionic Electron Counting Model; Electron Counts for Common Ligands and Hapticity; Bridging Ligands; Zero-Electron Ligands; 2.2 Limitations of The 18-Electron Rule; Steric Stabilization of Reactive Species

Kinetic Stability from Bulky SubstituentsPreparation of Metal Alkyls; Cyclometalation; Oxidative Addition; Insertion; Bridging Alkyls; Metalacycles; η1 and η2-Acyl and Vinyls; 3.2 Other σ-Bonded Ligands; Group 14 Elements; Groups 15-17; Oxophilicity and Functional Group Tolerance; 3.3 Metal Hydrides; Characterization; Synthesis; Reactions; Hydricity; Bridging Hydrides; 3.4 Sigma Complexes; Dihydrogen Complexes20; Characterization; Reactions; Agostic Species; 3.5 Bond Strengths; Supramolecular Interactions; References; Problems; 4: Carbonyls, Phosphines, and Substitution; 4.1 Metal Carbonyls

Preparation of CarbonylsReactions of Carbonyls; Bridging Carbonyls; Isonitriles; Thiocarbonyls; Nitrosyls; Cyanide; Other CO Analogs; 4.2 Phosphines; Structure and Bonding; Tolman Electronic Parameter and Cone Angle; Bite Angle; 4.3 N-Heterocyclic Carbenes (NHCs); 4.4 Dissociative Substitution; Kinetics; Stereochemistry and Trans Effect; Electronic and Steric Factors; 4.5 Associative Substitution; Kinetics; Trans Effect; Solvent Participation; Ligand Rearrangements; 4.6 Redox Effects and Interchange Substitution; 17e and 19e Species; The Interchange Mechanism; 4.7 Photochemical Substitution

Carbonyls

Notes:

Description based upon print version of record.

Includes bibliographical references at the end of each chapters and index.

Description based on print version record.

ISBN:

1-118-78824-9

1-118-78830-3

1-118-78844-3

OCLC:

863383849