Inorganic syntheses. Volume 36 / [edited by] Gregory S. Girolami, Alfred P. Satterberger.

Format:

Book

Contributor:

Girolami, Gregory S., editor.

Satterberger, Alfred P., editor.

Series:

Inorganic Syntheses

Language:

English

Subjects (All):

Inorganic compounds--Synthesis.

Inorganic compounds.

Physical Description:

1 online resource (333 p.)

Edition:

1st ed.

Place of Publication:

Hoboken, New Jersey : John Wiley & Sons, 2014.

Language Note:

English

Summary:

This volume of Inorganic Syntheses spans the preparations of wide range of important inorganic, organometallic and solid-state compounds. The volume is divided into 6 chapters. The first chapter contains the syntheses ofsome key early transition metal halide clusters and the very useful mononuclear molybdenum(III) synthon, MoCl3(THF)3. Chapter 2 covers the synthesis of a number of cyclopentadienyl compounds, including a novel route to sodium and potassium cyclopentadienide, MC5H5. Chapter 3 details synthetic procedures for a range of m

Contents:

Inorganic Syntheses; Preface; Dedication; Notice to Contributors and Checkers; Toxic Substances and Laboratory Hazards; Contents; Chapter One: Transition Metal Halide Compounds; 1. Octahedral Hexatantalum Halide Clusters; A. Tetradecachlorohexatantalum Octahydrate; B. Tetradecabromohexatantalum Octahydrate; C. Tetrakis(benzyltributylammonium) Octadecachlorohexatantalate; 2. Octahedral Hexamolybdenum Halide Clusters; A. Tetradecachlorohexamolybdate Hexahydrate (Chloromolybdic Acid); B. Hexamolybdenum Dodecachloride; 3. Ether Complexes of Molybdenum(III) and Molybdenum(IV) Chlorides

A. Tetrachlorobis(diethyl ether)molybdenum(IV)B. Trichlorotris(tetrahydrofuran)molybdenum(III); 4. Octahedral Hexatungsten Halide Clusters; A. Bis(hydroxonium) Tetradecachlorohexatungstate Heptahydrate (Chlorotungstic Acid); B. Hexatungsten Dodecachloride; 5. Trinuclear Tungsten Halide Clusters; A. Tritungsten Decachloride; B. Trisodium Tridecachlorotritungstate; C. Tris(benzyltributylammonium) Tridecachlorotritungstate; 6. Crystalline and Amorphous Forms of Tungsten Tetrachloride; A. Crystalline Tungsten Tetrachloride by Solid-State Reduction

B. Amorphous Tungsten Tetrachloride by Solution-Phase ReductionChapter Two: Cyclopentadienyl Compounds; 7. Sodium and Potassium Cyclopentadienide; A. Sodium Cyclopentadienide; B. Potassium Cyclopentadienide; 8. (Pentafluorophenyl)cyclopentadiene and its Sodium Salt; A. (Pentafluorophenyl)cyclopentadiene; B. Sodium (Pentafluorophenyl)cyclopentadienide; 9. Bis(η5-pentamethylcyclopentadienyl) Complexes of Scandium; A. Bis(η5-pentamethylcyclopentadienyl)chloroscandium; B. Bis(η5-pentamethylcyclopentadienyl)methylscandium; C. Bis(η5-pentamethylcyclopentadienyl)phenylscandium

D. Bis(η5-pentamethylcyclopentadienyl)(o-tolyl)scandium10. Bis(η5-pentamethylcyclopentadienyl) Complexes of Titanium,Zirconium, and Hafnium; A. Bis(η5-pentamethylcyclopentadienyl)dichlorotitanium(IV); B. Bis(η5-pentamethylcyclopentadienyl)dichlorozirconium(IV); C. Bis(η5-pentamethylcyclopentadienyl)dichlorohafnium(IV); 11. Bis(η5-pentamethylcyclopentadienyl) Complexes of Niobiumand Tantalum; A. Bis(η5-pentamethylcyclopentadienyl)dichlorotantalum(IV); B. Bis(η5-pentamethylcyclopentadienyl)dichloroniobium(IV); 12. Bis(η5-pentamethylcyclopentadienyl) Complexes of Molybdenum

A. Bis(pentamethylcyclopentadienyl)dichloromolybdenum(IV)B. Bis(pentamethylcyclopentadienyl)dihydridomolybdenum(IV); 13. (η5-Cyclopentadienyl)tricarbonylmanganese(I) Complexes; A. (η5-Cyclopentadienyl)tricarbonylmanganese(I); B. (η5-Pentamethylcyclopentadienyl)tricarbonylmanganese(I); 14. 1,1'-Diaminoferrocene; A. 1,1'-Dilithioferrocene N,N,N',N'-Tetramethylethylenediamine; B. 1,1'-Dibromoferrocene; C. One-Pot Preparation of 1,1'-Dibromoferrocene from Ferrocene; D. 1,1'-Diaminoferrocene; E. 1,1'-Diaminoferrocenium Hexafluorophosphate; F. 1,1'-Diaminoferrocenium Triflate

15. Mono(η5-pentamethylcyclopentadienyl) Complexes of Osmium

Notes:

Description based upon print version of record.

Includes bibliographical references and indexes.

Description based on online resource; title from PDF title page (ebrary, viewed April 1, 2014).

ISBN:

9781118744840

1118744845

9781118744994

1118744993

9781118744963

1118744969

OCLC:

878149535