Catalytic arylation methods : from the academic lab to industrial processes / Anthony J. Burke and Carolina Silva Marques.

Format:

Book

Author/Creator:

Burke, Anthony J., author.

Marques, Carolina Silva, author.

Language:

English

Subjects (All):

Arylation.

Physical Description:

1 online resource (1058 p.)

Edition:

1st ed.

Place of Publication:

Weinheim, Germany : Wiley-VCH Verlag GmbH & KGaA, [2015]

Language Note:

English

Summary:

A current view of the challenging field of catalytic arylation reactions. Clearly structured, the chapters in this one-stop resource are arranged according to the reaction type, and focus on novel, efficient and sustainable processes, rather than the well-known and established cross-coupling methods.The entire contents are written by two authors with academic and industrial expertise to ensure consistent coverage of the latest developments in the field, as well as industrial applications, such as C-H activation, iron and gold-catalyzed coupling reactions, cycloadditions or novel methodologies

Contents:

Cover; Related Titles; Title Page; Copyright; Dedication; Preface; List of Abbreviations; Chapter 1: Cross-Coupling Arylations: Precedents and Rapid HistoricalReview of the Field; 1.1 Metal-Catalyzed Cross-Couplings: From Its Origins to the Nobel Prize and Beyond; 1.2 Arylation: What Is So Special?; 1.3 Recent New Developments; 1.4 Selected Experiments from the Literature; References; Chapter 2: Amine, Phenol, Alcohol, and Thiol Arylation; 2.1 Introduction; 2.2 Pd-Catalyzed Processes; 2.3 Cu-Catalyzed and Promoted Arylations: (CAr-N Bond Formation); 2.4 Fe-Catalyzed Arylations

2.5 Ni-Catalyzed Reactions2.6 Co-Catalyzed Arylations; 2.7 Mn-Catalyzed Arylations; 2.8 Cd-Catalyzed Arylations; 2.9 Bi(III) and Indium Oxide-Catalyzed Thiol Arylations; 2.10 Conclusions and Final Comment; 2.11 Selected Experiments from the Literature; References; Chapter 3: Decarboxylative Coupling Techniques; 3.1 Introduction; 3.2 Pd-Catalyzed Versions; 3.3 Other Metal-Catalyzed Versions; 3.4 Conclusions; 3.5 Selected Experiments; References; Chapter 4: C-H Bond Activation for Arylations; 4.1 Introduction; 4.2 C(sp2)-H Activations; 4.3 Conclusions

4.4 Selected Experiments from the LiteratureReferences; Chapter 5: Conjugate Additions; 5.1 Conjugate Additions: A Powerful Tool for Appending Organic Residues to Cyclic and Acyclic Substrates; 5.2 Applications of Rh Catalysts; 5.3 Applications of Pd Catalysts; 5.4 Applications of Ru and Other Catalysts; 5.5 Conclusions; 5.6 Selected Experiments; References; Chapter 6: Imine Arylations - Synthesis of Arylamines; 6.1 Arylation of C=N Bonds: Simple Access to Chiral Amine Units; 6.2 Application of Rh Catalysts; 6.3 Application of Pd Catalysts; 6.4 Application of Ru and Other Catalysts

6.5 The Petasis-Akritopoulou Reaction6.6 Conclusions; 6.7 Selected Experiments; References; Chapter 7: Carbonyl Group Arylation; 7.1 Introduction; 7.2 Application of Rh Catalysts; 7.3 Application of Pd Catalysts; 7.4 Application of Ru and Other Catalysts; 7.5 Conclusions; 7.6 Selected Experiments; References; Chapter 8: α-Arylation Processes; 8.1 Introduction; 8.2 Arylation of Enolates and Equivalents; 8.3 Other Metal-Catalyzed α-Arylations; 8.4 Conclusions; 8.5 Selected Experiments; References; Chapter 9: Catalytic Cycloaddition Aromatization Processes; 9.1 Introduction

9.2 Cycloaddition Events9.3 Radical-Based Cycloaromatization Processes; 9.4 Conclusions; 9.5 Selected Experiments from the Literature; References; Index; End User License Agreement

Notes:

Description based upon print version of record.

Includes bibliographical references and index.

Description based on online resource; title from PDF title page (ebrary, viewed December 2, 2014).

ISBN:

9783527672745

3527672745

9783527672707

3527672702

9783527672851

3527672850

OCLC:

893739710