Homogeneous catalysis : mechanisms and industrial applications / Sumit Bhaduri, Doble Mukesh.

Format:

Book

Author/Creator:

Bhaduri, Sumit, 1948- author.

Mukesh, Doble, author.

Language:

English

Subjects (All):

Catalysis.

Catalysis--Industrial applications.

Physical Description:

1 online resource (291 p.)

Edition:

Second edition.

Place of Publication:

Hoboken, New Jersey : Wiley, 2014.

Summary:

"Providing a balanced treatment of the recent breakthroughs and developments while also detailing earlier discoveries and the fundamentals of homogeneous catalysis, the text provides problems and answers, along with real-life case studies, extensive references to cutting-edge research with application potential and leading patents, and examples from proven industrial processes with clear discussions on environmental and techno-commercial issues"-- Provided by publisher.

Contents:

Homogeneous Catalysis: Mechanisms and Industrial Applications; Copyright; Contents; Preface; Chapter 1 Chemical Industry and Homogeneous Catalysis; 1.1 Feedstocks, Fuels, and Catalysts; 1.2 Crude Oil to Gasoline and Basic Building Blocks by Heterogeneous Catalysts; 1.2.1 Cracking Reactions; 1.2.2 Hydrodesulfurization Reactions; 1.3 Basic Building Blocks to Downstream Products by Homogeneous Catalysis; 1.4 Comparison among Different Types of Catalysis; 1.5 Catalyst Recovery; 1.6 Environmental Issues; 1.6.1 Background; 1.6.2 Biofuel, Ethanol, and Glycerol; 1.6.3 Biodegradable Plastics

1.6.4 Hydrogen and Carbon DioxideProblems; Bibliography; Books; Articles; Chapter 2 Basic Chemical Concepts; 2.1 Ligands; 2.1.1 Types of Ligands; 2.1.2 Donor and Acceptor Properties of Ligands; 2.1.3 CO, R2C=CR2, other π-acids, and H- as Ligands; 2.1.4 Phosphines and Related Ligands; 2.1.5 Alkyl, Aryl, Alkylidene, and Related Ligands; 2.1.6 Cyclopentadienyl, Allyl, and Related Ligands; 2.1.7 Chiral Ligands; 2.2 Metals; 2.2.1 Oxidation State; 2.2.2 Electron Counting; 2.2.3 Coordinative Unsaturation; 2.2.4 Lanthanides and Actinides; 2.3 Important Reaction Types

2.3.1 Oxidative Addition and Reductive Elimination2.3.2 Insertion and Elimination Reactions; 2.3.3 Metallacycle Formation; 2.3.4 Attack on a Coordinated Ligand; 2.3.5 Activation of Alkanes; 2.3.6 Activation of Dinitrogen; 2.3.7 Activation of Dioxygen (O2); Problems; Bibliography; Books; Articles; Chapter 3 Methods of Investigation; 3.1 Catalytic Cycle and Intermediates; 3.2 Spectroscopic Studies; 3.2.1 In Situ Spectroscopy; 3.2.2 Infrared Spectroscopy; 3.2.3 NMR Spectroscopy; 3.2.4 Advanced NMR Spectroscopy; 3.2.5 Other Spectroscopic Methods; 3.3 Kinetic Studies; 3.4 Model Compounds

3.5 Computational Methods3.6 Asymmetric Catalysis; Problems; Bibliography; Books; Articles; Chapter 4 Carbonylation and Related Reactions; 4.1 Introduction; 4.2 Carbonylation and Manufacture of Acetic Acid; 4.2.1 Cobalt Process; 4.2.2 Rhodium Cycle; 4.2.3 Iridium Process; 4.2.4 Mechanistic Studies and Differences; 4.3 Carbonylation of Other Alcohols; 4.4 Carbonylation of Methyl Acetate; 4.5 Carbonylation of Alkynes; 4.6 Other Carbonylation and Hydrocarboxylation Reactions; 4.7 C1 Chemistry; 4.7.1 Water Gas Shift Reaction; 4.7.2 Fischer-Tropsch Reactions; 4.7.3 Utilization of CO2

4.7.4 Polycarbonates from CO24.8 Engineering Aspects; Problems; Bibliography; Articles; Patents; Chapter 5 Hydrogenation and Other Hydrogen-Based Catalytic Reactions; 5.1 Hydrogenation; 5.1.1 Mechanisms and Catalytic Cycles; 5.1.2 Asymmetric Hydrogenation; 5.2 Hydroformylation; 5.2.1 Ligands and Selectivity; 5.2.2 Mechanistic Studies; 5.2.3 Water-Soluble Phosphines and Catalyst Recovery; 5.2.4 Other Methods for Catalyst Recovery; 5.3 Other Hydroformylation Reactions; 5.4 Asymmetric Hydroformylation; 5.5 Hydrosilylation; 5.6 Hydrocyanation; 5.6.1 Catalysts and Mechanistic Studies

5.6.2 Asymmetric Hydrocyanation

Notes:

Description based upon print version of record.

Includes bibliographical references at the end of each chapters and index.

Description based on print version record.

ISBN:

9781118872512

1118872517

9781118872369

1118872363

9781118872475

1118872479

OCLC:

872655273