Multi-catalyst system in asymmetric catalysis / Jian Zhou ; Zhong-Yan Cao [and seven others], contributors.

Format:

Book

Author/Creator:

Zhou, Jian, 1974- author.

Contributor:

Cao, Zhong-Yan, contributor.

Language:

English

Subjects (All):

Asymmetric synthesis.

Catalysis.

Physical Description:

1 online resource (1279 p.)

Edition:

1st ed.

Place of Publication:

Hoboken, New Jersey : Wiley, 2015.

Language Note:

English

Summary:

This book introduces multi-catalyst systems by describing their mechanism and advantages in asymmetric catalysis. <br /> Helps organic chemists perform more efficient catalysis with step-by-step methods<br /> Overviews new concepts and progress for greener and economic catalytic reactions<br /> Covers topics of interest in asymmetric catalysis including bifunctional catalysis, cooperative catalysis, multimetallic catalysis, and novel tandem reactions<br /> Has applications for pharmaceuticals, agrochemicals, materials, and flavour and fragrance

Contents:

Cover; Dedication; Title Page; Copyright; Preface; Contributors; Chapter 1: Toward Ideal Asymmetric Catalysis; 1.1 Introduction; 1.2 Challenges to Realize Ideal Asymmetric Catalysis; 1.3 Solutions; 1.4 Borrow ideas from Nature; 1.5 Conclusion; References; Chapter 2: Multicatalyst System; 2.1 Introduction; 2.2 Models of Substrate Activation; 2.3 Early Examples of the Application of Multicatalyst System in Asymmetric Catalysis; 2.4 A General Introduction of Multicatalyst-Promoted Asymmetric Reactions; 2.5 Classification of Multicatalyst-Promoted Asymmetric Reactions

2.6 Challenges and Possible Solutions2.7 Multicatalyst System Versus Multifunctional Catalyst; 2.8 Multicatalyst System Versus Additives-Enhanced Catalysis; 2.9 Additive-Enhanced Catalysis; 2.10 Conclusion; References; Chapter 3: Asymmetric Multifunctional Catalysis; 3.1 Introduction; 3.2 Asymmetric Multifunctional Organocatalysis; 3.3 Asymmetric Hybrid Organo/Metal Catalysis; 3.4 Asymmetric Multifunctional Multimetallic Catalysis; 3.5 Anion-Enabled Bifunctional Asymmetric Catalysis; 3.6 Conclusion; References; Chapter 4: Asymmetric Cooperative Catalysis; 4.1 Introduction

4.2 Catalytic Asymmetric Michael Addition Reaction4.3 Catalytic Asymmetric Mannich Reaction; 4.4 Catalytic Asymmetric Conia-ENE Reaction; 4.5 Catalytic Asymmetric Umpolung Reaction; 4.6 Catalytic Asymmetric Cyanosilylation Reaction; 4.7 α-Alkylation Reaction of Carbonyl Compounds; 4.8 Catalytic Asymmetric Allylic Alkylation Reaction; 4.9 Catalytic Asymmetric Aldol-Type Reaction; 4.10 Catalytic Asymmetric (Aza)-Morita-Baylis-Hillman Reaction; 4.11 Catalytic Asymmetric Hydrogenation Reaction; 4.12 Catalytic Asymmetric Cycloaddition Reaction; 4.13 Catalytic Asymmetric N-H Insertion Reaction

4.14 Catalytic Asymmetric α-Functionalization of Aldehydes4.15 Miscellaneous Reaction; 4.16 Conclusion; References; Chapter 5: Asymmetric Double Activation Catalysis by Multicatalyst System; 5.1 Introduction; 5.2 Double Activation by Aminocatalysis and Lewis Base Catalysis; 5.3 Asymmetric Double Primary Amine and BrØnsted Acid Catalysis; 5.4 Asymmetric Double Metal and BrØnsted Base Catalysis; 5.5 Asymmetric H-bond Donor Catalysis and Lewis Base Catalysis; 5.6 Sequential Double Activation Catalysis; 5.7 Conclusion; References; Chapter 6: Asymmetric Assisted Catalysis by Multicatalyst System

6.1 Introduction6.2 Asymmetric Assisted Catalysis within Acids and Bases; 6.3 Modulation of a Metal Complex by a Chiral Ligand; 6.4 Supramolecular-Type Assisted Catalysis; 6.5 Conclusion; References; Chapter 7: Asymmetric Catalysis Facilitated by Photochemical or Electrochemical Methods; 7.1 Introduction; 7.2 Catalytic Asymmetric Reaction Facilitated by Photochemical Method; 7.3 Catalytic Asymmetric Reactions Facilitated by Electrochemical Method; 7.4 Conclusion; References; Chapter 8: Multicatalyst System Realized Asymmetric Tandem Reactions; 8.1 Introduction

8.2 Multicatalyst Systems of Homocombination

Notes:

Includes index.

Includes bibliographical references at the end of each chapters and index.

Description based on print version record.

ISBN:

9781118846933

1118846931

9781118846919

1118846915

9781118847008

1118847008

OCLC:

879983663