Pincer and pincer-type complexes : applications in organic synthesis and catalysis / edited by Kálmán J. Szabö and Ola F. Wendt.

Format:

Book

Contributor:

Szabo, Kalman J., editor.

Wendt, Ola F., editor.

Series:

In an Instant

Language:

English

Subjects (All):

Organometallic chemistry--Research.

Organometallic chemistry.

Organometallic compounds--Analysis.

Organometallic compounds.

Physical Description:

1 online resource (320 p.)

Edition:

1st ed.

Place of Publication:

Weinheim, Germany : Wiley-VCH Verlag GmbH & Co, 2014.

Language Note:

English

Summary:

This new book on this hot topic summarizes the key achievements for the synthesis and catalytic applications of pincer and pincer-type complexes, providing readers with the latest research highlights. The editors have assembled an international team of leaders in the field, and their contributions focus on the application of various pincer complexes in modern organic synthesis and catalysis, such as C-C and C-X bond forming reactions, C-H bond functionalization, and the activation of small molecules, as well as asymmetric catalysis. A must-have for every synthetic chemist in both acade

Contents:

Pincer and Pincer -Type Complexes; Contents; Preface; List of Contributors; Chapter 1 Catalysis by Pincer Complexes: Synthesis of Esters, Amides, and Peptides; 1.1 Introduction and Background; 1.2 Bond Activation by Metal-Ligand Cooperation; 1.3 Synthesis of Esters; 1.3.1 Synthesis of Esters from Primary Alcohols; 1.3.2 Synthesis of Cross-Esters from Primary and Secondary Alcohols; 1.3.3 Synthesis of Esters by Acylation of Secondary Alcohols Using Esters; 1.3.4 Synthesis of Polyesters from Diols; 1.4 Synthesis of Amides; 1.4.1 Synthesis of Amides from Alcohols and Amines

1.4.2 Synthesis of Amides from Esters and Amines1.4.3 Synthesis of Polyamides from Diols and Diamines; 1.5 Synthesis of Peptides from β-Amino Alcohols; 1.6 Concluding Remarks; Acknowledgments; References; Chapter 2 The Role of Redox Processes in Reactions Catalyzed by Nickel and Palladium Complexes with Anionic Pincer Ligands; 2.1 Introduction; 2.2 Pincer Complexes of Ni, Pd, and Pt in Oxidation States Different from II; 2.2.1 Complexes in the Higher Oxidation States (III, IV); 2.2.2 Reduced Complexes of Ni, Pd, and Pt with Pincer Ligands

2.3 Catalytic Reactions Involving Redox Processes in the Pincer-Metal Framework2.3.1 Atom-Transfer Radical Addition (ATRA) and Polymerization Reactions (ATRP); 2.3.2 The Heck Reaction; 2.3.3 C-C Cross-Coupling Reactions; 2.3.4 Carbon-Heteroatom Coupling Reactions; 2.4 Concluding Remarks; Acknowledgment; References; Chapter 3 Appended Functionality in Pincer Ligands; 3.1 Introduction; 3.1.1 Design Criteria; 3.1.2 Motivations; 3.1.2.1 Transition-Metal Catalysis; 3.1.2.2 Supramolecular Architectures; 3.2 Appended Functionality Coplanar with the Pincer Chelate

3.2.1 Systems that Incorporate 2,2':6',2''-Terpyridine3.2.1.1 Synthetic Strategies; 3.2.1.2 Appended Lewis Acid/Bases; 3.2.1.3 Appended Hydrogen-Bond Acceptor/Donors; 3.2.2 Pyridine-2,6-Dicarboxamide Systems; 3.3 Appended Functionality Not Coplanar to the Pincer Chelate; 3.3.1 ENE Pincer Systems; 3.3.2 PCP Pincer Systems; 3.3.3 PEP Pincer Systems; 3.3.4 Pyridine-2,6-Diimine Systems; 3.4 Future Outlook and Summary; References; Chapter 4 C-C, C-O, and C-B Bond Formation by Pincer Complexes Including Asymmetric Catalysis; 4.1 Introduction - Pros and Cons of Using Pincer Complexes in Catalysis

4.2 Reaction of Imines and Isocyanoacetates4.2.1 Stereoselective Synthesis of Imidazolines; 4.2.2 Application of Chiral Pincer Complexes; 4.2.3 Mechanistic Considerations; 4.3 C-H Functionalization of Organonitriles; 4.3.1 Allylation of Imines; 4.3.2 Benzyl Amine Synthesis; 4.4 Reactions Involving Hypervalent Iodines; 4.4.1 Arylation of Alkenes Using Pincer Complex Catalysis; 4.4.2 Acetoxylation with Hypervalent Iodines; 4.4.3 C-H Borylation of Alkenes; 4.5 Summary and Outlook; References; Chapter 5 Nickel-Catalyzed Cross-Coupling Reactions; 5.1 Introduction

5.2 Carbon-Carbon Bond-Forming Reactions

Notes:

Description based upon print version of record.

Includes bibliographical references at the end of each chapters and index.

Description based on online resource; title from PDF title page (ebrary, viewed June 4, 2014).

ISBN:

9783527681334

3527681337

9783527681303

3527681302

9783527681327

3527681329

OCLC:

880530991