Synthesis and applications of copolymers / edited by Andanandam Parthiban.

Format:

Book

Contributor:

Parthiban, Anbanandam, editor.

Language:

English

Subjects (All):

Polymerization.

Copolymers.

Copolymers--Industrial applications.

Physical Description:

1 online resource (410 p.)

Edition:

1st ed.

Place of Publication:

Hoboken, New Jersey : Wiley, 2014.

Language Note:

English

Summary:

Understanding the reactivity of monomers is crucial in creating copolymers and determining the outcome of copolymerization. Covering the fundamental aspects of polymerization, Synthesis and Applications of Copolymers explores the reactivity of monomers and reaction conditions that ensure that the newly formed polymeric materials exhibit desired properties. Referencing a wide-range of disciplines, the book provides researchers, students, and scientists with the preparation of a diverse variety of copolymers and their recent developments, with a particular focus on copolymerization, crystallizat

Contents:

Cover; Title Page; Contents; Preface; Contributors; Part 1 Synthesis of Copolymers; Chapter 1 Trends in Synthetic Strategies for Making (CO)Polymers; 1.1 Background and Introduction; 1.2 Significance of Control Over Arrangement of Monomers in Copolymers; 1.3 Chain-Growth Condensation Polymerization; 1.3.1 Sequential Self-Repetitive Reaction (SSRR); 1.3.2 Poly(phenylene Oxide)s by Chain-Growth Condensation Polymerization; 1.3.3 Hydroxybenzoic Acids as AA' Type Monomer in Nucleophilic Aliphatic Substitution Polymerization; 1.4 Sequence-Controlled Polymerization

1.4.1 Sequence-Controlled Copolymers of N-Substituted Maleimides1.4.2 Alternating Copolymers by Ring-Opening Polymerization; 1.4.3 Selective Radical Addition Assisted by a Template; 1.4.4 Alternating AB-Type Sequence-Controlled Polymers; 1.4.5 Metal-Templated ABA Sequence Polymerization; 1.4.6 Sequence-Controlled Vinyl Copolymers; 1.4.7 Sequence-Regulated Polymerization Induced by Dual-Functional Template; 1.5 Processing of Thermoset Polymers: Dynamic Bond Forming Processes and Self-Healing Materials; 1.5.1 Plasticity of Networked Polymers Induced by Light

1.5.2 Radically Exchangeable Covalent Bonds1.5.3 Self-Repairing Polyurethane Networks; 1.5.4 Temperature-Induced Self-Healing in Polymers; 1.5.5 Diels-Alder Chemistry at Room Temperature; 1.5.6 Trithiocarbonate-Centered Responsive Gels; 1.5.7 Shuffling of Trithiocarbonate Units Induced by Light; 1.5.8 Processable Organic Networks; 1.6 Miscellaneous Developments; 1.6.1 Atom Transfer Radical Polymerization (ATRP) Promoted by Unimolecular Ligand-Initiator Dual-Functional Systems (ULIS); 1.6.2 Unsymmetrical Ion-Pair Comonomers and Polymers; 1.6.3 Imidazole-Derived Zwitterionic Polymers

1.6.4 Post-Modification of Polymers Bearing Reactive Pendant Groups1.7 Conclusion; References; Chapter 2 Functional Polyolefins from the Coordination Copolymerization of Vinyl Monomers; 2.1 Molecular Aspects of Olefin Coordination to Metals; 2.2 Fundamentals of Homopolymerization of Alkenes; 2.3 Copolymerization of Ethene and other Alkenes; 2.4 Copolymerization of Alkenes and Carbon Monoxide; 2.5 Copolymerization of Alkenes and Polar Vinyl Monomers; 2.5.1 Migratory Insertion Polymerization; 2.5.2 Polymerization via a Dual Radical/Migratory Insertion Pathway

2.5.3 Coordinative Group Transfer Polymerization2.6 Copolymerization of Polar Vinyl Monomers and Carbon Monoxide; 2.7 Why are Phosphine-Sulfonate Ligands so Special?; 2.8 Telechelic and End-Capped Macromolecules; 2.9 On the Use of Chemoinformatics for a More Rapid Development of the Field; 2.10 Conclusion and Outlook; References; Chapter 3 General Aspects of Copolymerization; 3.1 Copolymerization in Chain Reactions; 3.1.1 Derivation of the Copolymerization Equation; 3.1.2 Types of Copolymers; 3.1.3 Polymerization Rates in Copolymerizations; 3.2 Measuring Copolymerization Parameters

3.3 Influence of Reaction Conditions

Notes:

Description based upon print version of record.

Includes bibliographical references at the end of each chapters and index.

Description based on print version record.

ISBN:

9781118860489

1118860489

9781118860168

1118860160

9781118860410

1118860411

OCLC:

875404486