Hypervalent iodine chemistry : preparation, structure and synthetic applications of polyvalent iodine compounds / Viktor V. Zhdankin.

Format:

Book

Author/Creator:

Zhdankin, Viktor V., 1956-

Language:

English

Subjects (All):

Iodine compounds.

Organoiodine compounds.

Hypervalence (Theoretical chemistry).

Physical Description:

1 online resource (480 p.)

Edition:

1st ed.

Place of Publication:

Chichester, West Sussex : John Wiley & Sons, Inc., 2014.

Language Note:

English

Summary:

Hypervalent Iodine Chemistry is the first comprehensive text covering all of the main aspects of the chemistry of organic and inorganic polyvalent iodine compounds, including applications in chemical research, medicine, and industry. Providing a comprehensive overview of the preparation, properties, and synthetic applications of this important class of reagents, the text is presented in the following way: The introductory chapter provides a historical background and describes the general classification of iodine compounds, nomenclature, hyperval

Contents:

Hypervalent Iodine Chemistry; Contents; Preface; 1 Introduction and General Overview of Polyvalent Iodine Compounds; 1.1 Introduction; 1.2 Classification and Nomenclature of Polyvalent Iodine Compounds; 1.3 Hypervalent Bonding; 1.4 General Structural Features; 1.4.1 Experimental Structural Studies; 1.4.2 Computational Studies; 1.5 General Principles of Reactivity; 1.5.1 Ligand Exchange and Reductive Elimination; 1.5.2 Radical Reactions; 1.5.3 Single-Electron Transfer (SET) Reactions; References; 2 Preparation, Structure and Properties of Polyvalent Iodine Compounds; 2.1 Iodine(III) Compounds

2.1.1 Inorganic Iodine(III) Derivatives2.1.2 Organoiodine(III) Fluorides; 2.1.3 Organoiodine(III) Chlorides; 2.1.4 Organo-Iodosyl Compounds; 2.1.5 Organoiodine(III) Carboxylates; 2.1.6 [Hydroxy(Organosulfonyloxy)Iodo]Arenes; 2.1.7 Organoiodine(III) Derivatives of Strong Acids; 2.1.8 Iodine(III) Heterocycles; 2.1.9 Iodonium Salts; 2.1.10 Iodonium Ylides; 2.1.11 Iodine(III) Species with Three Carbon Ligands; 2.1.12 Iodine(III) Species with I-N Bonds; 2.2 Iodine(V) Compounds; 2.2.1 Inorganic Iodine(V) Derivatives; 2.2.2 Noncyclic and Pseudocyclic Iodylarenes; 2.2.3 Iodine(V) Heterocycles

2.2.4 Organoiodine(V) Fluorides2.3 Iodine(VII) Compounds; References; 3 Hypervalent Iodine Reagents in Organic Synthesis; 3.1 Reactions of Iodine(III) Compounds; 3.1.1 Fluorinations; 3.1.2 Chlorinations; 3.1.3 Brominations; 3.1.4 Iodinations; 3.1.5 Oxidation of Alcohols; 3.1.6 Oxidative Functionalization of Carbonyl Compounds; 3.1.7 Oxidative Functionalization of Silyl Enol Ethers; 3.1.8 Oxidation of Alkenes and Alkynes; 3.1.9 Oxidations at the Benzylic or Allylic Position; 3.1.10 Oxidative Functionalization of Aromatic Compounds

3.1.11 Oxidative Dearomatization of Phenols and Related Substrates3.1.12 Oxidative Coupling of Aromatic Substrates; 3.1.13 Oxidative Cationic Cyclizations, Rearrangements and Fragmentations; 3.1.14 Oxidations at Nitrogen, Sulfur and other Heteroatoms; 3.1.15 Azidations; 3.1.16 Aminations; 3.1.17 Thiocyanations and Arylselenations; 3.1.18 Radical Fragmentations, Rearrangements and Cyclizations; 3.1.19 Reactions via Alkyliodine(III) Intermediates; 3.1.20 Transition Metal Catalyzed Oxidations; 3.1.21 Transition Metal Catalyzed Aziridinations and Amidations

3.1.22 Reactions of Iodonium Salts and C-Substituted Benziodoxoles3.1.23 Reactions of Iodonium Ylides; 3.2 Synthetic Applications of Iodine(V) Compounds; 3.2.1 Noncyclic and Pseudocyclic Iodylarenes; 3.2.2 2-Iodoxybenzoic Acid (IBX); 3.2.3 Dess-Martin Periodinane (DMP); 3.2.4 Inorganic Iodine(V) Reagents; 3.3 Synthetic Applications of Iodine(VII) Compounds; References; 4 Hypervalent Iodine Catalysis; 4.1 Catalytic Cycles Based on Iodine(III) Species; 4.1.1 Oxidative a-Functionalization of Carbonyl Compounds; 4.1.2 Oxidative Functionalization of Alkenes and Alkynes

4.1.3 Oxidative Bromination of Aromatic Compounds

Notes:

Includes index.

Includes bibliographical references and index.

Description based on print version record.

ISBN:

9781118341308

1118341309

9781118341155

1118341155

9781118341315

1118341317

OCLC:

859835664