Influence of the solvents on some radical reactions / [editors], Gennady E. Zeikov ... [et al.].

Format:

Book

Contributor:

Zaikov, G. E. (Gennadiĭ Efremovich), 1935-

Series:

Chemistry research and applications series.

Chemistry research and applications series

Language:

English

Subjects (All):

Solvents.

Chemical kinetics.

Free radical reactions.

Physical Description:

1 online resource (140 p.)

Edition:

1st ed.

Place of Publication:

New York : Nova Science Publishers, c2010.

Language Note:

English

Summary:

This text is based on the results of a series of experimental investigations. It was proved that the nature of medium has an essential influence both on the rate and the chemical mechanism of homolutical reactions.

Contents:

Intro

INFLUENCE OF THE SOLVENTS ON SOME RADICAL REACTIONS

CONTENTS

PREFACE

Chapter 1 COMPLICATIONS EXISTING AT CONSIDERATION OF FACTORS INFLUENCING ON KINETICS OF RADICAL REACTIONS

1. HOMOLYTICAL NON-INITIATED (INHIBITED) REACTIONS OF DECOMPOSITION [6, 7, 16, 17]

2. THE CASE, WHEN THE LIMITATIVE IS ONLY ONE STAGE AMONG OTHER STAGES OF THE RADICAL PROCESS

3. THE CASE, WHEN THERE ARE KNOWN THE RATE CONSTANTS OF SEPARATE ELEMENTARY STAGES OF RADICAL REACTIONS, FOR EXAMPLE, IN A CASE OF STYRENE, CUMENE, METHYLETHYLKETONE, TETRALIN OXIDATION

4. REACTIONS WITH THE PARTICIPATION OF LOW-ACTIVITY RADICALS, FOR EXAMPLE, IN A CASE OF PHENOXYL RADICALS DIMERIZATION [22]

REFERENCES

Chapter 2 THE MEDIUM INFLUENCE ON THERMOLYSIS OF DIACYL - AND DIALKYLPEROXIDES

Chapter 3 DECOMPOSITION OF PERACIDS ESTERS

Chapter 4 DECOMPOSITION OF THE HYDROPEROXIDES AND REACTIONS OF THE PHENOXY RADICALS

Chapter 5 EFFECTS OF THE SOLVENTS IN THE OXIDATION REACTIONS

5.1. OXIDATION OF UNSATURATED CYCLIC HYDROCARBONS

5.2. OXIDATION OF SATURATED CYCLIC HYDROCARBONS

5.3. OXIDATION OF ALDEHYDES

Chapter 6 THE MEDIUM INFLUENCE ON SOME OTHER HOMOLYTIC REACTIONS

6.1. THE MEDIUM INFLUENCE ON AZOBISISOBUTYRONITRILE (AIBN) DECOMPOSITION

6.2. THE MEDIUM INFLUENCE ON HYDROCARBONS HALOGENATION

6.3. THE EXAMPLES OF OXIDATION BY PERACETIC ACID

CONCLUSIONS

APPENDIX

THE MAIN CHARACTERISTICS OF THE SOLVENTS

INDEX

Blank Page.

Notes:

Description based upon print version of record.

Includes bibliographical references and index.

Description based on print version record and CIP data provided by publisher.

ISBN:

1-61728-243-X

OCLC:

923662562