Functional polymers by post-polymerization modification : concepts, guidelines, and applications / edited by Patrick Theato and Harm-Anton Klok.

Format:

Book

Contributor:

Theato, Patrick.

Klok, Harm-Anton.

Language:

English

Subjects (All):

Polymer engineering.

Polymers--Industrial applications.

Polymers.

Polymerization.

Physical Description:

1 online resource (438 p.)

Edition:

1st ed.

Place of Publication:

Weinheim an der Bergstrasse, Germany : Wiley-VCH Verlag GmbH, c2013.

Language Note:

English

Summary:

Filling the gap for a book dealing with synthetic strategies and recent developments, this volume provides a comprehensive and up-to-date overview of the field of post-polymerization modification. As such, the international team of expert authors covers a wide range of topics, including new synthetic techniques utilizing different reactive groups for post-polymerization modifications of synthetic polymers, as well as modification of biomimetic and biological polymers. Furthermore, industrial applications of polymers that are synthesized by post-polymerization techniques are included.

Contents:

Functional Polymers by Post-Polymerization Modification; Contents; List of Abbreviations; List of Contributors; 1 History of Post-polymerization Modification; 1.1 Introduction; 1.2 Post-polymerization Modification via Thiol-ene Addition; 1.3 Post-polymerization Modification of Epoxides, Anhydrides, Oxazolines, and Isocyanates; 1.4 Post-polymerization Modification of Active Esters; 1.5 Post-polymerization Modification via Thiol-Disulfide Exchange; 1.6 Post-polymerization Modification via Diels-Alder Reactions; 1.7 Post-polymerization Modification via Michael-Type Addition

1.8 Post-polymerization Modification via Azide Alkyne Cycloaddition Reactions 1.9 Post-polymerization Modification of Ketones and Aldehydes; 1.10 Post-polymerization Modifications via Other Highly Efficient Reactions; 1.11 Concluding Remarks; References; 2 Post-polymerization Modifications via Active Esters; 2.1 Introduction; 2.2 Active Esters in the Side Group; 2.2.1 Homopolymers; 2.2.1.1 General; 2.2.1.2 Stimuli-Responsive Polymers; 2.2.1.3 Biologically Active Polymers; 2.2.1.4 Thin Films; 2.2.1.5 Polymeric Ligands for Nanoparticles; 2.2.1.6 Miscellaneous Uses of Active Ester Polymers

2.2.2 Block Copolymers 2.2.2.1 General; 2.2.2.2 Block Copolymers and Inorganic Moieties; 2.2.2.3 Amphiphilic Block Copolymers; 2.2.2.4 Stimuli-Responsive Block Copolymers; 2.3 Star Polymers; 2.4 Active Esters at the End Groups; 2.5 Controlled Positioning of Active Ester Moieties; 2.6 Summary; References; 3 Thiol-ene Based Functionalization of Polymers; 3.1 Introduction; 3.2 General Considerations and Mechanisms; 3.2.1 Radical Thiol-ene Addition; 3.2.2 Nucleophilic Thiol-ene Addition; 3.3 Functionalization of Polymers; 3.3.1 Endfunctionalization; 3.3.1.1 Polymer-ene/Thiol

3.3.1.2 Polymer-SH/Olefin 3.3.2 Polymer-Analog Reactions; 3.3.2.1 Polyene/Thiol; 3.3.2.2 Polythiol/Olefin; 3.3.3 Bioconjugation; 3.4 Summary; Acknowledgments; References; 4 Thiol-yne Chemistry in Polymer and Materials Science; 4.1 Introduction; 4.2 The Thiol-yne Reaction in Small-Molecule Chemistry; 4.3 The Thiol-yne Reaction in Polymer and Material Synthesis; 4.3.1 Network Polymers; 4.3.2 Surface-Initiated Polymerizations and Modifications; 4.3.3 Polymer Beads; 4.3.4 Hyperbranched Polymers; 4.3.5 Dendrimers and Dendritic Polymers; 4.3.6 Main chain a- and w-Functional (co)Polymers

4.3.7 Nonradical Thiol-yne Click Polymerization 4.3.8 Summary and Outlook; References; 5 Design and Synthesis of Maleimide Group Containing Polymeric Materials via the Diels-Alder/Retro Diels-Alder Strategy; 5.1 Introduction; 5.2 Maleimide Functional Group Containing Polymeric Materials; 5.3 The Diels-Alder/Retro Diels-Alder Cycloaddition-Cycloreversion Reactions; 5.4 Application of Diels-Alder/Retro Diels-Alder Reaction to Synthesize Maleimide-Containing Polymers; 5.4.1 Synthesis of Polymers Containing the Maleimide Group at the Chain Termini

5.4.2 Polymers Containing Maleimide Groups as Side Chains

Notes:

Description based upon print version of record.

Includes bibliographical references and index.

ISBN:

9783527655427

3527655425

9781299313538

1299313531

9783527655458

352765545X

9783527655441

3527655441

OCLC:

829460528