Microreactors in organic chemistry and catalysis / edited by Thomas Wirth.

Format:

Book

Contributor:

Wirth, Thomas.

Language:

English

Subjects (All):

Microreactors.

Catalysis.

Chemistry, Organic.

Chemical reactors.

Physical Description:

1 online resource (487 p.)

Edition:

2nd completely rev. and enl. ed.

Place of Publication:

Weinheim, Germany : Wiley-VCH, 2013.

Language Note:

English

Summary:

For this second edition all the chapters have been revised and updated to reflect the latest developments, plus a new chapter on ""Analysis and optimization of reactions"" is now included.It remains a comprehensive publication covering most aspects of the topic. The use of microreactors in homogeneous, heterogeneous as well as biphasic reactions is covered in the main part of the book, together with catalytic approaches. The initial chapters also provide a solid physical chemistry background on fluidics in microdevices. Finally, a chapter on industrial applications and developments covers

Contents:

Microreactors in Organic Chemistry and Catalysis; Contents; Preface to the First Edition; Preface to the Second Edition; List of Contributors; 1 Properties and Use of Microreactors; 1.1 Introduction; 1.1.1 A Brief History of Microreactors; 1.1.2 Advantages of Microreactors; 1.2 Physical Characteristics of Microreactors; 1.2.1 Geometries; 1.2.2 Constructional Materials and Their Properties; 1.3 Fluid Flow and Delivery Regimes; 1.3.1 Fluid Flow; 1.3.2 Fluid Delivery; 1.3.3 Mixing Mechanisms; 1.4 Multifunctional Integration; 1.5 Uses of Microreactors; 1.5.1 Overview

1.5.1.1 Fast and Exothermic Reactions1.5.2 Precision Particle Manufacture; 1.5.3 Wider Industrial Context; 1.5.3.1 Sustainability Agenda; 1.5.3.2 Point-of-Demand Synthesis; References; 2 Fabrication of Microreactors Made from Metals and Ceramic; 2.1 Manufacturing Techniques for Metals; 2.2 Etching; 2.3 Machining; 2.4 Generative Method: Selective Laser Melting; 2.5 Metal Forming Techniques; 2.6 Assembling and Bonding of Metal Microstructures; 2.7 Ceramic Devices; 2.8 Joining and Sealing; References; 3 Microreactors Made of Glass and Silicon; 3.1 How Microreactors Are Constructed

3.1.1 Glass As Material3.1.2 Silicon As Material; 3.2 The Structuring of Glass and Silicon; 3.2.1 Structuring by Means of Masked Etching As in Microsystems Technology; 3.2.2 Etching Technologies; 3.2.2.1 Anisotropic (Crystallographic) Wet Chemical Etching of Silicon (KOH); 3.3 Isotropic Wet Chemical Etching of Silicon; 3.3.1 3.3.1.1 Isotropic Wet Chemical Etching of Silicon; 3.3.1.2 Isotropic Wet Chemical Etching of Silicon Glass; 3.3.2 Other Processes; 3.3.2.1 Photostructuring of Special Glass; 3.3.3 Drilling, Diamond Lapping, Ultrasonic Lapping; 3.3.4 Micro Powder Blasting; 3.3.5 Summary

3.4 Other Processes3.4.1 Sensor Integration; 3.5 Thin Films; 3.6 Bonding Methods; 3.6.1 Anodic Bonding of Glass and Silicon; 3.6.2 Glass Fusion Bonding; 3.6.3 Silicon Direct Bonding (Silicon Fusion Bonding); 3.6.4 Establishing Fluid Contact; 3.7 Other Materials; References; 4 Automation in Microreactor Systems; 4.1 Introduction; 4.2 Automation System; 4.3 Automated Optimization with HPLC Sampling; 4.4 Automated Multi-Trajectory Optimization; 4.5 Kinetic Model Discrimination and Parameter Fitting; 4.6 Conclusions and Outlook; References; 5 Homogeneous Reactions; 5.1 Acid-Promoted Reactions

5.2 Base-Promoted Reactions5.3 Radical Reactions; 5.4 Condensation Reactions; 5.5 Metal-Catalyzed Reactions; 5.6 High Temperature Reactions; 5.7 Oxidation Reactions; 5.8 Reaction with Organometallic Reagents; References; 6 Homogeneous Reactions II: Photochemistry and Electrochemistry and Radiopharmaceutical Synthesis; 6.1 Photochemistry in Flow Reactors; 6.2 Electrochemistry in Microreactors; 6.3 Radiopharmaceutical Synthesis in Microreactors; 6.3.1 Fluorinations in Microreactors; 6.3.2 Synthesis of 11C-Labeled PET Radiopharmaceuticals in Microreactors; 6.4 Conclusion and Outlook; References

7 Heterogeneous Reactions

Notes:

Description based upon print version of record.

Includes bibliographical references and index.

ISBN:

9783527659722

3527659722

9783527659746

3527659749

9781299277090

1299277098

9783527659753

3527659757

OCLC:

830163760