Environmentally harmonious chemistry for the 21st century / Masakazu Anpo and K. Mizuno, editors.

Format:

Book

Contributor:

Anpo, Masakazu.

Mizuno, K. (Kazuhiko)

Series:

Chemical engineering methods and technology.

Chemical engineering methods and technology series

Language:

English

Subjects (All):

Environmental chemistry.

Green chemistry.

Physical Description:

1 online resource (230 p.)

Edition:

1st ed.

Place of Publication:

New York : Nova Science Publishers, c2010.

Language Note:

English

Summary:

Environmental awareness in recycling and limiting toxic emissions are, indeed, important. However, although not generally known, this book introduces a chemical approach to the problem of environmental pollution in which the aim of the work carried out is to recover and protect our environment.

Contents:

Intro

ENVIRONMENTALLY HARMONIOUSCHEMISTRY FOR THE 21ST CENTURY

CONTENTS

PREFACE

BIOANALYTICAL SYSTEMS WITH IN VIVOBIOSENSORS AND MICROFLUIDIC DEVICES

ABSTRACT

1.1. INTRODUCTION

1.2. PRINCIPLE OF BIOANALYTICAL SENSORS

1.3. IN VIVO ANALYSIS OF BIOMOLECULES IN BRAIN,7

1.3.1. The Use of the Enzyme Reactor as a Recognition Element

1.3.1.1. On-Line Amperometric Assay of Glucose, L-Glutamate,and Acetylcholine Using Immobilized Enzyme Reactors [14]

1.3.1.2. An In Vivo Flow-Injection System for the Highly Selectiveand Sensitive Detection of L-Glutamate Using an Enzyme ReactorInvolving Amplification [15-17]

1.3.2. The Use of Biosensors as a Molecular Recognition Sensor

1.3.2.1. Simultaneous In Vivo Monitoring of Glucose, L-Lactate,and Pyruvate Concentrations in the Rat Brain [18, 19]

1.3.2.2. Microdialysis Fiber Enzyme Electrodefor In Vivo Monitoring [20, 21]

1.4. GENERAL ASPECTS OF ANALYTICAL SYSTEMSBASED ON MICROFLUIDIC DEVICES

1.4.1. Characteristics Provided by a Liquid Microspace

1.4.2. Multilayer Flow inside Microchannels

1.5. APPLICATIONS OF MICROFLUIDIC DEVICESFOR ANALYTICAL SYSTEMS

1.5.1. Multi-Ion Analysis System Based on an IntermittentReagent Pumping and Two Layer Flow InsideMicrochannel [29, 30]

1.5.2. Biosensing System Based on an In Situ-FabricatedOrganic Membrane Immobilizing Enzyme [39]

1.6. CONCLUSION

REFERENCES

DEVELOPMENT AND APPLICATION OFFUNCTIONAL INORGANIC MATERIALS

1. INTRODUCTION

2. FUNCTIONAL MATERIALS FROM ALUMINA

3. DEVELOPMENT AND APPLICATION OF GLASS-BASEDSOLID ELECTROLYTES

3.1. Solid Electrolytes

3.2. Sulfide-Based Glass-Ceramic Electrolyteswith Lithium Ion Conduction

4. ALL-SOLID-STATE BATTERIES

4.1. All-Solid-State Lithium Secondary BatteryUsing Sulfide Solid Electrolytes.

4.2. All-Sulfide Batteries - A New Conceptin All-Glass-Based Battery Systems

DEVELOPMENT OF ENVIRONMENTALLYFRIENDLYARTIFICIAL PHOTOSYNTHETICCATALYSTS USING CLEAN AND ABUNDANTSOLAR ENERGY

2. PRINCIPLES OF PHOTOCATALYSIS

Solar Energy Conversion and Environmental Applications

3. THE APPLICATION OF PHOTOCATALYSTS FOR SOLARENERGY CONVERSION AND ENVIRONMENTAL PROTECTION

3.1. Water Splitting Reaction to Produce Pure Hydrogen

3.2. Artificial Photosynthesis: Photocatalytic Reductionof CO2 with H2O

3.3. Direct Photocatalytic Decomposition of NO into N2 and O2

3.4. Applications in the Purification of Water Pollutedwith Various Toxic Compounds Such as Dioxins

3.5. Superhydrophilicity of TiO2 Thin Filmsand Their Application in Self-Cleaning Materials

4. DESIGN OF VISIBLE LIGHT-RESPONSIVETIO2 PHOTOCATALYSTS

4.1. Modification of the Electronic State of TiO2 by Applying anAdvanced Metal Ion-Implantation Method

4.2. Development of Visible Light-Responsive Ti/ZeoliteCatalysts by an Advanced Metal Ion Implantation Method

4.3. Preparation of Visible Light-Responsive TiO2 Thin FilmPhotocatalysts by a RF Magnetron Sputtering Deposition Method

5. SUMMARY

ECO-FRIENDLY ELECTROCHEMICAL DEVICESUSING "WATER" AND "HYDROGEN" AS KEYSUBSTANCES IN THE 21ST CENTURY

INTRODUCTION

NICKEL/METAL HYDRIDE BATTERY

1. Battery Reaction

2. General Features

3. Hydrogen Storage Alloys- Negative Electrode Active Materials

4. Outlook for the Future

FUEL CELLS

3. Classification of Fuel Cells

4. PEFC

5. Outlook for Future

ENVIRONMENTALLY HARMONIOUS ORGANICPHOTOCHEMICAL REACTIONS

5.1. INTRODUCTION

5.2. PHOTOCYCLOADDITION REACTIONS.

5.2.1. Stereoselective Inter- and Intramolecular Photocycloaddition

5.2.2. Construction of PolycyclicCompounds via Intramolecular Photocycloaddition

5.3. PHOTOREACTIONS BY USE OF MICROREACTORS

5.4. PHOTOINDUCED ELECTRON-TRANSFER REACTIONS

5.4.1.1. Photoinduced Carbon-Carbon BondForming Reactions by Use of Organosilicon Compounds

5.4.1.2.Photoinduced Carbon-Carbon BondForming Reactions by Use of Carbon Nucleophiles

5.4.2. Rearrangement and Oxygenation of ArylatedMethylenecyclopropane (MCP) Triggered byPhotoinduced Electron Transfer (PET)

5.4.2.1. PET Degenerate MCP Rearrangement of Arylated MCP

5.4.2.2. PET Oxygenation of Arylated MCP

5.4.3. Thermoluminescence (TL) and Organic Radical Light-Emitting Diode (ORLED) Using Arylated MCP

5.4.3.1. TL Using Arylated MCP

5.4.3.2. ORLED Using Arylated MCP

5.4.3.2.1. Basic Concept of ORLED

5.4.3.2.2. Trial Manufacture of ORLED Using Arylated MCP

5.5. HIGHLY EMISSIVE ORGANOSILICON COMPOUNDS

CONCLUSIONS

CREATION OF NEW ORGANICMOLECULES, NEW REACTIONS BASED ONHETEROATOM CHEMISTRY

1. TRANSITION-METAL-CATALYZED REACTIONSOF HETEROATOM COMPOUNDS[1]

2. PHOTOINDUCED RADICALREACTIONS OF HETEROATOM COMPOUNDS[2]

3. EARLY-TRANSITION-METAL-CATALYZEDOXIDATION WITH MOLECULAR OXYGEN[3]

4. PHOTOINDUCED RARE EARTH REDUCTION SYSTEMS[4]

5. FLUORINATED SOLVENT ANDSYNTHESIS OF FLUOROUS TAGS[5]

6. APPLICATIONS TO MATERIAL SCIENCE[6]

CONCLUSION

UTILIZATION OF LIGHT IN POLYMER SCIENCE

2. PHOTOPOLYMERS

3. REWORKABLE UV CURING MATERIALS[6]

3.1. Base Polymer/Crosslinker Blended System[7]

3.2. Functionalized Polymer System[8-10]

3.3. Multifunctional (Meth)Acrylate System[11]

5. CONCLUSION

POLYMER-BASED NANOMATERIALSFOR DRUG DELIVERY

INTRODUCTION.

STRATEGY OF DRUG TARGETING

POLYMER-DRUG CONJUGATES

POLYMER MICELLES

POLYMER-MODIFIED LIPOSOMES

AN ENVIRONMENTALLY-FRIENDLY PLASTICCOATING TECHNIQUE USING GOLDNANOPARTICLES FOR NANOELECTRONICDEVICE APPLICATIONS

INTRODUCITON

GOLD NANO PARTICLE COATINGON PLASTIC MATERIALS

NANOPARTICLE ARRAY BASED BIOSENSORS

POLYSILANES:NOVEL SIGMA-CONJUGATED POLYMERS

2. SYNTHESIS

2.1. Reductive Coupling Reaction of Dichlorodiorganisilanes

2.2. Dehydrogenative Coupling Reaction of Organosilanes

2.3. Other Polymerization Methods

2.4. Polysilanes Having Functional Organic Groups

2.5. Hybrid Polymers

3. PROPERTIES OF POLYSILANES

3.1. Sigma Conjugation

3.1.1. Electronic Spectra

3.2. Chromotropism of Polysilanes

3.3. Photochemistry of Polysilanes

3.4. Carrier Transport of Polysilanes

3.3. Some Possible Technological Application of Polysilanes

INDEX.

Notes:

Description based upon print version of record.

Includes bibliographical references and index.

ISBN:

1-61324-555-6

OCLC:

744634253