Metal-catalyzed reactions in water / edited by Pierre H. Dixneuf and Victorio Cadierno.

Format:

Book

Contributor:

Dixneuf, P. H. (Pierre H.)

Cadierno, Victorio.

Language:

English

Subjects (All):

Metal catalysts.

Physical Description:

1 online resource (427 p.)

Edition:

1st ed.

Place of Publication:

Weinheim : Wiley-VCH, 2013.

Language Note:

English

Summary:

Water is abundant in nature, non-toxic, non-flammable and renewable and could therefore be safer and economical for the chemical industry wherever it is used as a solvent. This book provides a comprehensive overview of developments in the use of water as a solvent for metal catalysis, illustrating the enormous potential of water in developing new catalytic transformations for fi ne chemicals and molecular materials synthesis. A group of international experts cover the most important metalcatalyzed reactions in water and bring together cutting-edge results from recent literature

Contents:

Metal-Catalyzed Reactions in Water; Copyright Page; Contents; Preface; List of Contributors; 1 Metal-Catalyzed Cross-Couplings of Aryl Halides to Form C-C Bonds in Aqueous Media; 1.1 Introduction; 1.2 Aqueous-Phase Cross-Coupling Using Hydrophilic Catalysts; 1.2.1 Hydrophilic Triarylphosphines and Diarylalkylphospines; 1.2.2 Sterically Demanding, Hydrophilic Trialkyl and Dialkylbiarylphosphines; 1.2.3 NHC Ligands; 1.2.4 Nitrogen Ligands; 1.2.5 Palladacyclic Complexes; 1.3 Cross-Coupling in Aqueous Media Using Hydrophobic Ligands; 1.3.1 Surfactant-Free Reactions

1.3.2 Surfactant-Promoted Reactions1.3.2.1 Cationic Surfactants; 1.3.2.2 Anionic Surfactants; 1.3.2.3 Nonionic Surfactants; 1.4 Heterogeneous Catalysts in Aqueous Media; 1.4.1 Supported Palladium-Ligand Complexes; 1.4.1.1 Polymer-Supported Palladium Complexes; 1.4.1.2 Palladium Complexes Supported on Inorganic Materials; 1.4.2 Nanoparticle-Catalyzed Coupling; 1.4.2.1 Unsupported Palladium Nanoparticle Catalysts; 1.4.2.2 Polymer-Supported Nanoparticles; 1.4.2.3 Inorganic-Supported Nanoparticle Catalysts; 1.5 Special Reaction Conditions; 1.5.1 Microwave Heating; 1.5.2 Ultrasound

1.5.3 Thermomorphic Reaction Control1.6 Homogeneous Aqueous-Phase Modification of Biomolecules; 1.6.1 Amino Acids and Proteins; 1.6.2 Nucleosides and Nucleotides; 1.7 Conclusion; References; 2 Metal-Catalyzed C-H Bond Activation and C-C Bond Formation in Water; 2.1 Introduction; 2.2 Catalytic Formation of C-C Bonds from spC-H Bonds in Water; 2.2.1 Catalytic Nucleophilic Additions of Alkynes in Water; 2.2.2 Addition of Terminal Alkynes to C-C Bonds in Water; 2.2.3 The Sonogashira-Type Reactions in Water; 2.3 Activation of sp2C-H Bonds for Catalytic C-C Bond Formation in Water

2.3.1 Homocoupling of sp2C-H Bonds2.3.2 Direct C-H Bond Arylation of Alkenes and Aryl Boronic Acid Derivatives; 2.3.3 Cross-Coupling Reactions of sp2C-H Bonds with sp2C-X Bonds in Water; 2.3.3.1 Direct C-H Bond Arylations with Aryl Halides and Palladium Catalysts; 2.3.3.2 Direct C-H Bond Arylations with Aryl Halides and Ruthenium Catalysts; 2.3.4 Cross-Coupling Reactions of sp2C-H Bonds with Carbon Nucleophiles in Water; 2.3.5 Oxidative Cross-Coupling of sp2C-H Bond Reactions in Water; 2.3.5.1 Alkenylations of Arenes and Heteroarenes with Palladium Catalysts

2.3.5.2 Alkenylation of Heterocycles Using In(OTf)3 Catalyst2.3.5.3 Alkenylation of Arenes and Heteroarenes with Ruthenium(II) Catalysts; 2.4 Activation of sp3C-H Bonds for Catalytic C-C Bond Formation in Water; 2.4.1 Selective sp3C-H Activation of Ketones; 2.4.2 Catalytic Enantioselective Alkynylation of sp3C-H Bonds; 2.4.3 Cross-Dehydrogenative Coupling between sp3C-H Bonds Adjacent to a Heteroatom; 2.4.4 Catalytic Enolate Carbon Coupling with (Arene) C-X Carbon; 2.4.5 Arylation of sp3C-H Bonds with Aryl Halides or sp2C-H Bond; 2.5 Conclusion; Acknowledgments; References

3 Catalytic Nucleophilic Additions of Alkynes in Water

Notes:

Description based upon print version of record.

Includes bibliographical references and index.

ISBN:

9783527656790

3527656790

9781299157361

129915736X

9783527656820

3527656820

9783527656813

3527656812

OCLC:

826638775