Anion coordination chemistry / edited by Kristin Bowman-James, Antonio Bianchi, Enrique García-Espana.

Format:

Book

Contributor:

Bianchi, Antonio, 1956-

Bowman-James, Kristin, 1946-

García-España, Enrique.

Language:

English

Subjects (All):

Anions.

Supramolecular chemistry.

Physical Description:

1 online resource (575 p.)

Edition:

1st ed.

Place of Publication:

Weinheim : Wiley-VCH, c2012.

Language Note:

English

Summary:

Building on the pioneering work in supramolecular chemistry from the last 20 years or so, this monograph addresses new and recentapproaches to anion coordination chemistry. Synthesis of receptors, biological receptors and metallareceptors, the energetics of anion binding, molecular structures of anion complexes, sensing devices are presented and computational studies addressed to aid with the understanding of the different driving forces responsible for anion complexation. The reader is promised an actual picture of the state of the art for this exciting and constantly evolving field of su

Contents:

Anion Coordination Chemistry; Contents; Preface; List of Contributors; 1 Aspects of Anion Coordination from Historical Perspectives; 1.1 Introduction; 1.2 Halide and Pseudohalide Anions; 1.3 Oxoanions; 1.4 Phosphate and Polyphosphate Anions; 1.5 Carboxylate Anions and Amino Acids; 1.6 Anionic Complexes: Supercomplex Formation; 1.7 Nucleotides; 1.8 Final Notes; References; 2 Thermodynamic Aspects of Anion Coordination; 2.1 Introduction; 2.2 Parameters Determining the Stability of Anion Complexes; 2.2.1 Type of Binding Group: Noncovalent Forces in Anion Coordination

2.2.2 Charge of Anions and Receptors2.2.3 Number of Binding Groups; 2.2.3.1 Additivity of Noncovalent Forces; 2.2.4 Preorganization; 2.2.4.1 Macrocyclic Effect; 2.2.5 Solvent Effects; 2.3 Molecular Recognition and Selectivity; 2.4 Enthalpic and Entropic Contributions in Anion Coordination; References; 3 Structural Aspects of Anion Coordination Chemistry; 3.1 Introduction; 3.2 Basic Concepts of Anion Coordination Chemistry; 3.3 Classes of Anion Hosts; 3.4 Acycles; 3.4.1 Bidentate; 3.4.2 Tridentate; 3.4.3 Tetradentate; 3.4.4 Pentadentate; 3.4.5 Hexadentate; 3.5 Monocycles; 3.5.1 Bidentate

3.5.2 Tridentate3.5.3 Tetradentate; 3.5.4 Pentadentate; 3.5.5 Hexadentate; 3.5.6 Octadentate; 3.5.7 Dodecadentate; 3.6 Cryptands; 3.6.1 Bidentate; 3.6.2 Tridentate; 3.6.3 Tetradentate; 3.6.4 Pentadentate; 3.6.5 Hexadentate; 3.6.6 Septadentate; 3.6.7 Octadentate; 3.6.8 Nonadentate; 3.6.9 Decadentate; 3.6.10 Dodecadentate; 3.7 Transition-Metal-Assisted Ligands; 3.7.1 Bidentate; 3.7.2 Tridentate; 3.7.3 Tetradentate; 3.7.4 Hexadentate; 3.7.5 Septadentate; 3.7.6 Dodecadentate; 3.8 Lewis Acid Ligands; 3.8.1 Transition Metal Cascade Complexes; 3.8.2 Other Lewis Acid Donor Ligands

3.8.2.1 Boron-Based Ligands3.8.2.2 Tin-Based Ligands; 3.8.2.3 Hg-Based Ligands; 3.9 Conclusion; Acknowledgments; References; 4 Synthetic Strategies; 4.1 Introduction; 4.2 Design and Synthesis of Polyamine-Based Receptors for Anions; 4.2.1 Acyclic Polyamine Receptors; 4.2.2 Tripodal Polyamine Receptors; 4.2.3 Macrocyclic Polyamine Receptors with Aliphatic Skeletons; 4.2.4 Macrocyclic Receptors Incorporating a Single Aromatic Unit; 4.2.5 Macrocyclic Receptors Incorporating Two Aromatic Units; 4.2.6 Anion Receptors Containing Separated Macrocyclic Binding Units; 4.2.7 Cryptands

4.3 Design and Synthesis of Amide Receptors4.3.1 Acid Halides as Starting Materials; 4.3.1.1 Acyclic Amide Receptors; 4.3.1.2 Macrocyclic Amide Receptors; 4.3.2 Esters as Starting Materials; 4.3.3 Using Coupling Reagents; References; 5 Template Synthesis; 5.1 Introductory Remarks; 5.2 Macrocyclic Systems; 5.3 Bowl-Shaped Systems; 5.4 Capsule, Cage, and Tube-Shaped Systems; 5.5 Circular Helicates and meso-Helicates; 5.6 Mechanically Linked Systems; 5.7 Concluding Remarks; References; 6 Anion-ð Interactions in Molecular Recognition; 6.1 Introduction; 6.2 Physical Nature of the Interaction

6.3 Energetic and Geometric Features of the Interaction Depending on the Host (Aromatic Moieties) and the Guest (Anions)

Notes:

Description based upon print version of record.

Includes bibliographical references and index.

ISBN:

9783527639519

3527639519

9781283869713

1283869713

9783527639526

3527639527

9783527639502

3527639500

OCLC:

792684103