Terpyridine-based materials : for catalytic, optoelectronic and life science applications / Ulrich S. Schubert, Andreas Winter, and George R. Newkome.

Format:

Book

Author/Creator:

Schubert, U. (Ulrich)

Contributor:

Winter, Andreas.

Newkome, George R. (George Richard)

Language:

English

Subjects (All):

Pyridine.

Physical Description:

1 online resource (544 p.)

Edition:

1st ed.

Place of Publication:

Weinheim, Germany : Wiley-VCH, 2011.

Language Note:

English

Summary:

In recent years, the utilization of terpyridines both in macromolecular structure assembly and device chemistry has exploded, enabling, for example, supramolecular polymer architectures with switchable chemical and physical properties as well as novel functional materials for optoelectronic applications such as light-emitting diodes and solar cells. Further applications include the usage of terpyridines and their metal complexes as catalysts for asymmetric organic reactions and, in a biological context, as anti-tumor agents or biolabels. This book covers terpyridine-based materials topics

Contents:

Terpyridine-based Materials: For Catalytic, Optoelectronic and Life Science Applications; Contents; Preface; List of Abbreviations; 1: Introduction; 2: Synthesis, Properties, and Applications of Functionalized 2,2 ;-Terpyridines; 2.1: Introduction; 2.2: Basic Synthetic Strategies; 2.2.1: Ring-Assembly Methodologies; 2.2.2: Cross-Coupling Procedures; 2.3: Synthesis and Properties of 2,-Terpyridine Derivatives; 2.3.1: 4x2032;-Substituted 2, Terpyridinoxy Derivatives; 2.3.2: Miscellaneous 4;-Substituted 2,2032;-Terpyridine Derivatives

3.3.1: Synthesis of RuII and OsII Bis(terpyridine) Complexes 3.3.2: RuII Ions and Terpyridine Ligands - A Happy Marriage?; 3.3.2.1: Photophysical Properties; 3.3.2.2: Mononuclear RuII Bis(terpyridine) Complexes; 3.3.2.3: Oligonuclear Complexes Containing RuII/OsII Bis(terpyridine) Units; 3.3.2.4: Dendritic and Star-Shaped Systems Containing RuII Bis(terpyridine) Units; 3.4: Iridium(III) Complexes with Terpyridine Ligands; 3.5: Platinum(II) Mono(terpyridine) Complexes; 4: Metallo-Supramolecular Architectures Based on Terpyridine Complexes; 4.1: Introduction

4.2: Terpyridine-Containing Metallo-Macrocycles 4.3: The HETTAP Concept; 4.4: Racks and Grids; 4.5: Helicates; 4.6: Rotaxanes and Catenanes; 4.7: Miscellaneous Structures; 4.7.1: Cyclodextrin Derivatives; 4.7.2: Other Assemblies; 5: CO; -Conjugated Polymers Incorporating Terpyridine Metal Complexes; 5.1: Introduction; 5.2: Metallo-Supramolecular Polymerization; 5.3: Metallopolymers Based on CO; -Conjugated Bis(terpyridine)s; 5.3.1: Polymerization by Transition Metal Ion Coordination; 5.3.2: Self-Assembly of Metallopolymers; 5.3.3: Chiral Metallopolymers; 5.3.4: Non-Classical Metallopolymers

5.3.5: Polymerization Using the ''Complex First'' Method 5.4: Main-Chain Metallopolymers Based on Terpyridine-Functionalized CO; -Conjugated Polymers; 6: Functional Polymers Incorporating Terpyridine-Metal Complexes; 6.1: Introduction; 6.2: Polymers with Terpyridine Units in the Side-Chain; 6.2.1: Materials Based on Flexible Organic Polymers; 6.2.2: Materials Based on CO; -Conjugated Polymers; 6.3: Polymers with Terpyridines within the Polymer Backbone; 6.3.1: Polymers from Organic Small-Molecule Building Blocks; 6.3.2: Chain-Extended Polymers from Polymeric Building Blocks

6.3.3: Monotopic Macroligands by End-Group Functionalization

Notes:

Description based upon print version of record.

Includes bibliographical references and index.

ISBN:

9786613370570

9783527639632

3527639632

9781283370578

1283370573

9783527639625

3527639624

9783527639649

3527639640

OCLC:

768732536