Metal mediated template synthesis of ligands / Otilia Costisor, Wolfgang Linert.

Format:

Book

Author/Creator:

Costisor, Otilia.

Contributor:

Linert, W.

Language:

English

Subjects (All):

Organometallic compounds--Synthesis.

Organometallic compounds.

Organic compounds--Synthesis.

Organic compounds.

Physical Description:

1 online resource (307 p.)

Edition:

1st ed.

Place of Publication:

Singapore ; River Edge, NJ : World Scientific Pub. Co., c2004.

Language Note:

English

Summary:

This book surveys the relatively new area of the synthesis of organic ligands when metal ions act as a template. In the last fifty years this field has undergone an explosive development, marked by a great amount of literature. The material in the book has been arranged according to the type of chemical reaction involved. In this frame, the basic principles of metal template reactions and the shape of the molecules are considered. Designed to satisfy the demands of students, young researchers doing their PhDs, and those working in the field of coordination chemistry, the book details the role

Contents:

Contents ; Preface ; The Template Effect ; 1.1. Types of Template Effects ; 1.2. The Template Effect as a Molecular Organizer Effect ; 1.3. Factors Affecting the Product of a Template Reaction ; 1.3.1. Coordination of ligands ; 1.3.2. The chelate effect ; 1.3.3. Macrocyclic effect

1.4. The Negative Template Effect 1.5. Advantages of Metal Template Reaction ; Alkylation Reactions ; 2.1. Alkylation of the Nitrogen Atom ; 2.2. Alkylation of the Sulfur Atom ; 2.2.1. Open chain systems ; 2.2.2. Macrocyclic ligands ; Schiff Condensation ; 3.1. Mechanistic Aspects

3.2. Open-chain Ligands 3.3. Macrocyclic Ligands ; 3.3.1 Diimine macrocycles ; 3.3.2. Tetraimine macrocycles ; 3.4. Cage Ligands ; 3.5 Compartmental Ligands ; 3.5.1. Closed-chain ligands ; 3.5.2. Open chain ligands ; Mannich Condensation ; 4.1. Mechanistic Aspects

4.2 Acyclic Ligands 4.2.1. Polyamine ligands ; 4.2.2. NO donor ligands ; 4.2.3. SN donor ligands ; 4.3. Monocyclic Ligands ; 4.3.1. Tetraaza macrocycles ; 4.3.2. Pentaaza macrocycles ; 4.3.3. Hexaaza macrocycles ; 4.3.4. Octaaza macrocycles ; 4.3.5. Azaether macrocycle

4.3.6. Azathioether macrocycle 4.3.7. Reinforced macrocycles ; 4.3.8. Macromonocyclic dicompartmental ligands ; 4.4. Isolated Dimacrocycles ; 4.5.Condensed Polymacrocyclic Ligands ; 4.5.1. Carbon and nitrogen caped amine ligands ; 4.5.2. P- As amine cage ligands

4.5.3. Thioamine cage ligands

Notes:

Description based upon print version of record

Includes bibliographical references (p. 257-294) and index.

ISBN:

9786611934705

9781281934703

1281934704

9789812794819

9812794816

OCLC:

815752366