Chemistry and technology of carbodiimides / Henri Ulrich.

Format:

Book

Author/Creator:

Ulrich, Henri, 1925-

Language:

English

Subjects (All):

Carbodiimides.

Physical Description:

1 online resource (312 p.)

Edition:

1st ed.

Place of Publication:

Chichester, England ; Hoboken, NJ : John Wiley & Sons, 2007.

Language Note:

English

Summary:

Carbodiimides play an important role as condensation agents in the synthesis of polypeptides, polynucleotides, polysaccharides and numerous other chemical transformations. Chemistry and Technology of Carbodiimides is the first book to examine both the chemistry and technology of carbodiimides. This book provides a comprehensive and in-depth coverage of the synthesis and reactions of this industrially important class of chemicals while focusing on industrial applications, including the M-sectors of biochemical synthesis, pharmaceuticals, polymers, ceramics, and herbicides. Written by a w

Contents:

Chemistry and Technology of Carbodiimides; Contents; Preface; Acknowledgements; 1 General Introduction; 1.1 References; 2 Alkyl- and Arylcarbodiimides; 2.1 Introduction; 2.2 Synthesis of Alkyl- and Arylcarbodiimides; 2.2.1 From Thioureas, Isothioureas and Selenoureas; 2.2.2 By Dehydration of Ureas; 2.2.3 From Isocyanates or Isothiocyanates; 2.2.4 From Cyanamides; 2.2.5 By Nitrene Rearrangements; 2.2.6 From Haloformamidines or Carbonimidoyl Dihalides; 2.2.7 By Thermolysis Reactions; 2.2.8 By Miscellaneous Other Methods; 2.3 References I; 2.4 Reactions of Alkyl- and Arylcarbodiimides

2.4.1 Oligomerization and Polymerization2.4.2 Cycloaddition Reactions; 2.4.3 Reaction of Ylides with Carbodiimides; 2.4.4 Insertion Reactions; 2.4.5 Nucleophilic Reactions; 2.4.6 Heterocycles from Carbodiimides; 2.4.7 Use of Carbodiimides In Condensation Reactions; 2.4.8 Miscellaneous Reactions; 2.5 References II; 3 Unsaturated Carbodiimides; 3.1 Introduction; 3.2 Synthesis of Unsaturated Carbodiimides; 3.2.1 From Thioureas; 3.2.2 From Unsaturated Isocyanates; 3.2.3 From Unsaturated Iminophosphoranes and Isocyanates or Isothiocyanates; 3.2.4 By Other Methods

3.3 Reactions of Unsaturated Carbodiimides3.3.1 Polymerization Reactions; 3.3.2 Cycloaddition Reactions; 3.3.3 Other Reactions; 3.4 References; 4 Halogenated Carbodiimides; 4.1 Introduction; 4.2 Synthesis of Halogenated Carbodiimides; 4.2.1 From -Haloisocyanates; 4.2.2 By Halogenation of Carbodiimides; 4.2.3 From Carbonimidoyl Dichlorides or Imidoyl Chlorides; 4.2.4 By Other Methods; 4.3 Reactions of Halogenated Carbodiimides; 4.3.1 Cycloaddition Reactions; 4.3.2 Nucleophilic Reactions; 4.3.3 Other Reactions; 4.4 References; 5 Acyl-, Thioacyl- and Imidoylcarbodiimides; 5.1 Introduction

5.2 Synthesis of Acyl-, Thioacyl- and Imidoylcarbodiimides5.2.1 From Thioureas; 5.2.2 From Ureas; 5.2.3 From Isocyanates; 5.2.4 From Carbonimidoyl Dichlorides or Chloroformamidines; 5.2.5 From Cyanamides; 5.2.6 From Other Carbodiimides; 5.2.7 By Other Methods; 5.3 Reactions of Acyl-, Thioacyl- and Imidoylcarbodiimides; 5.3.1 Cycloaddition Reactions; 5.3.2 Other Reaction; 5.4 References; 6 Silicon Substituted Carbodiimides; 6.1 Introduction; 6.2 Synthesis of Silicon Substituted Carbodiimides; 6.2.1 From Cyanamides; 6.2.2 From Ureas; 6.2.3 From Isocyanates and Isothiocyanates

6.2.4 From Silylamines6.2.5 From Other Carbodiimides; 6.2.6 By Other Methods; 6.3 Reactions of Silicon Substituted Carbodiimides; 6.3.1 Oligomerization Reactions; 6.3.2 Cycloaddition Reactions; 6.3.3 Other Reactions; 6.4 References; 7 Nitrogen Substituted Carbodiimides; 7.1 Introduction; 7.2 Synthesis of Nitrogen Substituted Carbodiimides; 7.3 Reactions of Nitrogen Substituted Carbodiimides; 7.4 References; 8 Phosphorous Substituted Carbodiimides; 8.1 Introduction; 8.2 Synthesis of Phosphorous Substituted Carbodiimides; 8.2.1 From Thioureas; 8.2.2 From Iminophosphoranes

8.2.3 From Carbonimidoyl Dichlorides

Notes:

Description based upon print version of record.

Includes bibliographical references and index.

Description based on metadata supplied by the publisher and other sources.

ISBN:

9786612237539

9781282237537

1282237535

9780470516683

0470516682

9780470516676

0470516674

OCLC:

609844468