Polymer materials for energy and electronic applications / Huisheng Peng, Xuemei Sun, Wei Weng, Xin Fang, Department of Macromolecular Science and Laboratory of Advanced Materials at Fudan University, Shanghai, China.

Format:

Book

Author/Creator:

Peng, Huisheng, author.

Sun, Xuemei, 1967- author.

Weng, Wei, 1962- author.

Fang, Xin, author.

Language:

English

Subjects (All):

Polymers--Electric properties.

Polymers.

Energy harvesting--Materials.

Energy harvesting.

Energy storage--Materials.

Energy storage.

Materials.

Physical Description:

xii, 373 pages : illustrations (some colour) ; 24 cm

Place of Publication:

London ; San Diego, CA : Academic Press is an imprint of Elsevier, [2017]

Summary:

Polymer Materials for Energy and Electronic Applications carefully highlights the main advancements in polymer materials for their electronic applications. It overviews the features of polymers and their applications in energy and electronics, and introduces the synthesis, structures, and properties of polymers as well as composites. It describes four families of electronic devices based on polymers: energy harvesting devices, energy storage devices, light-emitting devices, and electrically driving sensors. Flexible electronic devices are particularly highlighted to demonstrate the importance of polymers in electronics. Provides a basic understanding of the structure and morphology of polymers and their electronic properties and applications, Highlights the current applications of conducting polymers on energy harvesting and storage, Introduces the emerging flexible and stretchable electronic devices, and adds a new family of fiber-shaped electronic devices Book jacket.

Contents:

1 Introduction 1

1.1 History of Polymers 1

1.2 Energy Harvesting Based on Polymers 2

1.3 Energy Storage Based on Polymers 3

1.4 Light Emitting and Sensing Devices Based on Polymers 4

1.5 Flexible Energy and Electronic Devices Based on Polymers 5

1.6 Challenges and Perspectives 5

1.6.1 Stability 6

1.6.2 Electrical Conductivity 6

1.6.3 Temperature Tolerance 6

1.6.4 Scale-up Production 7

References 7

2 Synthesis and Design of Conjugated Polymers for Organic Electronics 9

2.1 Synthesis of Conjugated Polymers 9

2.1.1 Introduction 9

2.1.2 Common Methods for Constructing Carbon-Carbon Double Bond 9

2.1.3 Common Methods for Constructing Carbon-Carbon Single Bond 14

2.1.4 Conclusion 26

2.2 Design of Conjugated Polymers for Organic Electronics 26

2.2.1 Introduction 26

2.2.2 Rational Design of High-Performance Conjugated Polymers for PSCs 27

2.2.3 Rational Design of High-Performance Conjugated Polymers for PLEDs 38

2.2.4 Rational Design of Conjugated Polymers for Electrochromic Devices 46

2.2.5 Conclusions 52

References 52

3 Structure and Property of Electronic Polymers 63

3.1 Introduction 63

3.2 Aggregation Structure 63

3.2.1 Amorphous 64

3.2.2 Crystalline 64

3.3 Morphology of Assembly 67

3.3.1 Nanoparticle 67

3.3.2 Nanofiber 69

3.3.3 Solid Film 72

3.3.4 Porous Film 74

3.3.5 Polymer Gel 77

3.4 Properties 79

3.4.1 Mechanical Properties 79

3.4.2 Electronic Properties 81

3.4.3 Electrochemical Properties 82

3.4.4 Electroluminescent Properties 85

3.4.5 Electrochromic Properties 87

3.4.6 Electromechanical Properties 89

3.4.7 Stability 91

3.4.8 Biocompatibility 93

3.5 Summary 95

References 97

4 Electronic Polymer Composite 107

4.1 Synthesis 107

4.1.1 Direct Mixing 107

4.1.2 In Situ Polymerization in Inorganic Matrix 111

4.1.3 In Situ Growth of Inorganic Component in Polymer Matrix 112

4.1.4 One-Pot Synthesis 113

4.1.5 Multicomponent Preparation 115

4.2 Structure 116

4.2.1 Continuous Structure 116

4.2.2 Separated Structure 120

4.3 Property 127

4.3.1 Mechanical Property 127

4.3.2 Electrical Property 129

4.3.3 Electrochemical Property 131

4.3.4 Electroluminescent Property 135

4.3.5 Sensing 137

4.4 Summary 141

References 142

5 Energy Harvesting Based on Polymer 151

5.1 Introduction 151

5.2 Photovoltaic Device 151

5.2.1 Working Mechanism 152

5.2.2 Polymer as Light Harvesting Material 154

5.2.3 Polymer as Charge Transport Material 162

5.3 Thermoelectric Generator 164

5.3.1 Working Mechanism 164

5.3.2 Conducting Polymers for Thermoelectric Generator 166

5.3.3 Coordination Polymers for Thermoelectric Generator 172

5.3.4 Polymer Composite for Thermoelectric Generator 172

5.4 Piezoelectric Transducer 174

5.4.1 Working Mechanism 175

5.4.2 Materials 177

5.4.3 Poling Process 177

5.4.4 Morphology and Performance 179

5.5 Triboelectric Generator 181

5.5.1 Working Mechanism 181

5.5.2 Materials 184

5.5.3 Application 187

5.6 Perspective 188

References 189

6 Energy Storage Devices Based on Polymers 197

6.1 Introduction 197

6.2 Supercapacitor 198

6.2.1 Polymer-Based Electrode 199

6.2.2 Polymer-Based Electrolyte 211

6.3 Lithium-Ion Batteries Based on Polymers 215

6.3.1 Polymers as Active Materials in Electrode 216

6.3.2 Polymers as Separators 223

6.3.3 Polymers as Electrolytes 230

6.4 Summary 233

References 233

7 Light Emitting Based on Polymer 243

7.1 Light-Emitting Conjugated Polymers 243

7.1.1 Introduction 243

7.1.2 Photophysics of Conjugated Polymer 243

7.1.3 Categories of Light-Emitting Conjugated Polymers 245

7.2 Polymer Light-Emitting Diodes 247

7.2.1 Introduction 247

7.2.2 Structure and Mechanism 249

7.2.3 Performance 251

7.2.4 Functionality 262

7.3 Polymer Light-Emitting Electrochemical Cells 265

7.3.1 Introduction 265

7.3.2 Mechanism 266

7.3.3 Structure 269

7.3.4 Performance 270

7.3.5 Functionality 274

7.4 Summary 280

References 280

8 Electrically Driving Sensors Based on Polymer 287

8.1 Electromechanical Actuators 287

8.1.1 Electrostatically Driving Actuators 287

8.1.2 Electrochemicalfy Driving Actuators 291

8.1.3 Electrothermally Driving Actuators 296

8.1.4 Conclusions and Perspectives 300

8.2 Electrochromic Materials and Devices 302

8.2.1 Electro-Induced Oxidation-Reduction Mechanism 302

8.2.2 Electrothermal Chromatic Mechanism 307

8.2.3 Other Electrochromic Mechanisms 311

8.2.4 Conclusions and Perspectives 315

References 316

9 Flexible Electronic Devices Based on Polymers 325

9.1 Introduction 325

9.2 Flexible Energy Harvesting Devices Based on Polymers 325

9.2.1 Flexible Solar Cells Based on Polymers 326

9.2.2 Flexible Piezoelectric Devices Based on Polymers 329

9.3 Flexible Energy Storage Devices Based on Polymers 331

9.3.1 Flexible Supercapacitors Based on Polymers 331

9.3.2 Flexible Lithium-Ion Batteries Based on Polymer 334

9.4 Flexible Light-Emitting Devices Based on Polymer 338

9.5 Flexible Electrochromic Devices Based on Polymers 340

9.6 Flexible Fiber-Shaped Electronic Devices 342

9.6.1 Fiber-Shaped Energy Harvesting Devices 343

9.6.2 Fiber-Shaped Light-Emitting Devices 345

9.6.3 Fiber-Shaped Energy Storage Devices 346

9.7 Perspective 349

References 349

10 Summary and Perspective 355.

Notes:

Includes bibliographical references and index.

ISBN:

9780128110911

0128110910

OCLC:

959910029