Metallized and magnetic polymers : chemistry and applications / Johannes Karl Fink.

Format:

Book

Author/Creator:

Fink, Johannes Karl, author.

Language:

English

Subjects (All):

Polymers--Magnetic properties.

Polymers.

Metal coating.

Physical Description:

xii, 230 pages ; 24 cm

Place of Publication:

Hoboken, New Jersey : John Wiley & Sons, Inc., [2016]

Summary:

Metallized and Magnetic Polymers focuses on the chemistry of metallized and magnetic polymers, as well as the special applications of these materials. After an introductory section on the general aspects of the field, the types and uses of these polymers are detailed, followed by an overview of the testing methods. The book is divided equally into two parts - metallized polymers and magnetic polymers - and both parts follow the same structure: All methods of fabrication, Properties and methods of measurement including standard test methods and interface properties, Fields of applications, Environmental issues including recycling and biodegradable polymers, The book is complemented by three indices: an index of acronyms, an index of chemicals, and a general index. Audience, The book will be used by researchers and engineers in chemistry, polymer science, materials science, and the biomedical sciences. Book jacket.

Contents:

Part I Metallized Polymers 1

1 General Aspects 3

1.1 History 4

1.1.1 Capacitors 4

References 5

2 Methods of Fabrication 7

2.1 Methods for Metallizing 7

2.1.1 Laminating 7

2.1.2 Wet Plating 7

2.1.3 Fluid Electrolytic Deposition 8

2.1.4 Plating-out Method 10

2.1.5 Retroplating-out Method 11

2.1.6 Electroless Plating 11

2.1.7 Vacuum Deposition 12

2.1.8 Sputtering 13

2.1.9 Paint Coating 13

2.1.10 Pressure-Sensitive Conductive Rubber 14

2.1.11 Grafting of Polyelectrolytes 16

2.1.12 Selective Deposition of Metal onto Plastic Substrates 16

2.2 Welding 16

2.2.1 Ultrasonic Welding of Metallized Plastic 16

2.3 Molding 17

2.3.1 Molded Products 17

2.3.2 Metallized Plastic Molding 21

2.4 Special Aspects 22

2.4.1 Metallized Polymer Granules 22

2.4.2 Functional Poly(propylene) 27

2.4.3 Poly(amide) 28

2.4.4 Poly(imide)s 29

2.4.5 Poly(amide-imide)s 32

2.4.6 Poly(acetylene)s 32

2.4.7 Silaferrocenophanes 34

2.4.8 Metallized Hybrid Polymers 34

2.4.9 Radiation Curable Compositions 35

2.4.10 Heat Treatment 36

2.5 Special Uses 37

2.5.1 Films for Packaging Oxygen-Sensitive Materials 37

2.5.2 Margin Pattern Forming 39

2.5.3 Surface Reflectors 40

2.5.4 Electrical Applications 41

References 45

3 Properties and Methods of Measurement 49

3.1 Standard Test Methods 49

3.1.1 Requirements for Decorative Coatings 50

3.1.2 Corrodkote Method 50

3.1.3 Copper-Accelerated Salt Spray Test 50

3.1.4 Visual Defects 51

3.1.5 Peel Strength 51

3.1.6 Thickness 52

3.1.7 Adhesion 52

3.1.8 Thermal Cycling 52

3.1.9 Water Resistance 52

3.2 Interface Properties 53

3.2.1 Morphology 53

3.2.2 Sliding Wear 54

3.2.3 Promoting Adhesion 54

3.3 Combustion of Metallized Polymers 56

3.3.1 Cobalt Nanoparticles 56

References 58

4 Fields of Application 61

4.1 Shielding Electromagnetic Interference 61

4.2 Microwave Components 63

4.3 Conductive Fibers 64

4.4 Intermetallic Layers 65

4.5 Metallized Polymer Mirror 66

4.5.1 Poly(urethane) Insulating Fluid 66

4.6 In-Mold Metallized Polymer Articles 67

4.7 Camera Housing 68

4.8 Metallized Polymer Film Capacitors 70

4.9 Micro-fuel Cell 70

4.10 Printed Circuit Boards 71

4.10.1 Solderable Metallized Plastic Contact 71

4.10.2 Polymer Compositions for Metallized Polymers 72

4.10.3 Metallized Films 76

4.10.4 Pattern Forming 79

4.10.5 Pressure-Sensitive Conducting Film 81

4.10.6 Polymer with Finely Dispersed Metal Particles 83

4.10.7 Flexible Metallized Polymer Film 86

4.11 Electrostatic Miniature Valve 87

4.12 Antennas 87

4.12.1 Antenna Reflector 87

4.12.2 Rear Projection Television Receiver Mirrors 90

4.12.3 Metallized Foams 91

4.13 Gas Transmission 92

4.13.1 Oxygen Barrier 92

4.14 Micromechanical Sensor and Actuator Devices 93

4.15 Medical Uses 94

4.15.1 Leadwires and Intrafascicular Microelectrodes 94

References 95

5 Environmental Issues 99

5.1 Recycling 99

5.2 Metallized Plastic Packages 100

5.3 Biodegradable Metallized Polymers 102

References 102

Part II Magnetic Polymers 103

6 General Aspects 105

6.1 General Aspects 106

6.2 Basic Issues of Magnetism 108

6.3 Types of Magnetic Organic Polymers 109

6.3.1 Organic Radicals in the Side Chains 111

References 113

7 Methods of Fabrication 115

7.1 Preparation of Magnetic Polymer Particles 115

7.1.1 Coprecipitation 115

7.1.2 Superparamagnetic Substances 116

7.1.3 Conventional Processes 118

7.1.4 Iron Salt Modification 119

7.1.5 Fluorescent Magnetic Polymer Particles 121

7.2 Special Types 124

7.2.1 Spherical Iron Nanoparticles 124

7.2.2 Magnetic Polymer Latex 124

7.2.3 Imprinted Polymer Particles 128

7.2.4 Magnetic Polymers from Maghemite and Poly(vinyl alcohol) 129

7.2.5 Ethylenediamine-Functionalized Magnetic Polymers 129

7.2.6 Magnetic Fluids 130

7.2.7 Magnetic Ceramic Thin Films 130

7.2.8 Iron-Schiff-Base Magnetic Polymers 131

7.2.9 Bisverdazyl Diradicals 131

7.2.10 Non-Kekulé Biradicals 132

7.2.11 m-Chloroaniline for Magnetic Polymers 133

7.2.12 Porous Magnetic Polymer Microspheres 133

7.2.13 Magnetic Nanoporous Coordination Polymers 134

7.2.14 Magnetic Polymer Composites 135

7.2.15 Polymer-Coated Magnetic Particles 136

7.2.16 Magnetic Polymers with High Curie Temperature 138

7.2.17 Shaped Ceramics 138

7.2.18 Magnetic Polymer Microbeads 140

References 142

8 Properties and Methods of Measurement 145

8.1 Standard Test Methods 145

8.2 Phase Diagram of Magnetic Polymers 146

8.3 Adsorption Mechanism of Amino-Functionalized Magnetic Polymers 147

8.4 Cyano-Bridged Coordination Polymers 147

8.5 Spin-Glass Behavior in Some Schiff-Base Co-containing Magnetic Polymers 148

8.6 Neutron Scattering from Magnetic Polymers 148

8.7 Shape-Memory Effect 149

References 149

9 Fields of Application 151

9.1 Improvement of Drilling Performance 151

9.1.1 Wall Coating 154

9.1.2 Magnetically Controlled Delivery 155

9.2 Electronic Uses 155

9.2.1 High Frequency Transformers 155

9.2.2 Electrophotography 157

9.2.3 High Performance Magnetic Toner 167

9.3 Biotechnology 174

9.3.1 Alcohol Production by Magnetic Immobilized Yeast 174

9.3.2 Solid Acidic Catalysts 174

9.3.3 Supports for Biological Molecules 174

9.4 Medical Uses 177

9.4.1 Zero-Valent Nanoparticles 177

9.4.2 Drug Targeting 177

9.4.3 Stimuli - Responsive Polymers 178

9.4.4 Magnetic Drug Carriers 178

9.4.5 Surface Effects 182

9.4.6 Superparamagnetic Iron Oxide Nanoparticles 182

9.4.7 Magnetized Scleral Buckle 183

9.4.8 Magnetic Polymer Carriers 185

9.4.9 Magnetically-Controllable Delivery System for Therapeutic Agents 185

9.4.10 Magnetic Polymer Scaffolds 187

9.4.11 Theranostic Nanoparticles 188

9.4.12 Biodegradable Polymer Composites 188

9.4.13 Nanoencapsulation Methods 188

9.4.14 Uniform Field Magnetization 189

9.4.15 Nanomagnetic Actuation of Molecular Cell Signaling 192

9.4.16 Aerosol Therapy 193

9.4.17 Magnetofection 195

References 200

10 Environmental Issues 207

10.1 Analysis Methods 207

10.1.1 Fluoroquinolone Antibiotics in Environmental Water 207

10.1.2 Determination of Endocrine-Disrupting Compounds 208

10.1.3 Selective Recognition of Neodymium(III) 210

10.1.4 Bisphenol A 210

10.1.5 Sub-ppb Analysis of Dissolved Copper 211

10.1.6 Polycyclic Aromatic Hydrocarbons 211

10.1.7 Magnetic Graphene for Phthalate Analysis 212

10.2 Magnetic Polymers in Water Treatment 213

10.2.1 Carbon Dioxide Capturing 214

10.2.2 Separation of Metals from Wastewater 214

10.2.3 Polymer Support for Nanoscale Inorganic Particles 215

10.2.4 Selective Extraction of Pb(II) from Environmental Samples 215

10.2.5 Chromium Removal from Aqueous Solutions 216

10.2.6 Magnetic Zeolite-Polymer Composite 216

10.2.7 Binding of Nitrate and Nitrite 217

References 217.

Notes:

Includes bibliographical references and index.

ISBN:

9781119242321

1119242320

OCLC:

936349575