Nitrenes and nitrenium ions / edited by Daniel E. Falvey, Anna D. Gudmundsdottir.

Format:

Book

Contributor:

Falvey, Daniel E., 1961-

Gudmundsdottir, Anna D., 1962-

Series:

Wiley series on reactive intermediates in chemistry and biology

Wiley series of reactive intermediates in chemistry and biology

Language:

English

Subjects (All):

Nitrenes.

Nitrogen compounds.

Physical Description:

xii, 586 pages : illustrations (some color) ; 24 cm.

Place of Publication:

Hoboken, NJ : Wiley, 2013.

Summary:

"Nitrenes and Nitrenium ions are reactive intermediates with monovalent nitrogen atoms. These intermediates have diverse reactivity and physical properties, depending on their structure and spin state. The leading experts in nitrene chemistry have contributed to this book to highlight how spectroscopy and calculations have been used to characterize various nitrene intermediates. Emphasizes have also been placed on identifying the diverse methods to form these intermediates. Furthermore, the reactivity of nitrenes and nitrenium ions is discussed in details and how the reactivity can be used in various applications"-- Provided by publisher.

Contents:

1 Ultrafast Time-Resolved Studies of the Photochemistry of Aryl Azides / Jin Wang Wang, Jin, Gotard Burdzinski Burdzinski, Gotard, Matthew S. Platz Platz, Matthew S. 1

2 Theory and Computation in the Study of Nitrenes and their Excited-State Photoprecursors / Shubham Vyas Vyas, Shubham, Arthur H. Winter Winter, Arthur H., Christopher M. Hadad Hadad, Christopher M. 33

3 Nitrenium Ions and Related Species in Photoaffinity Labeling / R. Marshall Wilson Wilson, R. Marshall, Valentyna Voskresenska Voskresenska, Valentyna 77

4 Aryl Nitrenium Ions in Aqueous Solution / Michael Novak Novak, Michael, Yue-Ting Wang Wang, Yue-Ting 117

5 Triplet Alkyl Nitrenes / Sivaramakrishnan Muthukrishnan Muthukrishnan, Sivaramakrishnan, Ranaweera A. A. U. Ranaweera Ranaweera, Ranaweera A. A. U., Anna D. Gudmundsdottir Gudmundsdottir, Anna D. 167

6 Electronic Properties of Nitrenium Ions / Daniel E. Falvey Falvey, Daniel E. 191

7 Time-Resolved Resonance Raman Spectroscopic Studies of Aryl Nitrenium Ions and their Chemical Reactions / David Lee Phillips Phillips, David Lee 217

8 Matrix Studies on Aromatic and Heteroaromatic Nitrenes and their Rearrangements / Curt Wentrup Wentrup, Curt 273

9 Nitreno Radicals / Dirk Grote Grote, Dirk, Wolfram Sander Sander, Wolfram 317

10 Synthetic Applications of Nitrenium Ions / Duncan J. Wardrop Wardrop, Duncan J., Edward G. Bowen Bowen, Edward G. 347

11 Fluorinated Aryl Nitrene Precursors / Elisa Leyva Leyva, Elisa, Denisse de Loera Loera, Denisse de, Socorro Leyva Leyva, Socorro, Rogelio Jimenez-Cataño Jimenez-Cataño, Rogelio 451

12 Properties of Carbonyl Nitrenes and Related Acyl Nitrenes / Nina P. Gritsan Gritsan, Nina P. 481.

Notes:

Includes bibliographical references and index.

Machine generated contents note: Preface Contributors Introduction Chapter 1. Ultrafast Studies of Azides and Nitrenes Jin Wang, Matthew S. Platz, The Ohio State University, Ohio, Gotard Burdzinski, Adam Mickiewicz University Poland Chapter 2. Computational Studies of Nitrenes and their Excited State Precursors Subham Vyas, Arthur H. Winter, Christopher M. Haddad, The Ohio State University, Ohio Chapter 3. Nitrenium Ions in Photoaffinity Labeling R. Marshall Wilson, Valentyna Voskresenska Bowling Green State University, Ohio Chapter 4. Nitrenium Ions in Aquoeous Solution Mike Novak, Yue-Ting Wang Miami University, Ohio Chapter 5 Triplet Alkylnitrenes Sivaramakrishnan Muthukrishnan, Ranaweera A.A.U. Ranaweera, Anna D. Gudmundsdottir, University of Cincinnati, Ohio Chapter 6. Electronic Structures of Nitrenium Ions Dan Falvey, University of Maryland, Maryland Chapter 7. Raman Studies of Nitrenium Ions David Lee Phillips, University of Hong Kong, Hong Kong Chapter 8. Matrix Studies of Heterocyclic Nitrenes Curt Wentrup University of Queensland, Australia Chapter 9. Dehydroaromatic Nitrenes Dirk Grote Wolfram Sander, Ruhr-Universitat Bochum, Germany Chapter 10. Synthetic Applications of Nitrenium Ions Duncan Wardrop, University of Illinois-Chicago, Illinois Chapter 11. Flourinated Nitrene Precursors Elisa Leyva, Denisse de Loera Socorro Leyva Jimenez-Catano, Univ. Autonoma San Luis Potosi, San Luis Potosi, Mexico Chapter 12. Acylnitrenes Nina Gritsan, Institute of Chemical Kinetics and Combustion Novosibirsk, Russia Index.

Other Format:

Online version: Nitrenes and nitrenium ions.

ISBN:

9780470390597

047039059X

OCLC:

828833476

Online:

Cover image