Carbon meta-nanotubes : synthesis, properties, and applications / [editor] Marc Monthioux.

Format:

Book

Contributor:

Monthioux, Marc.

Language:

English

Subjects (All):

Nanostructured materials.

Nanotubes.

Organic compounds--Synthesis.

Organic compounds.

Physical Description:

xx, 426 pages, 12 unnumbered pages of color plates : illustrations (some color) ; 25 cm

Place of Publication:

Chichester, West Sussex : Wiley-Blackwell, 2012.

Summary:

"The book will present different chapters corresponding to each of the meta-nanotube categories. There will be an introductory chapter that will provide the basics of what is needed to be known about pristine nanotubes to understand what is in the subsequent chapters. Each of the chapters that follow the introductory chapter will cover aspects from synthesis to applications, characterization, behavior, properties, and mechanisms. These chapters will focus on heterogeneous nanotubes, doped nanotubes, functionalized nanotubes, coated nanotubes and hybrid nanotubes, respectively, and will be followed by a final concluding chapter"-- Provided by publisher.

Contents:

1 Introduction to Carbon Nanotubes / Marc Monthioux Monthioux, Marc 7

1.1 Introduction 7

1.2 One Word about Synthesizing Carbon Nanotubes 7

1.3 SWCNTs: The Perfect Structure 11

1.4 MWCNTs: The Amazing (Nano)Textural Variety 18

1.5 Electronic Structure 29

1.6 Some Properties of Carbon Nanotubes 31

1.7 Conclusion 35

References 35

2 Doped Carbon Nanotubes: (X:CNTs) / Alain Pénicaud Pénicaud, Alain, Pierre Petit Petit, Pierre, John E. Fischer Fischer, John E. 41

2.1 Introduction 41

2.1.1 Scope of this Chapter 41

2.1.2 A Few Definitions 42

2.1.3 Doped/Intercalated Carbon Allotropes-a Brief History 43

2.1.4 What Happens upon Doping SWCNTs? 48

2.2 n-Doping of Nanotubes 52

2.2.1 Synthetic Routes for Preparing Doped SWCNTs 52

2.2.2 Crystalline Structure and Chemical Composition of n-Doped Nanotubes 54

2.2.3 Modification of the Electronic Structure of SWCNTs upon Doping 59

2.2.4 Electrical Transport in Doped SWCNTs 61

2.2.5 Spectroscopic Evidence for n-Doping 65

2.2.6 Solutions of Reduced Nanotubes 72

2.3 p-Doping of Carbon Nanotubes 73

2.3.1 p-Doping of SWCNTs with Halogens 74

2.3.2 p-Doping with Acceptor Molecules 80

2.3.3 p-Doping of SWCNTs with FeCl3 84

2.3.4 p-Doping of SWCNTs with SOCL2 87

2.3.5 p-Doping of SWCNTs with Acids 87

2.3.6 p-Doping of SWCNTs with Superacids 91

2.3.7 p-Doping with other Oxidizing Agents 95

2.3.8 Diameter Selective Doping 96

2.4 Practical Applications of Doped Nanotubes 99

2.5 Conclusions, Perspectives 100

References 101

3 Functionalized Carbon Nanotubes: (X-CNTs) / Stephane Campidelli Campidelli, Stephane, Stanislaus S. Wong Wong, Stanislaus S., Maurizio Prato Prato, Maurizio 113

3.1 Introduction 113

3.2 Functionalization Routes 113

3.2.1 Noncovalent Sidewall Functionalization of SWCNTs 114

3.2.2 Covalent Functionalization of SWCNTs 114

3.3 Properties and Applications 125

3.3.1 Electron Transfer Properties and Photovoltaic Applications 125

3.3.2 Chemical Sensors (FET-Based) 137

3.3.3 Opto-Electronic Devices (FET-Based) 139

3.3.4 Biosensors 145

3.4 Conclusion 149

References 150

4 Decorated (Coated) Carbon Nanotubes: (X/CNTs) / Revathi R. Bacsa Bacsa, Revathi R., Philippe Serp Serp, Philippe 163

4.1 Introduction 163

4.2 Metal-Nanotube Interactions - Theoretical Aspects 166

4.2.1 Curvature-Induced Effects 168

4.2.2 Effect of Defects and Vacancies on the Metal-Graphite Interactions 169

4.3 Carbon Nanotube Surface Activation 170

4.4 Methods for Carbon Nanotube Coating 171

4.4.1 Deposition from Solution 171

4.4.2 Self-Assembly Methods 178

4.4.3 Electro- and Electrophoretic Deposition 183

4.4.4 Deposition from Gas Phase 187

4.4.5 Nanoparticles Decorating Inner Surfaces of Carbon Nanotubes 190

4.5 Characterization of Decorated Nanotubes 191

4.5.1 Electron Microscopy and X-ray Diffraction 191

4.5.2 Spectroscopic Methods 192

4.5.3 Porosity and Surface Area 196

4.6 Applications of Decorated Nanotubes 196

4.6.1 Sensors 196

4.6.2 Catalysis 198

4.6.3 Fuel Cells 202

4.6.4 Hydrogen Storage 204

4.7 Decorated Nanotubes in Biology and Medicine 205

4.8 Conclusions and Perspectives 207

References 208

5 Filled Carbon Nanotubes 223

5.1 Presentation of Chapter 5 223

5a Filled Carbon Nanotubes: (X@CNTs) / Jeremy Sloan Sloan, Jeremy, Marc Monthioux Monthioux, Marc 225

5a.1 Introduction 225

5a.2 Synthesis of X@CNTs 227

5a.2.1 A Glimpse at the Past 227

5a.2.2 The Expectations with Filling CNTs 228

5a.2.3 Filling Parameters, Routes and Mechanisms 229

5a.2.4 Materials for Filling 240

5a.2.5 Filling Mechanisms 245

5a.3 Behaviours and Properties 247

5a.3.1 Peculiar in-Tube Behaviour (Diffusion, Coalescence, Crystallization) 247

5a.3.2 Electronic Properties (Transport, Magnetism and Others) 252

5a.4 Applications (Demonstrated or Expected) 256

5a.4.1 Applications that Make Use of Mass Transport Properties 256

5a.4.2 Applications Arising as a Result of Filling 258

Acknowledgements 261

References 261

5b Fullerenes inside Carbon Nanotubes: The Peapods / Ferenc Simon Simon, Ferenc, Marc Monthioux Monthioux, Marc 273

5b.1 Introduction 273

5b.2 The Discovery of Fullerene Peapods 274

5b.3 Classification of Peapods 277

5b.4 Synthesis and Behavior of Fullerene Peapods 279

5b.4.1 Synthesis of Peapods 279

5b.4.2 Behavior of Peapods under Various Treatments 289

5b.5 Properties of Peapods 295

5b.5.1 Structural Properties 295

5b.5.2 Peapod Band Structure from Theory and Experiment 298

5b.5.3 Transport Properties 301

5b.5.4 Optical Properties 302

5b.5.5 Vibrational Properties 303

5b.5.6 Magnetic Properties 305

5b.6 Applications of Peapods 308

5b.6.1 Demonstrated Applications 308

5b.6.2 Expected Applications 310

Acknowledgements 314

References

6 Heterogeneous Nanotubes: (X*CNTs, X*BNNTs) / Dmitri Golberg Golberg, Dmitri, Mauricio Terrones Terrones, Mauricio 323

6.1 Overall Introduction 323

6.2 Pure BN Nanotubes 324

6.2.1 Introduction 324

6.2.2 Synthesis of BN Nanotubes 325

6.2.3 Morphology and Structure of BN Nanotubes 331

6.2.4 Properties of BN Nanotubes 337

6.2.5 Stability of BN Nanotubes to High-Energy Irradiation 346

6.2.6 Boron Nitride Meta-Nanotubes 346

6.2.7 Other BN Nanomaterials 353

6.2.8 Challenging Applications 355

6.3 B_x C_y N_z Nanotubes and Nanofibers 359

6.3.1 Tuning the Electronic Structure with C-Substituted BN Nanotubes 359

6.3.2 Production and Characterization of B_xC_yN_z Nanotubes and Nanofibers 362

6.4 B-Substituted or N-Substituted Carbon Nanotubes 368

6.4.1 Substituting Carbon Nanotubes with B or N 368

6.4.2 Synthesis Strategies for Producing B- or N-Substituted CNTs 370

6.4.3 Morphology and Structure of Substituted CNTs 374

6.4.4 Properties of Substituted CNTs 379

6.4.5 Applications of Substituted CNTs 385

6.5 Perspectives and Future Outlook 392

Acknowledgements 394

References 395.

Notes:

Includes bibliographical references and index.

ISBN:

9780470512821

0470512822

OCLC:

721928302

Online:

Publisher description