Chemical thermodynamics at a glance / H. Donald Brooke Jenkins.

Format:

Book

Author/Creator:

Jenkins, H. Donald Brooke.

Series:

At a glance series (Oxford, England)

At a glance

Language:

English

Subjects (All):

Thermodynamics.

Chemical equilibrium.

Entropy.

Thermochemistry.

Physical Description:

vii, 195 pages : illustrations ; 30 cm.

Place of Publication:

Oxford ; Malden, MA : Blackwell Pub., 2008.

Contents:

Thermodynamic changes, properties and types of function

Integration in thermodynamics

Graphical gradients and intercepts

The ideal gas

Partial derivatives simplified

Logarithms and exponentials

Thermodynamics conventions

Heat and work. First Law of Thermodynamics

Work of expansion

Internal energy, U and enthalpy, H

Reference states

Bond enthalpy (energy)

Spontaneity, entropy and Gibbs energy

Entropy and Second Law

Calculation of entropy

The Third Law of Thermodynamics

The statistical definition of entropy

Variation of G with T (dP = 0)

Variation of H and S with T (dP = 0)

Variation of G and S with P (dP = 0)

Variation of G with T for solid, liquid and gaseous phase

Variation of H with T for solid , liquid and gaseous phase

Effect of pressure on melting point and boiling point : normal substances

Effect of pressure on melting point and boiling point : water

Phase equilibria. Clapeyron equation

Clausius-Clapeyron equation

Open systems. Chemical potential. Chemical reactions

Coupled reactions

Chemical potentials applied to physical processes

The Phase Rule

Ideal and real gases. Dalton's Law of Partial Pressures

Ideal liquid mixtures. Vapour pressure and Raoult's Law

Ideal liquid mixtures. Real liquid mixtures

Binary liquid mixtures

Chemical potentials and equilibrium relationships

Interpretation of logarithmic term. Molality

Thermodynamics of ideal mixing

Chemical potentials of real gases. Fugacity

Chemical potentials of real solutions. Activity

Measurement of equilibrium constant, K

Reaction quotient, Q and equilibrium constant, K. Relationship between deltaG⁰ and Kp/p⁰

Chemical equilibrium

K for a multiphase reaction

Reactions not at equilibrium

Equilibrium calculations for reactions not initially at equilibrium

Gibbs-Helmholtz equation

Qualitative interpretation of Van't Hoff equation. Coupled reaction

Variation of equilibrium constant, K, with overall total pressure, P

Le Chatelier's Principle

Gibbs-Duhem equation

Colligative properties : freezing point

Colligative properties : boiling point

Colligative properties : osmotic pressure

Core thermodynamic relationships.

Notes:

Includes index.

ISBN:

9781405139977

1405139978

9780632040414

0632040416

OCLC:

85018892

Online:

Contributor biographical information

Publisher description