Activation and functionalization of C-H bonds / Karen I. Goldberg, editor, Alan S. Goldman, editor ; sponsored by the ACS Division of Inorganic Chemistry, Inc.

Format:

Book

Contributor:

Goldberg, Karen I., 1962-

Goldman, Alan S., 1958-

American Chemical Society. Division of Inorganic Chemistry.

American Chemical Society. Meeting 2002 : Orlando, Fla.)

Alumni and Friends Memorial Book Fund.

Series:

ACS symposium series ; 885.

ACS symposium series ; 885

Language:

English

Subjects (All):

Hydrocarbons--Congresses.

Hydrocarbons.

Activation (Chemistry)--Congresses.

Activation (Chemistry).

Organometallic compounds--Congresses.

Organometallic compounds.

Catalysis--Congresses.

Catalysis.

Genre:

Conference papers and proceedings.

Physical Description:

xiv, 440 pages : illustrations ; 24 cm.

Place of Publication:

Washington, DC : American Chemical Society : Distributed by Oxford University Press, [2004]

Contents:

1. Organometallic C-H Bond Activation: An Introduction / Alan S. Goldman, Karen I. Goldberg 1

Oxidative Addition Reactions

2. C-H Bond Activation by Iridium and Rhodium Complexes: Catalytic Hydrogen-Deuterium Exchange and C-C Bond-Forming Reactions / Steven R. Klei, Kian L. Tan, Jeffrey T. Golden, Cathleen M. Yung, Reema K. Thalji, Kateri A. Ahrendt, Jonathan A. Ellman, T. Don Tilley, Robert G. Bergman 46

3. Alkane Complexes as Intermediates in C-H Bond Activation Reactions / William D. Jones, Andrew J. Vetter, Douglas D. Wick, Todd O. Northcutt 56

4. C-C versus C-H Bond Oxidative Addition in PCX (X=P,N,O) Ligand Systems: Facility, Mechanism, and Control / Boris Rybtchinski, David Milstein 70

5. Kinetic and Equilibrium Deuterium Isotope Effects for C-H Bond Reductive Elimination and Oxidative Addition Reactions Involving the Ansa-Tungstenocene Methyl-Hydride Complex [Me subscript 2 Si(C subscript 5 Me subscript 4) subscript 2]W(Me)H / Kevin E. Janak, David G. Churchill, Gerard Parkin 86

6. Alkane C-H Bond Activation by O-Donor Ir Complexes / Gaurav Bhalla, Xiang Yang Liu, Antek Wong-Foy, C. J. Jones, Roy A. Periana 105

7. Lanthanide Complexes: Electronic Structure and H-H, C-H, and Si-H Bond Activation from a DFT Perspective / Lionel Perrin, Laurent Maron, Odile Eisenstein 116

C-H Bond Activations in Organic Synthesis, Alkane Dehydrogenation, and Related Chemistry

8. Catalytic, Thermal, Regioselective Functionalization of Alkanes and Arenes with Borane Reagents / John F. Hartwig 136

9. C-H Bond Functionalization in Complex Organic Synthesis / Dalibor Sames 155

10. Pincer and Chelate N-Heterocyclic Carbene Complexes of Rh, Ir, and Pd: Synthetic Routes, Dynamics, Catalysis, Abnormal Binding, and Counterion Effects / Anthony R. Chianese, Robert H. Crabtree 169

11. Sequential Hydrocarbon C-H Bond Activations by 16-Electron Organometallic Complexes of Molybdenum and Tungsten / Peter Legzdins, Craig B. Pamplin 184

12. Alkane Transfer-Dehydrogenation Catalyzed by a Pincer-Ligated Iridium Complex / Alan S. Goldman, Kenton B. Renkema, Margaret Czerw, Karsten Krogh-Jespersen 198

13. DFT Calculations on the Mechanism of (PCP)Ir-Catalyzed Acceptorless Dehydrogenation of Alkanes: Realistic Computational Models and Free Energy Considerations / Karsten Krogh-Jespersen, Margaret Czerw, Alan S. Goldman 216

14. Double Cyclometalation: Implications for C-H Oxidative Addition with PCP Pincer Compounds of Iridium / Hani A. Y. Mohammad, Jost C. Grimm, Klaus Eichele, Hans-Georg Mack, Bernd Speiser, Filip Novak, William C. Kaska, Hermann A. Mayer 234

Activation of C-H Bonds by Pt(II) (Shilov) Chemistry

15. C-H Bond Activation at Pt(II): A Route to Selective Alkane Oxidation? / Alan F. Heyduk, H. Annita Zhong, Jay A. Labinger, John E. Bercaw 250

16. Competitive Trapping of Equilibrating Pt(IV) Hydridoalkyl and Pt(II) Alkane Complexes: A Valuable Tool for the Mechanistic Investigation of C-H Activation Reactions / Mats Tilset, Lars Johansson, Martin Lersch, Bror J. Wik 264

17. Mechanisms of Reactions Related to Selective Alkane Oxidation by Pt Complexes / Jennifer L. Look, Ulrich Fekl, Karen I. Goldberg 283

18. Hydrocarbon C-H Bond Activation with Tp'Pt Complexes / Cynthia M. Norris, Joseph L. Templeton 303

19. C-H Bond Activation with Neutral Platinum Methyl Complexes / Carl N. Iverson, Charles A. G. Carter, John D. Scollard, Melanie A. Pribisko, Kevin D. John, Brian L. Scott, R. Tom Baker, John E. Bercaw, Jay A. Labinger 319

20. Issues Relevant to C-H Activation at Platinum(II): Comparative Studies between Cationic, Zwitterionic, and Neutral Platinum(II) Compounds in Benzene Solution / Jonas C. Peters, J. Christopher Thomas, Christine M. Thomas, Theodore A. Betley 334

Oxidations

21. Non-Organometallic Mechanisms for C-H Bond Oxidation: Hydrogen Atom versus Electron versus Hydride Transfer / James M. Mayer, Anna S. Larsen, Jasmine R. Bryant, Kun Wang, Mark Lockwood, Gordon Rice, Tae-Jin Won 356

22. Oxidation of Organic Molecules with Molecular Oxygen Catalyzed by Heterometallic Complexes / Patricia A. Shapley 370

23. Catalytic Hydrocarbon Oxidations Involving Coreductants / Joseph E. Remias, Ayusman Sen 379

24. New Applications of Electrophilic Aromatic C-H Activation with Metal Trifluoroacetates / Vladimir V. Grushin, David L. Thorn, William J. Marshall, Viacheslav A. Petrov 393

25. Reengineering of Organic-Based Metal Active Sites for Oxidations and Oxygenations / Sergiu M. Gorun 407.

Notes:

Includes bibliographical references and indexes.

Local Notes:

Acquired for the Penn Libraries with assistance from the Alumni and Friends Memorial Book Fund.

ISBN:

0841238499

OCLC:

54356679