Corrosion of ceramic and composite materials / Ronald A. McCauley.

Format:

Book

Author/Creator:

McCauley, Ronald A., 1942-

Contributor:

McCauley, Ronald A., 1942-

Alumni and Friends Memorial Book Fund.

Series:

Corrosion technology (New York, N.Y.) ; 22.

Corrosion technology ; 22

Language:

English

Subjects (All):

Ceramic materials--Corrosion.

Ceramic materials.

Composite materials--Corrosion.

Composite materials.

Physical Description:

xiii, 405 pages : illustrations ; 24 cm.

Edition:

Second edition.

Place of Publication:

New York : M. Dekker, [2004]

Contents:

2.2 Corrosion by Liquids 11

2.2.2 Crystalline Materials 15

2.2.3 Glasses 47

2.3 Corrosion by Gas 56

2.3.1 Crystalline Materials 56

2.3.2 Vacuum 63

2.3.3 Glasses 64

2.4 Corrosion by Solid 65

2.5 Surface Effects 67

2.5.1 Surface Charge 67

2.5.2 Porosity and Surface Area 68

2.5.3 Surface Energy 71

2.6 Acid/Base Effects 77

2.7 Thermodynamics 78

2.7.1 Mathematical Representation 79

2.7.2 Graphical Representation 85

2.8 Kinetics 91

2.9 Diffusion 100

3 Methods of Corrosion Analysis 123

3.2 Laboratory Test vs. Field Trials 124

3.3 Sample Selection and Preparation 126

3.4 Selection of Test Conditions 129

3.5 Characterization Methods 130

3.5.1 Microstructure and Phase Analysis 130

3.5.2 Chemical Analysis 134

3.5.3 Physical Property Measurement 136

3.6 Data Reduction 139

4 Corrosion Test Procedures 143

4.2 ASTM Standards 149

4.3 Nonstandard Tests 162

5 Corrosion of Specific Crystalline Materials 165

5.1 Attack by Liquids 165

5.1.1 Attack by Glasses 165

5.1.2 Attack by Aqueous Solutions 177

5.1.3 Attack by Molten Salts 191

5.1.4 Attack by Molten Metals 197

5.2 Attack by Gases 201

5.2.1 Oxides 202

5.2.2 Nitrides and Carbides 209

5.2.3 Borides 231

5.2.4 Silicides 233

5.2.5 Superconductors 234

5.3 Attack by Solids 234

5.3.1 Silica 234

5.3.2 Magnesia 235

5.3.3 Superconductors 235

5.3.4 Attack by Metals 236

6 Corrosion of Specific Glassy Materials 257

6.2 Silicate Glasses 258

6.3 Borosilicate Glasses 271

6.4 Lead-Containing Glasses 275

6.5 Phosphorus-Containing Glasses 276

6.6 Fluoride Glasses 278

6.7 Chalcogenide-Halide Glasses 280

7 Corrosion of Composite Materials 291

7.2 Reinforcement 295

7.2.1 Fibers 295

7.2.2 Fiber Coatings or Interphases 298

7.2.3 Particulates 299

7.3 Ceramic Matrix Composites 300

7.3.1 Oxide-Matrix Composites 301

7.3.2 Nonoxide-Matrix Composites 309

7.4 Metal Matrix Composites 316

7.5 Polymer Matrix Composites 318

8 Properties and Corrosion 333

8.2 Mechanisms 337

8.2.1 Crystalline Materials 337

8.2.2 Glassy Materials 339

8.3 Degradation of Specific Materials 345

8.3.1 Degradation by Oxidation 345

8.3.2 Degradation by Moisture 352

8.3.3 Degradation by Other Atmospheres 352

8.3.4 Degradation by Molten Salts 354

8.3.5 Degradation by Molten Metals 358

8.3.6 Degradation by Aqueous Solutions 358

9 Methods to Minimize Corrosion 373

9.2 Crystalline Materials

Oxides 374

9.2.1 Property Optimization 374

9.2.2 External Methods of Improvement 379

9.3 Crystalline Materials

Nonoxides 382

9.3.1 Property Improvement 382

9.3.2 External Methods of Improvement 384

9.4 Glassy Materials 385

9.4.1 Property Optimization 385

9.4.2 External Methods of Improvement 385.

Notes:

"The first edition was Corrosion of ceramics (Dekker, 1994)"--T.p. verso.

Includes bibliographical references and index.

Local Notes:

Acquired for the Penn Libraries with assistance from the Alumni and Friends Memorial Book Fund.

Related Work:

McCauley, Ronald A., 1942- Corrosion of ceramics.

ISBN:

0824753666

OCLC:

55858249