Silicon chemistry : from the atom to extended systems / Peter Jutzi, Ulrich Schubert (eds.).

Format:

Book

Contributor:

Jutzi, Peter.

Schubert, U. (Ulrich)

Language:

English

Subjects (All):

Silicon.

Silicon compounds.

Physical Description:

xi, 494 pages : illustrations ; 25 cm

Place of Publication:

Weinheim : Wiley-VCH, [2003]

Summary:

The combined results from an international research project involving 40 interdisciplinary groups, providing the latest knowledge from the past few years. Adopting an application-oriented approach, this handy reference is a must-have for every silicon chemist, whether working in inorganic, organic, physical or polymer chemistry, materials science or physics.

Contents:

I Reactive Intermediates in Silicon Chemistry

Synthesis, Characterization, and Kinetic Stabilization

Investigations on the Reactivity of Atomic Silicon: A Playground for Matrix Isolation Spectroscopy / G. Maier, H. P. Reisenauer, H. Egenolf, J. Glatthaar 4

Reactions with Matrix Isolated SiO Molecules / H. Schnockel, R. Koppe 20

In situ

Diagnostics of Amorphous Silicon Thin Film Deposition / H. Stafast, G. Andra, F. Falk, E. Witkowicz 33

The Gas Phase Oxidation of Silyl Radicals by Molecular Oxygen: Kinetics and Mechanism / T. Kocher, C. Kerst, G. Friedrichs, F. Temps 44

Oxidation of Matrix-Isolated Silylenes / W. Sander, H. F. Bettinger, H. Bornemann, M. Trommer, M. Zielinski 58

Short-Lived Intermediates with Double Bonds to Silicon: Synthesis by Flash Vacuum Thermolysis, and Spectroscopic Characterization / H. Beckers 71

Kinetic Stabilization of Disilenes [greater than sign]Si=Si[less than sign] and Disilynes -Si[identical with]Si- / N. Wiberg 85

A Tetrasilabuta-1,3-diene and Related Compounds with Conjugated Multiple Bonds / M. Weidenbruch 100

II Si-Si-Systems: From Molecular Building Blocks to Extended Networks

Chemistry of Metalated Oligosilanes / R. Fischer, D. Frank, C. Kayser, C. Mechtler, J. Baumgartner, C. Marschner 118

Oligosilyl Substituted Heptaphosphanes

Syntheses, Reactions and Structures / J. Baumgartner, V. Cappello, A. Dransfeld, K. Hassler 129

Polysilanes: Formation, Bonding and Structure / R. G. Jones 139

Phase Behavior of n-Alkylsubstituted Polysilanes / C. Mueller, C. Peter, H. Frey, C. Schmidt 159

Structural and Electronic Systematics in Zintl Phases of the Tetrels / R. Nesper 171

Zintl Phases Msi[superscript 2] (M = Ca, Eu, Sr, Ba) at Very High Pressure / J. Evers, G. Oehlinger 181

Silicon- and Germanium-Based Sheet Polymers and Zintl Phases / M. S. Brandt, G. Vogg, M. Stutzmann 194

Kautsky-Siloxene Analogous Monomers and Oligomers / H. Stuger 214

Silicon-Based Nanotubes: A Theoretical Investigation / Th. Kohler, G. Seifert, Th. Frauenheim 226

Structure and Reactivity of Solid SiO / U. Schubert, T. Wieder 242

Si Nanocrystallites in SiO[subscript x] Films by Vapour Deposition and Thermal Processing / H. Hofmeister, U. Kahler 252

Theoretical Treatment of Silicon Clusters / A. Sax 269

Isomers of Neutral Silicon Clusters / R. Schafer, M.l Rosemeyer, C. Herwig, J. A. Becker 281

Investigation of the Influence of Oxidation and HF Attack on the Photoluminescence of Silicon Nanoparticles / F. Huisken, G. Ledoux, O. Guillois, C. Reynaud 293

Localization Phenomena and Photoluminscence from Nano-structured Silicon, Silicon/Silicon Dioxide Nanocomposites, Silsesquioxanes and Branched Polysilanes / S. Veprek, D. Azinovic 308

III Si-O Systems: From Molecular Building Blocks to Extended Networks

Higher-Coordinate Silicon Compounds with SiO[subscript 5] and SiO[subscript 6] Skeletons: Syntheses and Crystal Structures / R. Tacke, O. Seiler 324

Functionalized Silanols and Silanolates / S. Kliem, C. Reiche, U. Klingebiel 338

Transition Metal Fragment Substituted Silanols of Iron and Tungsten

Synthesis, Structure and Condensation Reactions / W. Malisch, M. Hofmann, M. Vogler, D. Schumacher, A. Sohns, H. Bera, H. Jehle 348

Rational Syntheses of Cyclosiloxanes and Molecular Alumo- and Gallosiloxanes / M.l Veith, A. Rammo 360

Synthesis, Structure and Reactivity of Novel Oligomeric Titanasiloxanes / P. Jutzi, H. M. Lindemann, J.-O. Nolte, M. Schneider 372

Metallasilsesquioxanes

Synthetic and Structural Studies / F. T. Edelmann 383

Spin-Spin Interaction in Silsesquioxanes and Transition Metal Substitution / W. W. Schoeller, D. Eisner 395

Characterization of Si-polymers by Coupling of HPLC-Separation Methods with MALDI-TOF-MS / J. Falkenhagen, R.-P. Kruger, G. Schulz 406

The Stepwise Formation of Si-O-Networks / M. Binnewies, N. Soger 419

Mechanism of Ring and Cage Formation in Siloxanes / K.l Jug 431

Structurally Well-Defined Amphiphilic Polysiloxane Copolymers / G. Kickelbick, J. Bauer, N. Husing 439

Synthesis and Functionalization of Mesostructured Silica-Based Films / N. Husing, B. Launay, G. Kickelbick 451

Modification of Ordered Mesostructured Materials during Synthesis / S. Altmaier, P. Behrens 460

Biosilicification; Structure, Regulation of Structure and Model Studies / C. C. Perry 475.

Notes:

Includes bibliographical references and index.

ISBN:

3527306471

OCLC:

51840320