EPR of free radicals in solids : trends in methods and applications / edited by Anders Lund and Masaru Shiotani.

Format:

Book

Contributor:

Lund, A. (Anders)

Shiotani, M. (Masaru), 1940-

Series:

Progress in theoretical chemistry and physics ; v. 10.

Progress in theoretical chemistry and physics ; v. 10

Language:

English

Subjects (All):

Electron paramagnetic resonance.

Free radicals (Chemistry).

Solid state physics.

Physical Description:

xvii, 644 pages : illustrations ; 25 cm.

Place of Publication:

Dordrecht ; Boston : Kluwer Academic, [2003]

Contents:

Part I Trends in Methods 1

Chapter 1. Continuous wave EPR of radicals in solids / Anders Lund, Wei Liu 3

2. Radical Structure

3. Saturation Properties of Radicals

4. Internal Motion of Radicals

5. Diffusion of Radicals

Chapter 2. Pulsed EPR of paramagnectic centers in solid phases / Marina Brustolon, Antonio Barbon 39

2. Theory

3. The Determination of Electron Spin Longitudinal Relaxation

4. The Determination of Electron Spin Transverse Relaxation

5. The Determination of Hyperfine Interactions

Chapter 3. Dynamical effects in CW and pulsed EPR / Nikolas P. Benetis 95

2. Types of Dynamical Processes Accessible by EPR

3. Selected Examples of Conformational Reorganization and Libration

4. Fundamental Dynamical Parameters

5. Magnetic Relaxation

6. Chemical Exchange

7. Inertial Effects of Rotation

8. Dynamics by CW-ENDOR Spectroscopy

9. Pulsed-EPR Techniques

10. Librational Motion Studied by ED-EPR

Chapter 4. Quantum effects in deuterium labelled radicals at low temperature / Masaru Shiotani, Kenji Komaguchi 153

2. High Resolution ESR and Nuclear Spin-Rotation Coupling of Methyl Radicals

3. Hydrogen Atom - Hydrogen Molecule Pair Formation in Argon

4. Para-Hydrogen Molecule and High Resolution ESR Spectra

5. Jahn-Teller Distortion of T[subscript d] and D[subscript 3h] Molecules and H/D Isotope Effects

6. Deuterium Isotope Effects on Methyl Hydrogen Conformation

7. Static and Dynamic Structures of Cyclohexane and Related Radical Cations

8. Hydrogen Atom Abstraction Via Tunnelling

Chapter 5. XSophe - Sophe - XeprView: A computer simulation software suite for the analysis of continuous wave EPR spectra / Graeme R. Hanson, Kevin E. Gates, Christopher J. Noble, Anthony Mitchell, Simon Benson, Mark Griffin, Kevin Burrage 197

2. The XSophe X-Window Graphical User Interface

3. Sophe

4. Role of Frequency (and Temperature) in Extracting Spin Hamiltonian Parameters

5. Future Directions for Xsophe

Chapter 6. The calculation of the hyperfine coupling tensors of biological radicals / Fuqiang Ban, James W. Gauld, Stacey D. Wetmore, Russell J. Boyd 239

3. Theoretical Studies of Amino Acid Radicals

Chapter 7. Ab initio and density functional calculations of electronic g-tensors for organic radicals / Martin Kaupp 267

2. The Hamiltonian

3. Quantum Chemical Approaches

4. Performance of Ab Initio and DFT Methods, Validation Studies

5. Applications to Biologically Relevant Radicals

Chapter 8. Radiolabelled radicals derived from volatile organic compounds (VOCs) sorbed on reactive surfaces: implications for atmospheric chemistry and pollution control / Christopher J. Rhodes 303

2. Methods

3. Zeolites and Clay Surfaces

4. Carbon Particles

Part II Trends in Applications 335

Chapter 9. EPR studies of atomic impurities in rare gas matrices / Henrik Kunttu, Jussi Eloranta 337

2. Experimental Techniques

3. Atomic Impurities in Rare Gas Matrices

4. Theoretical Treatments for Atomic Impurities

Chapter 10. Organic radical cations and neutral radicals produced by radiation in low-temperature matrices / Vladimir Feldman 363

2. Experimental Approaches and Overview of Results

3. Positive Hole Migration and Trapping

4. Matrix Effects on Trapping and Reactions of Radical Cations

5. Selectivity of the Primary Radiation-Induced Chemical Events

Chapter 11. Molecule-based exchange-coupled high-spin clusters / Takeji Takui, Hideto Matsuoka, Kou Furukawa, Shigeaki Nakazawa, Kazunobu Sato, Daisuke Shiomi 407

3. Spectral Simulation Based on a Hybrid Eigenfield Method and Perturbation Treatments

4. Solution ESR Spectroscopy for Molecular High-Spin Systems with Exchange Interaction Comparable to Hyperfine Interactions

5. High Spin Chemistry of Various Molecular Clusters; Utilization of High-Field/High-Frequency ESR and Pulsed ESR Spectroscopy

6. Metal High-Spin Clusters of Biological Importance; Manganese Clusters in Photosystem II

Chapter 12. High spin molecules directed towards molecular magnets / Martin Baumgarten 491

2. Biradicals

the Triplet State

3. Triradicals - the Quartet State

4. Tetraradicals- the Quintet State

5. Higher Spin States, S [greater than or equal] 5/2

Chapter 13. Electron transfer and structure of plant photosystem II / Asako Kawamori 529

2. Methods Applied to Photosynthesis

3. Sample Preparations

4. Studied Components

5. Structure of PS II; Comparison with X-ray Analysis

Chapter 14. Recent development of EPR dosimetry / Nicola D. Yordanov, Veselka Gancheva 565

2. Principles of EPR Dosimetry as a Method for Estimation of the Absorbed Dose and for Post Radiation Processing Detection

3. Solid State/EPR Dosimeters

4. Trends in the Future Studies on SS/EPR Dosimeters

5. Identification of Radiation Processing of Foodstuffs by EPR

6. Detection of Pharmaceuticals Sterilized by High Energy Radiation

7. Emergency Dosimetry

Chapter 15. Optically detected magnetic resonance of defects in semiconductors / Weimin M. Chen 601

2. Background of the Odmr Technique

3. Varieties of the Odmr Technique

4. Applications of the Odmr Technique

5. Recent Developments and Trends.

Notes:

Includes bibliographical references and index.

ISBN:

1402012497

OCLC:

52047275