Fire resistant and thermally stable materials derived from chlorinated polyethylene / A.A. Donskoi, M.A. Shashkina and G.E. Zaikov.

Format:

Book

Author/Creator:

Donskoi, A. A.

Contributor:

Shashkina, M. A. (Margarita Aleksandrovna)

Zaikov, G. E. (Gennadiĭ Efremovich), 1935-

Series:

New concepts in polymer science

New concepts in polymer science.

Language:

English

Subjects (All):

Fire resistant materials.

Physical Description:

v, 225 pages : illustrations ; 25 cm.

Place of Publication:

Utrecht, Netherlands ; Boston, Mass. : VSP, 2003.

Summary:

Donskoi, M. A. Shashkina (both: Institute of Aviation Materials, Moscow) and G. E. Zaikov (biochemical physics, Russian Academy of Sciences) take advantage of the relatively freer publishing climate in post-Soviet Russia to present data on the development of polymeric materials with reduced combustibility that can be used for heat shields in aviation. They focus on chlorinated polyolefins as organic polymers. The study might interest graduate students, engineers, and scientists working in material science and engineering, especially those dealing with new polymeric materials for aircraft, ships, or automobiles. Distributed in the US by Brill. Annotation (c)2003 Book News, Inc., Portland, OR (booknews.com)

Contents:

1. Combustion of polymeric materials and methods to reduce it. The mechanism of fire and heat shield covers 5

2. Investigation methods for fire and heat shield materials and covers based on them 31

3. Chlorinated polymers as the base for materials with reduced combustibility 41

3.1. Current state of chlorinated polyolefins production and application 42

3.1.1. Chlorination methods 42

3.1.2. Structure and properties 48

4. Vulcanization 67

4.1. Vulcanization effect on physical and mechanical properties and stability of materials 67

4.2. Study of vulcanization mechanism and the effect of fillers 79

5. Fillers 89

5.1. Inorganic fillers and their function in decreasing combustibility 91

5.2. Organic compounds increasing fire shield properties of materials 100

5.3. Combustion decelerators. Operation mechanism and injection methods 102

5.4. Methods of antipyren injection into materials 107

5.5. Application of phosphorus-containing compounds on the silicon dioxide surface from the liquid phase 112

5.6. Obtaining of phosphorus-containing silica filler by mechanochemical method 115

5.7. Study of biological activity of phosphorus-containing silicon dioxides 117

5.8. Study of fire and heat shield properties of materials filled with modified silicon dioxide 119

6. Plasticizers 123

6.1. Influence of plasticizers on glass transition temperature and flow rate of polymers 124

6.2. Classification of plasticizers 130

6.3. Selection of plasticizers 130

6.3.1. Miscibility of plasticizers with polymers 131

6.3.2. Plasticizer effect on mechanical, fire and heat shield, and electrical properties of composite materials 131

7. Tests of materials. Study of operation mechanism at high-temperature influence 134

7.1. Coke formation as the investigation method of fire and heat shield materials and covers 135

7.2. The role of intumescence in the problem of fire protection of polymers 138

7.2.1. Intumescence chemistry 138

7.2.2. Protection through intumescence 139

7.2.3. The role of ammonium polyphosphates in protection of polymers from fire 141

8. Development of fire and heat shield materials 156

9. Climatic natural and artificial aging of materials 170

10. Multilayer materials for increasing efficiency of covers 176

10.1. Materials with surface reinforcement 176

10.2. Heat-accumulating materials in cover compositions 177

10.3. Estimation of thermophysical properties of heat-accumulating materials 186

11. Tests of materials as covers for flight information recorders under conditions modeling an accident 192.

Notes:

Includes bibliographical references and index.

ISBN:

9067643734

OCLC:

52105958