Solvent mixtures : properties and selective solvation / Yizhak Marcus.

Format:

Book

Author/Creator:

Marcus, Y.

Language:

English

Subjects (All):

Solvents.

Solution (Chemistry).

Physical Description:

xvii, 258 pages : illustrations ; 24 cm

Place of Publication:

New York : Marcel Dekker, [2002]

Contents:

1.1 Solvent Mixtures 1

1.2 The Concept of Preferential Solvation 6

1.3 The Composition of Mixed Solvents 11

2. Properties of Binary Solvent Mixtures 16

2.1 Representative Solvent Mixtures 16

2.2 Physical Properties 19

2.3 Thermodynamic Properties 45

2.4 Chemical Properties 86

2.5 Associated Mixtures 104

3. The Structure of Solvent Mixtures 121

3.1 Diffraction Methods 122

3.2 Computer Simulation Methods 128

3.3 Spectroscopic Methods 132

4. Preferential Solvation in Binary Solvent Mixtures 142

4.1 General Considerations 142

4.2 Descriptive Expressions 145

4.3 The Preferential Solvation Parameters 154

4.4 Use of Chemical Probes 167

4.5 Direct Spectroscopic and Structural Studies 176

5. Preferential Solvation of Solutes 180

5.1 General Considerations 180

5.2 Nonelectrolyte Solutes 183

5.3 Electrolyte Solutes 209

5.4 Preferential Solvation of Large Molecules 229

6. Multicomponent Solvent Mixtures 239

6.1 Thermodynamic and Physical Properties of Multicomponent Mixtures 240

6.2 Preferential Solvation in Ternary Solvent Mixtures 245

6.3 Solute Solubility in Ternary Solvent Mixtures 249.

Notes:

Includes bibliographical references and indexes.

ISBN:

0824708377

OCLC:

50198276