Reactive separation processes / edited by Santi Kulprathipanja.

Format:

Book

Contributor:

Kulprathipanja, Santi.

Language:

English

Subjects (All):

Separation (Technology).

Physical Description:

xvi, 251 pages : illustrations ; 24 cm

Place of Publication:

New York : Taylor & Francis, 2002.

Contents:

1 Reactive Separation Processes / William A. Leet, Santi Kulprathipanja 1

1.2 Advantages and Disadvantages 6

1.2.1 Advantages 7

1.2.2 Disadvantages 10

1.3 Applications Topics 12

2 Reactive Distillation / Gavin P. Towler, Stanley J. Frey 18

2.2 Industrial Applications 20

2.2.1 Esterification 20

2.2.2 Etherification 22

2.3 Theory 25

2.3.1 Equilibrium Behavior 25

2.3.2 Kinetically Limited Behavior 28

2.4 Modeling and Design 33

2.4.1 Equilibrium Modeling 33

2.4.2 Rate-Limited Modeling 35

2.5 Practical Design Considerations 36

2.5.1 Installation, Containment, and Removal of the Catalyst 37

2.5.2 Design for Good Reactive Phase Contact with the Catalyst 38

2.5.3 Design for Liquid-Vapor Contacting Through the Reactive Zone 39

2.5.4 Design for Proper Pressure Drop Through the Reactive Zone 39

2.5.5 Design for Proper Liquid Hold-Up 40

2.5.6 Design for Catalyst Deactivation 40

2.6 Commercially Proven Equipment Technology 41

2.6.1 Chemical Research & Licensing (CR&L) Catalyst Bales 41

2.6.2 Koch-Glitsch, Inc. Catalyst-Containing Structured Packing 42

2.6.3 Eastman Chemical High Liquid Hold-up Trays 45

2.6.4 Other Leading Reactive Distillation Equipment Concepts 45

3 Extraction with Reaction / Vincent Van Brunt, Jeffrey S. Kanel 51

3.2 Hydrometallurgical Separations 52

3.3 Homogeneous Reactions: Organic Separations 57

3.3.2 Hydrolysis 58

3.3.3 Saponification 62

3.3.4 Esterification 64

3.3.5 Transesterification 66

3.3.6 Polycarbonates 67

3.3.7 Nitration 68

3.3.8 UOP HF Alkylation Technology 70

3.3.9 UOP HF Detergent Alkylate Process 72

3.3.10 Oxidation 74

3.3.11 Oximation 75

3.3.12 Shell Higher Olefin Process (SHOP) 77

3.3.13 Hydroformylation 78

3.3.14 Modifiers, Phase Transfer Catalysts, and Surfactants 80

3.3.15 Dense Gas and Ionic Fluid Applications 86

4 Absorption with Reaction / Jerry H. Meldon 93

4.2 Local Mass Transfer Models 94

4.3 Mass Transfer with Chemical Reaction 97

4.3.1 Irreversible Reaction 97

4.3.2 Reversible Reaction 103

4.3.3 Perturbation Methods 104

4.4 Simultaneous Absorption of Carbon Dioxide and Hydrogen Sulfide in Alkaline Solutions 107

5 Adsorption with Reaction / Robert W. Carr, Hemant W. Dandekar 115

5.1.1 Applicability 116

5.1.2 Attributes 116

5.2 Reactor Types 117

5.2.1 Rotating Cylindrical Annulus Chromatographic Reactors 118

5.2.2 Countercurrent Moving-Bed Chromatographic Reactors 120

5.2.3 Simulated Countercurrent Moving-Bed Chromatographic Reactors 121

5.2.4 Pressure-Swing Adsorption Reactors 128

5.2.5 The Trickle-Bed Reactor 130

5.3 Issues in Adsorbent/Catalyst and Reactor Design 131

5.3.1 Adsorption Issues 131

5.3.2 Reaction Issues 132

5.3.3 Particle Design 132

5.4 Applications 133

5.4.1 Equilibrium-Limited Reactions 133

5.4.2 Selectivity-Limited Reactions 144

5.5 Process Evaluation 150

5.5.1 Impact on Process Flowsheet 150

5.5.2 Economic Impact 151

6 Reactive Membrane Separation / Jose G. Sanchez Marcano, Theodore T. Tsotsis 155

6.2 Catalytic Reactive Separation Processes 161

6.2.1 Dehydrogenation Reactions 161

6.2.2 Hydrogenation Reactions 164

6.2.3 Oxidation Reactions 165

6.2.4 Other High-Temperature Applications 172

6.2.5 Economic Considerations 176

6.2.6 Emerging Applications 178

6.3 Pervaporation Membrane Reactors 181

6.4 Membrane-Based Reactive Separations for Biological Processes 183

6.5 Environmental Applications of Membrane Bioreactors 189

6.6 Modeling of Membrane-Based Reactive Separation Processes 191

7 Reactive Crystallization / Vaibhav V. Kelkar, Ketan D. Samant, Ka M. Ng 209

7.2 Solid-Liquid Phase Diagrams with Reactions 210

7.2.1 Generation of Phase Diagrams 210

7.2.2 Example Phase Diagrams 211

7.2.3 Representation of High-Dimensional Phase Diagrams 212

7.2.4 Process Synthesis Based on Phase Diagrams 216

7.3 Crystallization Kinetics 218

7.3.1 Kinetics of Nucleation 219

7.3.2 Kinetics of Crystal Growth 221

7.4 The Population Balance 224

7.5 Generic Model for a Reactive Crystallizer 226

7.6 Mixing in Reactive Crystallizers 229

7.6.1 Experimental Studies 231

7.6.2 Modeling of Turbulent Mixing in Reactive Crystallizers 234

7.6.3 Operating Regimes 237

7.6.4 Effect of Operating Conditions on Crystal Attributes 239

7.6.5 Choice of Operating Regimes 241.

Notes:

Includes bibliographical references and index.

ISBN:

1560328258

OCLC:

45583416