Polyoxometalate chemistry : from topology via self-assembly to applications / edited by Michael T. Pope and Achim Müller.

Format:

Book

Contributor:

Pope, Michael Thor, 1933-

Müller, Achim.

Language:

English

Subjects (All):

Polyoxometalates.

Physical Description:

vii, 427 pages : illustrations (some color) ; 25 cm

Place of Publication:

Dordrecht ; Boston : Kluwer Academic Publishers, [2001]

Contents:

Synthetic Strategies

1. Rational Approaches to Polyoxometalate Synthesis / R. J. Errington 7

2. Functionalization of Polyoxometalates: Achievements and Perspectives / A. Proust, R. Villanneau 23

3. From the First Sulfurated Keggin Anion to a New Class of Compounds Based on the [M[subscript 2]O[subscript 2]S[subscript 2 superscript 2+] Building Block M=Mo, W / E. Cadot, B. Salignac, A. Dolbecq, F. Secheresse 39

4. Organometallic Oxometal Clusters / A. Proust, R. Villanneau, R. Delmont, V. Artero, P. Gouzerh 55

Structures: Molecular and Electronic

5. Spherical (Icosahedral) Objects in Nature and Deliberately Constructable Molecular Keplerates: Structural and Topological Aspects / O. Delgado, A. Dress, A. Muller 69

6. Syntheses and Crystal Structure Studies of Novel Selenium- and Tellurium-Substituted Lacunary Polyoxometalates / B. Krebs, E. Droste, M. Piepenbrink 89

7. Vibrational Spectroscopy of Heteropoly Acids / H. Ratajczak, A.J. Barnes, A. Bielanski, H.D. Lutz, A. Muller, M.T. Pope 101

8. Bond-Stretch Isomerism in Polyoxometalates? / M.-M. Rohmer, M. Benard, E. Cadot, F. Secheresse 117

9. Quantum-Chemical Studies of Electron Transfer in Transition-Metal Substituted Polyoxometalates / S.A. Borshch, H. Duclusaud 135

Solution Equilibria and Dynamics

10. Aqueous Peroxoisopolyoxometalates / O.W. Howarth, L. Pettersson, I. Andersson 145

11. Molybdate Speciation in Systems Related to the Bleaching of Kraft Pulp / F. Taube, I. Andersson, L. Pettersson 161

12. NMR Studies of Various Ligands Coordinated to Paramagnetic Polyoxometalates / B. A. Kim, H. So 175

From Discrete Clusters to Networks and Materials

13. Molecular Aspect of Energy Transfer from Tb[superscript 3+] to Eu[superscript 3+] in the Polyoxometalate Lattices: An Approach for Molecular Design of Rare-Earth Metal-Oxide Phosphors / T. Yamase 187

14. Conducting and Magnetic Organic / Inorganic Molecular Materials Based on Polyoxometalates / L. Ouahab, S. Golhen, S. Triki 205

15. Molecular Materials From Polyoxometalates / J.J. Borras-Almenar, J.M. Clemente-Juan, M. Clemente-Leon, E. Coronado, J.R. Galan-Mascaros, C.J. Gomez-Garcia 231

16. Framework Materials Composed of Transition Metal Oxide Clusters / M.I. Khan 255

17. Perspectives in the Solid State Coordination Chemistry of the Molybdenum Oxides / P.J. Hagrman, D. Hagrman, J. Zubieta 269

18. Polyoxometalate Clusters in a Supramolecular Self-Organized Environment: Steps Towards Functional Nanodevices and Thin Film Applications / D.G. Kurth, D. Volkmer 301

19. Polyoxometalate Chemistry: A Source for Unusual Spin Topologies / D. Gatteschi, R. Sessoli, A. Muller, P. Kogerler 319

20. Heteropolyanions: Molecular Building Blocks for Ultrathin Oxide Films / J.D. Powell, A.A. Gewirth, W.G. Klemperer 329

Applications: Catalysis, Biological Systems, Environmental Studies

21. Selective Oxidation of Hydrocarbons with Hydrogen Peroxide Catalyzed by Iron-substituted Silicotungstates / N. Mizuno 335

22. Aerobic Oxidations Catalyzed by Polyoxometalates / A.M. Khenkin, R. Ben-Daniel, A. Rosenberger, I. Vigdergauz, R. Neumann 347

23. Polyoxoanions in Catalysis: From Record Catalytic Lifetime Nanocluster Catalysis to Record Catalytic Lifetime Catechol Dioxygenase Catalysis / R.G. Finke 363

24. Ribosomal Crystallography and Heteropolytungstates / D. Janell, A. Tocilj, I. Kolln, F. Schlunzen, M. Gluhmann, H.A.S. Hansen, J. Harms, A. Bashan, I. Agmon, H. Bartel, M. Kessler, S. Weinstein, F. Franceshi, A. Yonath 391

25. Photocatalytic Decontamination by Polyoxometalates / A. Hiskia, E. Androulaki, A. Mylonas, A. Troupis, E. Papaconstantinou 417.

Notes:

Includes bibliographical references and index.

ISBN:

0792370112

OCLC:

46857935