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Clean synthesis using porous inorganic solid catalysts and supported reagents / James H. Clark and Christopher N. Rhodes.

LIBRA QD505 .C58 2000
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Format:
Book
Author/Creator:
Clark, James H.
Contributor:
Rhodes, Christopher N.
Royal Society of Chemistry (Great Britain)
Rosengarten Family Fund.
Series:
RSC clean technology monographs
Language:
English
Subjects (All):
Catalysis.
Supported reagents.
Organic compounds--Synthesis.
Organic compounds.
Physical Description:
x, 107 pages : illustrations ; 25 cm.
Place of Publication:
Cambridge : Royal Society of Chemistry, [2000]
Contents:
1 Waste Minimisation 1
2 Clean Synthesis 1
3 Catalysts and Catalysis 3
4 Heterogeneous Catalysts 4
5 Heterogeneous Catalysis 5
6 Adsorption by Powders and Porous Solids 6
7 Reactor Types 7
8 Commercial Heterogeneous Catalytic Processes 10
9 Role of Catalysis in Industrial Waste Minimisation 12
10 Heterogenisation 14
Chapter 2 Zeolitic Materials 17
2 Compositions 18
3 Synthesis 18
4 Zeolite Catalysis 18
5 Isomorphously Substituted Zeolites 20
6 Mesoporous Molecular Sieves 21
7 Catalytic Applications of Zeolites and Related Materials 21
Alkylation of Aromatics 22
Catalytic Cracking 23
Fischer-Tropsch Synthesis 24
Aromatisation 24
Alcohol Dehydration 25
Methanol Synthesis 25
Base Catalysis 26
Oxidation 26
Rearrangements 27
Ammoxidation 27
Epoxidation 28
8 Future Trends in Zeolite Catalysts 28
9 New Developments in the Context of Clean Synthesis 28
Chapter 3 Clay Materials 37
2 Structure of Clays 37
3 Methods of Increasing the Catalytic Activity of Clays 39
4 Clay-supported Metal Catalysts 39
5 Pillared Clays 40
6 Clay Catalysed Reactions 42
Hydrogenation 42
Fischer-Tropsch Synthesis 43
Bronsted Acid Catalysed Reactions 43
Friedel-Crafts Alkylation 45
Aldol Condensation 48
Oxidation 48
7 New Developments in the Context of Clean Synthesis 49
Chapter 4 Supported Reagents 55
1 Introduction to Supported Reagent Chemistry 55
2 Types of Supported Reagents 56
Porosity 57
Chemical Composition 58
Surface 58
3 Preparation of Supported Reagents 60
4 Properties of Supported Reagents 62
Methods of Studying Supported Reagents 62
Surface Structure 62
Catalyst Stability 68
Catalyst Recovery and Regenerability 70
5 Applications of Supported Reagents 71
Partial Oxidations 71
Reactions Catalysed by Solid Acid Supported Reagents 79
Base Catalysis 88
Other Applications for Supported Reagent Catalysts 92.
Notes:
Includes bibliographical references and index.
Local Notes:
Acquired for the Penn Libraries with assistance from the Rosengarten Family Fund.
ISBN:
0854045260
OCLC:
44398743

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