Direct synthesis of coordination and organometallic compounds / edited by Alexander D. Garnovskii, Boris I. Kharisov ; contributors, A.D. Garnovskii ... [and others].

Format:

Book

Contributor:

Garnovskiĭ, A. D.

Kharisov, Boris I.

Language:

English

Subjects (All):

Coordination compounds--Synthesis.

Organometallic compounds--Synthesis.

Organometallic compounds.

Coordination compounds.

Physical Description:

ix, 244 pages : illustrations ; 25 cm

Edition:

First edition.

Place of Publication:

Amsterdam ; New York : Elsevier, 1999.

Summary:

This book is devoted to the interaction between elemental metals and (in)organic ligands in different reaction conditions. Metals could be activated for further reactions as cryosynthesis, electrosynthesis and tribosynthesis, some of them with or without ultrasonic and microwave treatment. The kinetics of metal dissolution in various non-aqueous media is discussed in detail.

Contents:

Chapter I Cryosynthesis of Metal Complexes

1. Methods, Conditions, Equipment, Reagents

2. Synthesis of Metal Complexes with Simple Inorganic Ligands

3. Cryosynthesis of [pi] and [sigma] Metal Complexes

4. Vapor Synthesis of Metal Chelates

Chapter II Electrochemical Synthesis of Metal Complexes

1. General Concepts about Electrochemical Synthesis

a) Practical Aspects

b) Solvent and Supporting Electrolyte

c) Types of Cells

d) Electrolytic Parameters

2. Electrosynthesis at Sacrificial Anode

a) Synthesis of Molecular Complexes (Adducts)

b) Synthesis of Metal Chelates

c) Synthesis of Di- and Polymetallic Complexes

d) Synthesis of [sigma] and [pi] Organometallic Complexes

3. Electrosynthesis at Sacrificial Cathode

Chapter III Oxidative Dissolution of Metals and Metal Oxides in a Liquid Phase

1. Kinetics of Dissolution of Metal Powders and Metal Oxides

2. Direct Synthesis Using Halogenated Hydrocarbon

3. Direct Synthesis in Solutions of Proton-Donor Reagents

4. Direct Synthesis with Ammonium Salts Solutions

a) Complexes Containing Ammonia and Solvent Molecules

b) Compounds Containing Complex Anions

c) Complexes with Pyridine

d) Complexes with Ethylenediamine and its Derivatives

e) Complexes with Aminoalcohols

5. Interaction of Metals with Quinones and Phthalocyanine Precursors

Chapter IV Mechanosynthesis of Coordination Compounds

1. Complex-Formation in the System "Metal-CC1[subscript 4]-DMSO"

2. Interaction Between Copper and Salycialdehyde

3. Interaction Between Copper and Azomethinic Ligands

4. Interaction Between Copper and Schiff Bases of 1-phenyl-3-methylpyrasolone-5 and its S- and Se-Containing Analogues

5. Interaction Between Copper and Oxyazo Compounds

6. Interaction Between Copper and Nickel with 8-Oxyquinoline and its Derivatives

7. Interaction Between Copper and Iron with Acetylacetone and 1-(Tenoil-2)-3, 3, 3-Trifluoroacetone

8. Interaction Between Copper with N-Acylsalicylamide Solutions

9. Interaction Between Copper with Disalicylamide

10. Formation of Coordination Metal-Polymers

Chapter V Some Peculiarities of Crystal Structure of Complexes Obtained by the Direct Synthesis.

Notes:

Includes bibliographical references and indexes.

ISBN:

0444720006

OCLC:

41355647