Heterogeneous catalysis and fine chemicals IV : proceedings of the 4th International Symposium on Heterogeneous Catalysis and Fine Chemicals, Basel, Switzerland, September 8-12, 1996 / editors, H.U. Blaser, A. Baiker, R. Prins.

Format:

Book

Conference/Event

Contributor:

Blaser, H. U.

Baiker, A. (Alfons)

Prins, Roelof.

Conference Name:

International Symposium on Heterogeneous Catalysis and Fine Chemicals (4th : 1996 : Basel, Switzerland)

Series:

Studies in surface science and catalysis ; 108.

Studies in surface science and catalysis ; 108

Language:

English

Subjects (All):

Heterogeneous catalysis--Congresses.

Heterogeneous catalysis.

Genre:

Conference papers and proceedings.

Physical Description:

xvi, 675 pages : illustrations ; 25 cm.

Place of Publication:

Amsterdam ; New York : Elsevier, 1997.

Contents:

Financial Support XV

Industrial and Engineering Problems

1 Homogeneous catalysis for fine chemicals synthesis - new trends and perspectives / M. Beller 1

2 Catalysis for agrochemicals: the case history of the DUAL herbicide / R.R. Bader, H.U. Blaser 17

3 Heterogeneous vs. homogeneous catalysis in manufacturing of terbinafine - a case study for route selection of an industrial process / U. Beutler, C. Fleury, P.C. Funfschilling, G. Penn, Th. Ryser, B. Schenkel 31

4 Multiple use of palladium in a homogeneous and a consecutive heterogeneous catalytic reaction / P. Baumeister, W. Meyer, K. Oertle, G. Seifert, U. Siegrist, H. Steiner 37

5 The optimization of the catalytic hydrogenation of hydroxybenzamidines to benzamidines / M.G. Scaros, P.K. Yonan, S.A. Laneman 41

6 Catalytic hydrogenation reactors for the fine chemicals industries; their design and operation / K.R. Westerterp, E.J. Molga, K.B. van Gelder 47

7 Selective catalytic hydrogenation of 2-butyne-1,4-diol to cis-2-butene-1,4-diol in mass transfer efficient slurry reactors / J.M. Winterbottom, H. Marwan, J. Viladevall, S. Sharma, S. Raymahasay 59

Alkylation and Acylation Reactions

8 Replacing liquid acids in fine chemical synthesis by sulfonated polysiloxanes as solid acids and as acidic supports for precious metal catalysts / St. Wieland, P. Panster 67

9 Amine functions linked to MCM-41-type silicas as a new class of solid base catalysts for condensation reactions / M. Lasperas, T. Llorett, L. Chaves, I. Rodriguez, A. Cauvel, D. Brunel 75

10 Modified clay catalysts for acylation of crown compounds / S. Bekassy, K. Biro, T. Cseri, B. Agai, F. Figueras 83

11 Acylation of aromatics over a HBEA Zeolite; effect of solvent and of acylating agent / F. Jayat, M.J. Sabater Picot, D. Rohan, M. Guisnet 91

12 Zeolite-catalysed acetylation of alkenes with acetic anhydride / K. Smith, Zhao Zhenhua, L. Delaude, P.K.G. Hodgson 99

13 Influence of the acidity and of the pore structure of zeolites on the alkylation of toluene by 1-heptene / P. Magnoux, A. Mourran, S. Bernard, M. Guisnet 107

14 Reductive O- and N-alkylations; alternative catalytic methods to nucleophilic substitution / F. Fache, V. Bethmont, L. Jacquot, F. Valot, A. Milenkovic, M. Lemaire 115

15 N-Methylation of aniline over AIPO[subscript 4] and AIPO[subscript 4]-metal oxide catalysts / F.M. Bautista, J.M. Campelo, A. Garcia, D. Luna, J.M. Marinas, A.A. Romero 123

16 Preparation of symmetrical and mixed secondary alkylamines over Raney nickel and supported copper catalysts / S. Gobolos, M. Hegedus, E. Talas, J.L. Margitfalvi 131

17 Synthesis of dimethylethylamine from ethylamine and methanol over copper catalysts / Y. Pouilloux, V. Doidy, S. Hub, J. Kervennal, J. Barrault 139

18 Catalyst acid/base properties regulation to control the selectivity in gasphase methylation of catechol / L. Kiwi-Minsker, S. Porchet, R. Doepper, A. Renken 149

Enantio- and Diastereoselective Hydrogenation Reactions

19 Enantioselective hydrogenation of ethyl-pyruvate and isophorone over modified Pt and Pd catalysts / A. Tungler, K. Fodor, T. Mathe, R.A. Sheldon 157

20 Controlling the enantioselective hydrogenation of ethyl pyruvate using zeolites as catalyst support / K. Morgenschweis, E. Polkiehn, W. Reschetilowski 167

21 Kinetic modeling of the ligand accelerated catalysis in the enantioselective hydrogenation of ethyl pyruvate; influence of solvents, catalysts and additives / H.U. Blaser, D. Imhof, M. Studer 175

22 Modeling of kinetically coupled selective hydrogenation reactions: kinetic rationalization of pressure effects on enantioselectivity / J. Wang, C. LeBlond, C.F. Orella, Y. Sun, J.S. Bradley, D.G. Blackmond 183

23 Enantioselective hydrogenation of (E)-[alpha]-phenylcinnamic acid on cinchonidine-modified palladium catalysts: influence of support / Y. Nitta, K. Kobiro, Y. Okamoto 191

24 Enantio-differentiating hydrogenation of 3-alkanones with asymmetrically modified fine nickel powder / T. Osawa, T. Harada, A. Tai, O. Takayasu, I. Matsuura 199

25 Diastereoselective hydrogenation of a prostaglandin intermediate over Ru supported on different molecular sieves / F. Cocu, S. Coman, C. Tanase, D. Macovei, V.I. Parvulescu 207

26 Diastereoselective hydrogenation of substituted aromatics on supported rhodium catalysts: influence of support and of thermal treatment / M. Besson, P. Gallezot, C. Pinel, S. Neto 215

27 Stereoselective reductions of aromatic compounds / E. Auer, A. Freund, P. Panster, G. Stein, Th. Tacke 223

Chemoselective Hydrogenation Reactions

28 Selective reduction of nitro groups in aromatic azo compounds / M. Lauwiner, R. Roth, P. Rys, J. Wissmann 231

29 Selective catalytic hydrogenation of 2,4-dinitrotoluene to nitroaryl-hydroxylamines on supported metal catalysts / M.G. Musolino, C. Milone, G. Neri, L. Bonaccorsi, R. Pietropaolo, S. Galvagno 239

30 Kinetics and pathways of selective hydrogenation of 1-(4-nitrobenzyl)-1,2,4-triazole / C. LeBlond, J. Wang, R.D. Larsen, C.J. Orella, A.L. Forman, F.P. Gortsema, T.R. Verhoeven, Y.-K. Sun 247

31 Design of selective 1-ethyl-2-nitromethylenepyrrolidine hydrogenation for pharmaceuticals production / V.A. Semikolenov, I.L. Simakova, A.V. Golovin, O.A. Burova, N.M. Smirnova 255

32 Kinetic study of a nitroaliphatic compound hydrogenation / V. Dubois, G. Jannes, P. Verhasselt 263

33 Kinetics of the hydrogenation of citral over supported Ni catalyst / P. Maki-Arvela, L.-P. Tiainen, R. Gil, T. Salmi 273

34 Selective hydrogenation of [alpha, beta]-unsaturated aldehydes to allylic alcohols over supported monometallic and bimetallic Ag catalysts / P. Claus, P. Kraak, R. Schodel 281

35 Surface organometallic chemistry on metals; selective hydrogenation of acetophenone on modified rhodium catalyst / F. Humblot, M.A. Cordonnier, C. Santini, B. Didillon, J.P. Candy, J.M. Basset 289

36 Use of Ni containing anionic clay minerals as precursors of catalysts for the hydrogenation of nitriles / D. Tichit, F. Medina, R. Durand, C. Mateo, B. Coq, J.E. Sueiras, P. Salagre 297

37 The effect of co-adsorbates on activity/selectivity in the hydrogenation of aromatic alkynes / S.D. Jackson, H. Hardy, G.J. Kelly, L.A. Shaw 305

38 Simple preparation of bimetallic palladium-copper catalysts for selective liquid phase semihydrogenation of functionalized acetylenes and propargylic alcohols / M.P.R. Spee, D.M. Grove, G. van Koten, J.W. Geus 313

39 Catalytic hydrogenation by polymer stabilized rhodium / G.W. Busser, J.G. van Ommen, J.A. Lercher 321

Oxidation Reactions

40 Epoxidation of cycloalkenones over amorphous titania-silica aerogels / R. Hutter, T. Mallat, A. Baiker 329

41 Selective aerobic epoxidation of olefins over NaY and NaZSM-5 zeolites containing transition metal ions / O. Kholdeeva, A.V. Tkachev, V.N. Romannikov, I.V. Khavrutskii, K.I. Zamaraev 337

42 Effect of preparation methods of titania/silicas on their catalytic activities in the oxidation of olefins / M. Toba, S. Niwa, H. Shimada, F. Mizukami 345

43 Heterogeneous catalysts from organometallic precursors: how to design isolated, stable and active sites; applications to zirconium catalyzed organic reactions / A. Choplin, B. Coutant, C. Dubuisson, P. Leyrit, C. McGill, F. Quignard, R. Teissier 353

44 Selective sulfoxidation of thioethers on Ti-containing zeolites under mild conditions / V. Hulea, P. Moreau, F. Di Renzo 361

45 Allylic oxidation of cyclohexene catalysed by metal exchanged zeolite Y / O.B. Ryan, D.E. Akporiaye, K.H. Holm, M. Stocker 369

46 Ammoxidation of methylaromatics over NH[subscript 4 superscript +]-containing vanadium phosphate catalysts - new mechanistic insights / A. Martin, A. Bruckner, Y. Zhang, B. Lucke 377

47 Hydrogen peroxide oxidation of methyl [alpha]-D-glucopyranoside, sucrose and [alpha, alpha]-trehalose with Ti-MCM-41 / E.J.M. Mombarg, S.J.M. Osnabrug, F. van Rantwijk, H. van Bekkum 385

48 On the role of bismuth-based alloys in carbon-supported bimetallic Bi-Pd catalysts for the selective oxidation of glucose to gluconic acid / M. Wenkin, C. Renard, P. Ruiz, B. Delmon, M.

Devillers 391

49 Selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarbox-aldehyde in the presence of titania supported vanadia catalysts / C. Moreau, R. Durand, C. Pourcheron, D. Tichit 399

50 Dehydrogenation of methoxyisopropanol to methoxyacetone on supported bimetallic Cu-Zn catalysts / M.V. Landau, S.B. Kogan, M. Herskowitz 407

51 Butadione synthesis by dehydrogenation and oxidative dehydrogenation of 2,3-butanediol / G.V. Isagulyants, I.P. Belomestnykh 415

52 Phase transition of crystalline [alpha]-Te[subscript 2]MoO[subscript 7] to the vitreous [beta]-form, surface composition, and activity in the vapor-phase selective oxidation of ethyl lactate to pyruvate over TeO[subscript 2]-MoO[subscript 3] catalysts / H. Hayashi, S. Sugiyama, T. Moriga, N. Masaoka, A. Yamamoto 421

53 Selective oxidation with air of glyceric to hydroxypyruvic acid and tartronic to mesoxalic acid on PtBi/C catalysts / P. Fordham, M. Besson, P. Gallezot 429

Immobilized and Encapsulted Complex Catalysts

54 PDMS occluded Ti-MCM-41 as an improved olefin epoxidation catalyst / I.F.J. Vankelecom, N.M.F. Moens, K.A.L. Vercruysse, R.F. Parton, P.A. Jacobs 437

55 Epoxidation with manganese N,N'-bis(2-pyridinecarboxamide) complexes encapsulated in Zeolite Y / P.P. Knops-Gerrits, M. L'abbe, P.A. Jacobs 445

56 Selective oxidation of benzyl alcohol on a zeolite ship-in-a-bottle complex / A. Zsigmond, F. Notheisz, Z. Frater, J.E. Backvall 453

57 Oxidation of pinane using zeolite encapsulated metal phthalocyanine catalysts / A.A. Valente, J. Vital 461

58 Hydrogenation of carbonyl groups containing compounds over Pt(II)-salen complexes occluded in zeolites / W. Kahlen, A. Janssen, W.F. Holderich 469

59 Novel clay intercalated metal catalysts: a study of the hydrogenation of styrene and 1-octene on clay intercalated Pd catalysts / A. Mastalir, F. Notheisz, Z. Kiraly, M. Bartok, I. Dekany 477

60 Catalytic enantioselective addition of diethylzinc to benzaldehyde induced by immobilized ephedrine: comparison of silica and MCM-41 type mesoporous silicates as supports / N. Bellocq, D. Brunel, M. Lasperas, P. Moreau 485

61 The immobilization of sulfonated Ru-BINAP chloride by anion exchange on layered double hydroxides / D. Tas, D. Jeanmart, R.F. Parton, P.A. Jacobs 493

62 Regiospecific hydrosilylation of styrene by rhodium complexes heterogenised on modified USY-zeolites / A. Corma, M.I. de Dios, M. Iglesias, F. Sanchez 501

63 Polymer-supported Al and Ti species as catalysts for Diels-Alder reactions / B. Altava, M.I. Burguete, J.M. Fraile, J.I. Garcia, S.V. Luis, J.A. Mayoral, A.J. Royo, R.V. Salvador 509

64 Molecular imprinting; polymerised catalytic complexes in asymmetric catalysis / F. Locatelli, P. Gamez, M. Lemaire 517

65 Environmentally friendly catalysis of liquid phase organic reactions using chemically modified mesoporous materials / A.J. Butterworth, J.H. Clark, A. Lambert, D.J. Macquarrie, S.J. Tavener 523

Zeolite and Clay Catalysts

66 Meerwein-Ponndorf-Verley and Oppenauer reactions catalysed by heterogeneous catalysts / E.J. Creyghton, J. Huskens, J.C. van der Waal, H. van Bekkum 531

67 Selective synthesis of monoglycerides from glycerol and oleic acid in the presence of solid catalysts / S. Abro, Y. Pouilloux, J. Barrault 539

68 Zeolite-catalysed hydrolysis of aromatic amides / B. Gigante, C. Santos, M.J. Marcelo-Curto, C. Coutanceau, J.M. Silva, F. Alvarez, M. Guisnet, E. Selli, L. Forni 547

69 Hydration of [alpha]-pinene and camphene over USY zeolites / H. Valente, J. Vital 555

70 Dehydration of 2-(2-hydroxyethyl)-pyridine to 2-vinyl-pyridine over solid acid catalysts / L. Forni, D. Moscotti, E. Selli, I. Belegridi, M. Guisnet, D. Rohan, B. Gigante, C. Coutanceau, J.M. Silva, F. Alvarez 563

71 The use of heterogeneous copper catalysts in cyclopropanation reactions / J.M. Fraile, B. Garcia, J.I. Garcia, J.A. Mayoral, F. Figueras 571

72 Reaction between haloaromatics over Cu-HZSM-5 zeolite; mechanistic study / S. Vol, L. Vivier, G. Perot 579

73 Selective isomerization of [alpha]-pinene oxide with heterogeneous catalysts / A.T. Liebens, C. Mahaim, W.F. Holderich 587

74 Reactions of 2,2-dimethyl-1,3-propanediol with zeolites: correlation of selectivity with acidity / H.U. Blaser, B. Casagrande, B. Siebenhaar 595

75 Clay-catalyzed reactions of imidazole and benzimidazoles with propiolic esters / M. Balogh, C. Gonczi, I. Hermecz 603

76 Selective synthesis of cyclohexylcyclohexanone on bifunctional zeolite catalysts; influence of the metal and of the pore structure / F. Alvarez, A.I. Silva, F. Ramoa Ribeiro, G. Giannetto, M. Guisnet 609

77 Solid acid catalyzed disproportionation and alkylation of alkylsilanes / T. Yamaguchi, T. Yamada, M. Shibata, T. Tsuneki, M. Ookawa 617

78 Intramolecular ene reactions promoted by mixed cogels / N. Ravasio, M. Antenori, F. Babudri, M. Gargano 625

79 Rh[superscript 3+]ions and Rh[superscript 3+]-diamine complexes intercalated in [alpha]- and [gamma]-zirconium hydrogen phosphate as stable and effective catalysts for the conversion of aniline or nitrobenzene to carbamates and/or N,N'-diphenylurea; Part 3 / P. Giannoccaro, S. Doronzo, C. Ferragina 633

80 1,4-Butanediol conversion routes over bifunctional supported Co-Zn catalyst / L. Leite, S. Kruc, Zh. Yuskovets, V. Stonkus, M. Fleisher, E. Lukevics, J. Stoch, M. Mikalayczyk 641

81 Preparation of solid superbase catalyst and its application to the synthesis of fine chemicals / G. Suzukamo, M. Fukao, T. Hibi, K. Tanaka, M. Minobe 649

82 Synthesis of delicious peptide fragments catalyzed by immobilized proteases / M.D. Romero, J. Aguado, M.J. Guerra, G. Alvaro, R. Navarro, E. Rubio 657

Other volumes in the series 669.

Notes:

Includes bibliographical references and index.

ISBN:

0444823905

OCLC:

36656366